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Three fluorous resorcin[4]arenes (1a-c) were synthesized and characterized for their potential application in separation science. A crystal structure of 1b confirmed its ring size and conformation. The fluorous resorcin[4]arenes are soluble in hybrid fluorous solvents. Preliminary studies demonstrated that 1a immobilized in a fluorous bulk membrane is capable of transporting tetramethylammonium cation from an aqueous source phase into an aqueous receiving phase.

Graphical abstract: Synthesis, characterization, and applications of fluorous resorcin[4]arenes

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