A metal and photocatalyst-free method for synthesizing BCP boronates via difunctionalization of [1.1.1]propellane using B2pin2 and Katritzky salts was reported.
Herein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.
This review summarises several approaches for photoinduced stereoselective deaminative alkylation. We have discussed a variety of bond formations, including Csp3–Csp, Csp3–Csp2, Csp3–Csp3, and Csp3–N.
A photochemical method for generating alkyl radicals and N-pyridyl radical cations from Katritzky salts and application of the radicals in functionalization of [1.1.1]propellane to generate benzophenone-type bioisosteres was reported.
A metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.