Ba8SrPb24O24Cl18: the first alkali-earth metal lead(II) oxyhalide with an intriguing multimember-ring layer

Zhuang Li; Shengzi Zhang; Wenhao Xing; Zheshuai Lin; Jiyong Yao; Yicheng Wu

doi:10.1039/C9DT02839K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Ba₈SrPb₂₄O₂₄Cl₁₈: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer†

Zhuang Li,

^abc Shengzi Zhang,^ac Wenhao Xing,^abc Zheshuai Lin,^a Jiyong Yao

*^ab and Yicheng Wu^ad

Author affiliations

* Corresponding authors

^a Beijing Center for Crystal Research and Development, Key Lab of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: jyao@mail.ipc.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^c University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^d Institute of Functional Crystal Materials, Tianjin University of Technology, Tianjin 300384, P.R. China

Abstract

The first alkali-earth metal lead(II) oxyhalide Ba₈SrPb₂₄O₂₄Cl₁₈ characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba₈SrPb₂₄O₂₄Cl₁₈ exhibits a moderate band gap of 3.09 eV, incongruent melting behavior and birefringence of 0.014@1064 nm. This discovery may offer new ideas for regulating the optical properties of oxyhalides and broadening their structural diversity.

This article is part of the themed collection: Inorganic Porous and Layered Material

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9DT02839K
Article type: Communication
Submitted: 09 юли 2019
Accepted: 17 авг 2019
First published: 19 авг 2019

Download Citation

Dalton Trans., 2020,49, 3667-3671

Permissions

Request permissions

Ba₈SrPb₂₄O₂₄Cl₁₈: the first alkali-earth metal lead(II) oxyhalide with an intriguing multimember-ring layer

Z. Li, S. Zhang, W. Xing, Z. Lin, J. Yao and Y. Wu, Dalton Trans., 2020, 49, 3667 DOI: 10.1039/C9DT02839K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions