Issue 4, 2023

Advanced atomic layer deposition: metal oxide thin film growth using the discrete feeding method

Abstract

A HfO2 film was grown via atomic layer deposition (ALD) with a discrete feeding method (DFM), called DF-ALD, and its physical, chemical, and electrical properties were studied. In conventional ALD processes, even in the growth saturation condition, not all substrate surface reactive sites react with precursor or reactant molecules because physisorbed precursor and byproduct molecules screen the subjacent surface reactive sites. The DF-ALD process in this work employed divided precursor feeding and purging steps in the growth saturation condition of a control ALD process, such that the divided steps efficiently eliminated the physisorbed precursor molecules or by-products screening the subjacent surface reactive sites. This increased the adsorption and filling efficiency of the precursor molecules onto the substrate or film surface during deposition. As a result, the DF-ALD increased the film density and reduced the interfacial layer thickness which degrades the electrical properties of a high-k dielectric, and reduced impurities in the HfO2 thin film.

Graphical abstract: Advanced atomic layer deposition: metal oxide thin film growth using the discrete feeding method

Supplementary files

Article information

Article type
Paper
Submitted
18 авг 2022
Accepted
10 дек 2022
First published
12 дек 2022

J. Mater. Chem. C, 2023,11, 1298-1303

Advanced atomic layer deposition: metal oxide thin film growth using the discrete feeding method

J. C. Park, C. I. Choi, S. Lee, S. J. Yoo, J. Lee, J. H. Jang, W. Kim, J. Ahn, J. H. Kim and T. J. Park, J. Mater. Chem. C, 2023, 11, 1298 DOI: 10.1039/D2TC03485A

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