Issue 10, 2018

Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

Abstract

Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.

Graphical abstract: Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

Supplementary files

Article information

Article type
Paper
Submitted
17 яну 2018
Accepted
06 мар 2018
First published
07 мар 2018

New J. Chem., 2018,42, 8220-8229

Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

X. Jiang, W. Shan, N. Desbois, V. Quesneau, S. Brandès, E. V. Caemelbecke, W. R. Osterloh, V. Blondeau-Patissier, C. P. Gros and K. M. Kadish, New J. Chem., 2018, 42, 8220 DOI: 10.1039/C8NJ00300A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements