Issue 30, 2009

One-step formation of fused tetracyclic skeletons from cyclohexene-diynes and carbon monoxide through Rh(i)-catalyzed [2 + 2 + 2 + 1] cycloaddition reaction

Abstract

Rapid construction of 5-7-6-5 fused tetracyclic carbocycles and heterocycles from cyclohexene-diynes and CO has been achieved in one step through a Rh(I)-catalyzed [2 + 2 + 2 + 1] cycloaddition process.

Graphical abstract: One-step formation of fused tetracyclic skeletons from cyclohexene-diynes and carbon monoxide through Rh(i)-catalyzed [2 + 2 + 2 + 1] cycloaddition reaction

Supplementary files

Article information

Article type
Communication
Submitted
18 май 2009
Accepted
15 юни 2009
First published
29 юни 2009

Chem. Commun., 2009, 4569-4571

One-step formation of fused tetracyclic skeletons from cyclohexene-diynes and carbon monoxide through Rh(I)-catalyzed [2 + 2 + 2 + 1] cycloaddition reaction

J. J. Kaloko, Y. G. Teng and I. Ojima, Chem. Commun., 2009, 4569 DOI: 10.1039/B909781C

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