Issue 3, 2010
From the journal:

Chemical Communications

Hydrogen evolution by cobalt tetraiminecatalysts adsorbed on electrode surfaces†

Louise A. Berbena  and  Jonas C. Peters*a  

* Corresponding authors

a Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA
E-mail: jcpeters@mit.edu
Fax: +1 617 324 1554
Tel: +1 617 253 1819

Abstract

Aryl-substituted tetraimine complexes related to Co(dmgBF2)2(MeCN)2 (dmg = dimethylglyoxime) were synthesized and are active for hydrogen evolution. Co(dmgBF2)2(MeCN)2 can be adsorbed to a glassy carbon electrode. The chemically modified electrode is active for hydrogen evolution in aqueous solution at pH < 4.5, with an overpotential of only 100 mV.

Graphical abstract: Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B921559J
Article type
Communication
Submitted
14 окт 2009
Accepted
10 ное 2009
First published
25 ное 2009

Chem. Commun., 2010,46, 398-400

Permissions

Request permissions

Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces

L. A. Berben and J. C. Peters, Chem. Commun., 2010, 46, 398 DOI: 10.1039/B921559J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements