Organic–metal complexes (OMCs) are endowed with new functions and properties due to the characteristics of valence changes of metal ions and the diversity of organic molecular structures.
Pyridyl-substituted platinum acetylide complexes bind coinage metal cations, strongly influencing photoluminescence properties. Large counterions maintain the blue phosphorescence profile with large increases in radiative rate and quantum yield.
Mechanism study of dual ECL of p-PtBTD, driven by singlet and triplet excited states through RISC and TTA pathways.
Blue-phosphorescent platinum bis-acetylide complexes with two acyclic diaminocarbene (ADC) supporting ligands are described, with sequential beneficial effects of the ADCs on quantum yield and lifetime.
This Feature Article describes blue-phosphorescent organometallics supported by strong-field ligands, emphasizing our own group's efforts using isocyanides and acyclic diaminocarbenes to improve blue phosphorescence metrics.