Issue 18, 2012
From the journal:

Dalton Transactions

Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks†

Adam F. Gross,*a   Elena Shermana  and  John J. Vajoa  

* Corresponding authors

a HRL Laboratories, LLC, 3011 Malibu Canyon Rd., Malibu, CA 90265, USA
E-mail: afgross@hrl.com
Fax: +01-310-317-5450
Tel: +01-310-317-5747

Abstract

Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.

Graphical abstract: Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

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Article information

DOI
https://doi.org/10.1039/C2DT30174A
Article type
Communication
Submitted
24 яну 2012
Accepted
28 фев 2012
First published
12 мар 2012

Dalton Trans., 2012,41, 5458-5460

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Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

A. F. Gross, E. Sherman and J. J. Vajo, Dalton Trans., 2012, 41, 5458 DOI: 10.1039/C2DT30174A

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