Recent developments and future prospects of all-metal aromatic compounds

Abstract

The usefulness of aromaticity/antiaromaticity concepts to foresee structural stability patterns and salient features of the electronic structure of small inorganic and all-metal rings has been put forward. A critical revision of the advances made in the theoretical methods to assess the aromaticity/antiaromaticity of these compounds has also been made. In particular, the performance of local versus non-local indices has been reviewed. Finally, the passivation of these rings has been put forward as a key issue in order to prevent them from collapsing into larger aggregates and to provide them protection against the environment.