Piers’ borane-mediated hydrosilylation of epoxides and cyclic ethers

Jianbo Zhang; Sehoon Park; Sukbok Chang

doi:10.1039/C8CC03741H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Piers’ borane-mediated hydrosilylation of epoxides and cyclic ethers†

Jianbo Zhang,

^ab Sehoon Park

*^ab and Sukbok Chang

*^ab

Author affiliations

* Corresponding authors

^a Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 305-701, South Korea
E-mail: sehoonp@kaist.ac.kr, sbchang@kaist.ac.kr

^b Department of Chemistry, Korea Advanced Institute of Science & Technology (KAIST), Daejeon 305-701, South Korea

Abstract

We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers’ borane (C₆F₅)₂BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C₆F₅)₂BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.

This article is part of the themed collection: Celebrating the 75th Anniversary of the Korean Chemical Society (KCS)

Download options Please wait...

Supplementary files

Supplementary information PDF (3290K)

Article information

DOI: https://doi.org/10.1039/C8CC03741H
Article type: Communication
Submitted: 09 май 2018
Accepted: 06 юни 2018
First published: 07 юни 2018

Download Citation

Chem. Commun., 2018,54, 7243-7246

Permissions

Request permissions

Piers’ borane-mediated hydrosilylation of epoxides and cyclic ethers

J. Zhang, S. Park and S. Chang, Chem. Commun., 2018, 54, 7243 DOI: 10.1039/C8CC03741H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Piers’ borane-mediated hydrosilylation of epoxides and cyclic ethers†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Piers’ borane-mediated hydrosilylation of epoxides and cyclic ethers

Social activity

Search articles by author

Spotlight

Advertisements