A novel ball milling technique for room temperature processing of TiO2 nanoparticles employed as the electron transport layer in perovskite solar cells and modules

Abstract

Anatase titanium dioxide (an-TiO₂) is often used as the electron transporting material (ETM) in planar-heterojunction perovskite solar cells (PSCs) because of its excellent semiconductor characteristics, outstanding optical transmittance, and suitable band structure. Herein, we report an inexpensive method for mass-scale production of TiO₂ ETMs at room temperature (RT ∼ 30 °C), involving the grinding of large clumps of an-TiO₂ to form a suspension of TiO₂ nanoparticles (NPs) in isopropyl alcohol for meso-superstructured PSCs. This process does not involve any chemical synthesis; it is a purely physical process. The lowest unoccupied molecular orbital (LUMO) of ground an-TiO₂ NPs, estimated using ultraviolet photoelectron spectroscopy (UPS), was ca. 4.06 eV, which is a salient feature for the active layer. A regular perovskite solar cell (PSC) based on a CH₃NH₃PbI₃ absorber and ground an-TiO₂ ETL exhibited a champion power conversion efficiency (PCE) of 17.43% with an active area of 0.1 cm². The same ground an-TiO₂ NPs were used to fabricate a large-area (designated area: 25.2 cm²) PSC and a PCE of 14.19% was achieved. PSC devices incorporating the ground an-TiO₂ NP ETLs exhibited an attractive long-term device stability, with the PCE retaining approximately 85% of the initial values after 80 days.