Issue 44, 2017

Electrophilicity of oxalic acid monomer is enhanced in the dimer by intermolecular proton transfer

Abstract

We have analyzed the effect of excess electron attachment on the network of hydrogen bonds in the oxalic acid dimer (OA)2. The most stable anionic structures may be viewed as complexes of a neutral hydrogenated moiety HOA˙ coordinated to an anionic deprotonated moiety (OA–H). HOA˙ acts as a double proton donor and (OA–H) as a double proton acceptor. Thus the excess electron attachment drives intermolecular proton transfer. We have identified several cyclic hydrogen bonded structures of (OA)2. Their stability has been analyzed in terms of the stability of the involved conformers, the energetic penalty for deformation of these conformers to the geometry of the dimer, and the two-body interaction energy between the deformed HOA˙ and (OA–H). There are at least seven isomers of (OA)2 with stabilization energies in the range of 1.26–1.39 eV. These energies are dominated by attractive two-body interaction energies. The anions are vertically bound electronically by 3.0–3.4 eV and adiabatically bound by at least 1.6 eV. The computational predictions are consistent with the anion photoelectron spectrum of (OA)2. The spectrum consists of a broad feature, with an onset of 2.5 eV and spanning to 4.3 eV. The electron vertical detachment energy (VDE) is assigned to be 3.3 eV.

Graphical abstract: Electrophilicity of oxalic acid monomer is enhanced in the dimer by intermolecular proton transfer

Supplementary files

Article information

Article type
Communication
Submitted
21 яну 2017
Accepted
30 окт 2017
First published
31 окт 2017

Phys. Chem. Chem. Phys., 2017,19, 29760-29766

Electrophilicity of oxalic acid monomer is enhanced in the dimer by intermolecular proton transfer

Z. G. Keolopile, M. R. Ryder, B. Calzada, M. Gutowski, A. M. Buytendyk, J. D. Graham and K. H. Bowen, Phys. Chem. Chem. Phys., 2017, 19, 29760 DOI: 10.1039/C7CP00474E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements