Visible light photocatalytic NOx removal with suppressed poisonous NO2 byproduct generation over simply synthesized triangular silver nanoparticles coupled with tin dioxide

Abstract

The treatment or conversion of air pollutants with a low generation of secondary toxic substances has become a hot topic in indoor air pollution abatement. Herein, we used triangle-shaped Ag nanoparticles coupled with SnO₂ for efficient photocatalytic NO removal. Ag triangular nanoparticles (TNPs) were synthesized by the photoreduction method and SnO₂ was coupled by a simple chemical impregnation process. The photocatalytic NO removal activity results show that the modification with Ag TNPs significantly boosted the removal performance up to 3.4 times higher than pristine SnO₂. The underlying roles of Ag TNPs in NO removal activity improvement are due to some advantages of Ag TNPs. Moreover, the Ag TNPs contributed photogenerated holes as the main active species toward enhancing the NO oxidation reaction. In particular, the selectivity toward green products significantly improved from 52.78% (SnO₂) to 86.99% (Ag TNPs/SnO₂). The formation of reactive radicals under light irradiation was also verified by DMPO spin-trapping experiments. This work provides a potential candidate for visible-light photocatalytic NO removal with low toxic byproduct generation.