Photocatalytic decarboxylation of carboxylic acids or their redox active esters has become an important strategy in organic chemistry.
Surface engineered Ti6-oxo clusters anchoring Ir photosensitizers and Ni catalytic centers drive C–N bond formation via intramolecular electron transfer under blue light (430 nm), boosting activity, preventing Ni leaching, and achieving broad functional group tolerance.
This review describes the recent advancements in visible light-induced bromine radical enhanced hydrogen atom transfer (HAT) reactions in organic synthesis.
This review highlights recent advances in the development of triple catalysis methodology, including mechanistic information, catalyst design, green synthesis, and late-stage functionalization, and emphasizes the growing potential of triple catalytic systems in modern organic chemistry.
The strategic installation of the “magic methyl” group has become highly desirable for drug discovery. This review summarized the recent photochemical and electrochemical strategies in installing the methyl group.