The recent advances in trifluoroethylation reactions were summarized based on the bond formation: C(sp)–CH2CF3, C(sp2)–CH2CF3, C(sp3)–CH2CF3, and X (X = N, O, S, Se)–CH2CF3.
This review systematically summarizes the key control parameters involved in the formation process of single-crystal COFs and discusses the challenges and opportunities of single-crystal COFs in various applications.
A novel photoredox-catalyzed coupling of silyl enol ethers with an N-trifluoroethyl hydroxylamine reagent via a radical 1,2-H shift efficiently affords β-trifluoromethyl β-aminoketones.
In this study, we have uncovered that trifluoroethylamine-substituted solvatochromic fluorophores maintain consistently high and stable fluorescence intensity in diverse polar environments, including highly polar and protic solvents.
We review recent progress in metalloporphyrin-catalyzed fluorinated carbene transfer reactions covering the transfer of various carbene species.