Spin-state modulation of molecular FeIII complexes via inclusion in halogen-bonded supramolecular networks

Ie-Rang Jeon; Olivier Jeannin; Rodolphe Clérac; Mathieu Rouzières; Marc Fourmigué

doi:10.1039/C7CC01943B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Spin-state modulation of molecular Fe^III complexes via inclusion in halogen-bonded supramolecular networks†

Ie-Rang Jeon,

*^a Olivier Jeannin,^a Rodolphe Clérac,

^bc Mathieu Rouzières^bc and Marc Fourmigué

*^a

Author affiliations

* Corresponding authors

^a Institut des Sciences Chimiques de Rennes, Université de Rennes 1 & CNRS UMR 6226, Campus Beaulieu, 35042 Rennes, France
E-mail: ie-rang.jeon@univ-rennes1.fr, marc.fourmigue@univ-rennes1.fr

^b CNRS, CRPP, UPR 8641, 33600 Pessac, France

^c Univ. Bordeaux, CRPP, UPR 8641, 33600 Pessac, France

Abstract

The cationic complex [Fe(qsal)₂]⁺ (Hqsal = N-(8-quinolyl)salicylaldimine) is encapsulated in anionic halogen-bonded 1D and 2D networks derived from sym-triiodotrifluorobenzene, [(C₆F₃I₃)Cl]⁻ and [(C₆F₃I₃)I]⁻. Structural analysis and magnetic measurements show that the spin-state of this complex can be modulated by its inclusion in supramolecular host frameworks.

This article is part of the themed collection: 1st International Conference on Noncovalent Interactions

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7CC01943B
Article type: Communication
Submitted: 14 мар 2017
Accepted: 31 мар 2017
First published: 31 мар 2017

Download Citation

Chem. Commun., 2017,53, 4989-4992

Permissions

Request permissions

Spin-state modulation of molecular Fe^III complexes via inclusion in halogen-bonded supramolecular networks

I. Jeon, O. Jeannin, R. Clérac, M. Rouzières and M. Fourmigué, Chem. Commun., 2017, 53, 4989 DOI: 10.1039/C7CC01943B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications