Issue 21, 2019

Low-dimensional non-toxic A3Bi2X9 compounds synthesized by a dry mechanochemical route with tunable visible photoluminescence at room temperature

Abstract

We have synthesized fifteen inorganic and hybrid organic–inorganic non-toxic A3Bi2X9 compounds (A = K+, Rb+, Cs+, CH3NH3+ and HC(NH2)2+; X = I, Br, Cl) through dry mechanochemistry. We demonstrate that this synthetic method is very well suited to prepare compounds from poorly soluble precursors, allowing thus the preparation of so far unreported compounds. X-ray diffraction analysis demonstrates the high crystallinity of the so-formed ternary bismuth halides. Furthermore, we show that, through substitution of the A-cation and X-anion, the bandgap of these compounds can be tuned to absorb throughout the whole visible spectrum. As-prepared powders of Cs3Bi2Br9 and Cs3Bi2I9 without any passivating agents show room-temperature photoluminescence covering the visible spectrum from 450 nm to 800 nm, making them especially promising for white-light emission.

Graphical abstract: Low-dimensional non-toxic A3Bi2X9 compounds synthesized by a dry mechanochemical route with tunable visible photoluminescence at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
02 апр 2019
Accepted
08 май 2019
First published
09 май 2019

J. Mater. Chem. C, 2019,7, 6236-6240

Low-dimensional non-toxic A3Bi2X9 compounds synthesized by a dry mechanochemical route with tunable visible photoluminescence at room temperature

Y. El Ajjouri, V. S. Chirvony, N. Vassilyeva, M. Sessolo, F. Palazon and H. J. Bolink, J. Mater. Chem. C, 2019, 7, 6236 DOI: 10.1039/C9TC01765H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements