Issue 83, 2020
From the journal:

Chemical Communications

All-metal Baird aromaticity†

Dandan Chen, ORCID logo ab   Dariusz W. Szczepanik, ORCID logo bc   Jun Zhu ORCID logo *a  and  Miquel Solà ORCID logo *b  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: jun.zhu@xmu.edu.cn

b Institute of Computational Chemistry and Catalysis and Department of Chemistry, University of Girona, C/M. Aurèlia Capmany 69, Girona, Catalonia, Spain
E-mail: miquel.sola@udg.edu

c K. Guminski Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, Kraków 30-387, Poland

Abstract

Baird's rule has been applied to a large scope of organic molecular systems for rationalizing the aromaticity reversal in the lowest-lying triplet state. In this study, we demonstrate that Baird's rule can also be extended to all-metal systems with σ- and π-aromaticity.

Graphical abstract: All-metal Baird aromaticity

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC05586G
Article type
Communication
Submitted
17 авг 2020
Accepted
07 сеп 2020
First published
07 сеп 2020

Chem. Commun., 2020,56, 12522-12525

Permissions

Request permissions

All-metal Baird aromaticity

D. Chen, D. W. Szczepanik, J. Zhu and M. Solà, Chem. Commun., 2020, 56, 12522 DOI: 10.1039/D0CC05586G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements