Issue 40, 2009

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

Abstract

Chiral rhodium–bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.

Graphical abstract: Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

Supplementary files

Article information

Article type
Communication
Submitted
31 юли 2009
Accepted
09 сеп 2009
First published
16 сеп 2009

Chem. Commun., 2009, 5987-5989

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

T. Shiomi, T. Adachi, K. Toribatake, L. Zhou and H. Nishiyama, Chem. Commun., 2009, 5987 DOI: 10.1039/B915759J

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