Issue 41, 2022

Three-dimensional Cd(ii) porphyrin metal–organic frameworks for the colorimetric sensing of Electron donors

Abstract

Metalloporphyrins are promising colorimetric sensors for a wide range of small molecule analytes. Three 3D metal–organic frameworks containing metallated 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin (TCPP) with Cd(II) and 1,2-bis(4-pyridyl)ethylene (bpe) or 1,2-bis(4-pyridyl)diazene (bpaz) featured open square 1D channels decorated with metalloporphyrin units. Exposure of the frameworks to amine vapours resulted in significant shifts in the metalloporphyrin Soret bands, enabling the colorimetric detection of amines. The electron-accepting properties of metalloporphyrin units were additionally exploited for the colorimetric detection of electron-rich species.

Graphical abstract: Three-dimensional Cd(ii) porphyrin metal–organic frameworks for the colorimetric sensing of Electron donors

Supplementary files

Article information

Article type
Paper
Submitted
21 яну 2022
Accepted
16 мар 2022
First published
18 мар 2022

CrystEngComm, 2022,24, 7277-7282

Three-dimensional Cd(II) porphyrin metal–organic frameworks for the colorimetric sensing of Electron donors

H. M. Tay, E. J. Goddard and C. Hua, CrystEngComm, 2022, 24, 7277 DOI: 10.1039/D2CE00103A

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