Inherently chiral homo-heteracalixarenes: design and synthesis via an enantioselective intramolecular Sonogashira cross-coupling reaction

Y.-F. Jiang, Y. Zhang, S. Tong, J. Zhu and M.-X. Wang

Chem. Sci., 2026, 17, 1365
DOI: 10.1039/D5SC05923B

Synthesis, structures, and conformational characteristics of pillararene-based Diels–Alder adducts with embedded chiral centres

Haiying Wang, Tushar U. Thikekar, Jingfeng Xue, Yumei Zhu, Wangjian Fang, Jiong Xu, Andrew C.-H. Sue and Hongxia Zhao

Org. Chem. Front., 2023, 10, 2663
DOI: 10.1039/D3QO00399J

Gold(i)-catalysed hydroarylations of alkynes for the synthesis of inherently chiral calix[4]arenes

Gabriele Giovanardi, Gabriele Scarica, Valentina Pirovano, Andrea Secchi and Gianpiero Cera

Org. Biomol. Chem., 2023, 21, 4072
DOI: 10.1039/D3OB00603D

Enantioselective gold(i)-catalysed alkyne hydroarylations for inherently chiral calix[4]arenes

Mehri Goudarzi, Anuruddha Alagiyawanna, Andrea Serafino, Silvia Rizzato, Francesco Bertocchi, Francesca Terenziani, Stefano Santoro, Wenling Qin, Gianpiero Cera and Valentina Pirovano

Chem. Commun., 2025, 61, 16380
DOI: 10.1039/D5CC04405G

Calix[4]arene@MIL-101 as host@MOF for cage-in-cage pore space partitioning for enhanced CO2 separation and catalysis

Saied Shafiei Navid, Rahman Hosseinzadeh, Robert Oestreich, Soheil Abdpour, Thi Hai Yen Beglau and Christoph Janiak

J. Mater. Chem. A, 2025, 13, 3894
DOI: 10.1039/D4TA07357F

Enantioselective electrosynthesis of inherently chiral calix[4]arenes via a cobalt-catalyzed aryl C–H acyloxylation

Liming Zhang, Chen Yang, Xinhai Wang, Taixin Yang, Dandan Yang, Yingchao Dou and Jun-Long Niu

Green Chem., 2024, 26, 10232
DOI: 10.1039/D4GC02877E

Recent progress towards catalytic asymmetric construction of inherently chiral scaffolds

Kai Zhu, David R. Spring, Bing-Feng Shi and Fengzhi Zhang

Chem. Soc. Rev., 2025, 54, 10856
DOI: 10.1039/D5CS00235D

N-Heterocyclic carbene-catalyzed enantioselective (dynamic) kinetic resolution for the assembly of inherently chiral macrocycles

Zhipeng Li, Jingyang Zhang, Wanmeng Zhu, Tianyi Wang, Yefeng Tang and Jian Wang

Chem. Sci., 2025, 16, 11021
DOI: 10.1039/D5SC01773D

Inherently chiral nor-heteracalixarenes: design and synthesis via enantioselective intramolecular Suzuki–Miyaura reaction

Yi-Fan Jiang, Shuo Tong, Jieping Zhu and Mei-Xiang Wang

Chem. Sci., 2024, 15, 12517
DOI: 10.1039/D4SC03506B

C–H silylation and boronation enabled by alkyne insertion/vinyl to aryl 1,5-palladium migration

Zhendong Cheng, Weiwei Xu, Xuliang Tan, Zhengrui Zhou, Liwei Zhou, Yun Liang and Yuan Yang

Org. Chem. Front., 2025, 12, 1491
DOI: 10.1039/D4QO02224F

Advances in circularly polarized luminescence materials based on chiral macrocycles

Jia-Qi Wang, Xiao-Ni Han, Ying Han and Chuan-Feng Chen

Chem. Commun., 2023, 59, 13089
DOI: 10.1039/D3CC04187E

Enantioselective synthesis of calix[4]arenes with C–C axial and inherent chirality via palladium/chiral norbornene cooperative catalysis

Yiming You, Hongwei Cheng, Xiao Huang, Peng Wang, Hengjiang Cong, Hong-Gang Cheng and Qianghui Zhou

Chem. Sci., 2026
DOI: 10.1039/D5SC10040B

Accessing inherently chiral multifunctional structures by desymmetrization of a wide-rim calix[4]arene triamine

Ivan Alekseev, Ioann Shugaev, Alexander Gorbunov, Dmitry Cheshkov, Elena Tarasenko, Elena Kudryashova, Stanislav Bezzubov, Vladimir Kovalev and Ivan Vatsouro

Org. Chem. Front., 2026, 13, 851
DOI: 10.1039/D5QO01509J

Upper rim-bridged calixarenes

Pavel Lhoták

RSC Adv., 2024, 14, 23303
DOI: 10.1039/D4RA04663C

Synthesis and catalytic applications of NHC–metal complexes supported on p-tert-butylcalix[4]arene frameworks

Francisco J. Ruiz-Mendoza, Emmanuel Campos-Dominguez, Alejandro Álvarez-Hernández and Daniel Mendoza-Espinosa

New J. Chem., 2024, 48, 14021
DOI: 10.1039/D4NJ02392G

De novo synthesis of inherently chiral heteracalix[4]aromatics from enantioselective macrocyclization enabled by chiral phosphoric acid-catalyzed intramolecular SNAr reaction

Xing-Chi Li, Ying Cheng, Xu-Dong Wang, Shuo Tong and Mei-Xiang Wang

Chem. Sci., 2024, 15, 3610
DOI: 10.1039/D3SC06436K

Atropisomeric synthesis of multiple C–N or N–N axially chiral calix[4]arenes through cobalt-catalyzed multisite C-H activation/annulation

Taixin Yang, Yuanyuan Huang, Yingchao Dou, Yanbo Zhang, Baohe Yang, Dandan Yang and Jun-Long Niu

Chinese Chemical Letters, 2026, 112436
DOI: 10.1016/j.cclet.2026.112436

Asymmetric synthesis of saddle-shaped eight-membered azaheterocycles via (dynamic) kinetic resolution

Dekun Zhang, Jinmiao Zhou, Tianren Qin and Xiaoyu Yang

Chem Catalysis, 2024, 4, 100827
DOI: 10.1016/j.checat.2023.100827

Iridium-Catalyzed C–H Borylations: Regioselective Functionalizations of Calix[4]arene Macrocycles

Gabriele Giovanardi, Silvia Cattani, Davide Balestri, Andrea Secchi and Gianpiero Cera

J. Org. Chem., 2024, 89, 8486
DOI: 10.1021/acs.joc.4c00419

Simultaneous construction of inherent and axial chirality by cobalt-catalyzed enantioselective C-H activation of calix[4]arenes

Tong Li, Yanbo Zhang, Cong Du, Dandan Yang, Mao-Ping Song and Jun-Long Niu

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-52133-8

Catalytic enantioselective synthesis of inherently chiral calix[4]arenes via organocatalyzed aromatic amination enabled desymmetrization

Mengyao Yuan, Wansen Xie, Shaoze Yu, Tong Liu and Xiaoyu Yang

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-59221-3

Enantioselective Synthesis of Pillar[5]arenes by Dynamic Kinetic Resolution via Pd-Catalyzed Suzuki Cross-Coupling

Antoine Konter, Jaume Rostoll-Berenguer, Céline Besnard, Baptiste Leforestier and Clément Mazet

ACS Catal., 2025, 15, 2607
DOI: 10.1021/acscatal.4c07646

A Carbazole‐Centered Expanded Helicene Stabilized with Hexabenzocoronene (HBC) Units

Xin‐Yue Wang, Jinku Bai, Yun‐Jia Shen, Zhi‐Ao Li and Han‐Yuan Gong

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202417745

A Carbazole‐Centered Expanded Helicene Stabilized with Hexabenzocoronene (HBC) Units

Xin‐Yue Wang, Jinku Bai, Yun‐Jia Shen, Zhi‐Ao Li and Han‐Yuan Gong

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202417745

Vinyl-to-Acyl 1,5-Palladium Shift Enabled Amidation and Esterification of Aldehydes

Yaru Fang, Qifan Guan, Meiyu Chen, Shan Yuan and Xueliang Huang

J. Org. Chem., 2025, 90, 10139
DOI: 10.1021/acs.joc.5c01114

Asymmetric Synthesis of Inherently Chiral Tetraoxacalix[2]arene[2]pyridines via SNAr‐Based Cross‐Cyclotetramerization

Regina Ibragimova, Qiu‐Lin Lu, Mei‐Xiang Wang, Jieping Zhu and Shuo Tong

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401621

Inherently chiral resorcinarene cavitands through ionic catalyst-controlled cross-coupling

Mingfeng Li, Clement Kim Soon Ho, Ivan Keng Wee On, Vincent Gandon and Ye Zhu

Chem, 2024, 10, 3323
DOI: 10.1016/j.chempr.2024.06.012

Uniform Half‐Substituted Chiral Arylcycloparaphenylene: Synthesis, Crystal Structure, and Chiroptical Properties

Wen Zhang, Jinyi Wang, Xinyu Zhang, Bing Yuan, Pengwei Fang, Nan Yin and Pingwu Du

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202508017

Asymmetric Synthesis of Chiral Calix[4]arenes with Both Inherent and Axial Chirality via Cobalt‐Catalyzed Enantioselective Intermolecular C−H Annulation

Pu‐Fan Qian, Gang Zhou, Jia‐Heng Hu, Bing‐Jie Wang, Ao‐Lian Jiang, Tao Zhou, Wen‐Kui Yuan, Qi‐Jun Yao, Jia‐Hao Chen, Ke‐Xin Kong and Bing‐Feng Shi

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202412459

Desymmetric esterification catalysed by bifunctional chiral N-heterocyclic carbenes provides access to inherently chiral calix[4]arenes

Vojtěch Dočekal, Ladislav Lóška, Adam Kurčina, Ivana Císařová and Jan Veselý

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-59781-4

Synthesis of Imidazolium Cations Linked to Para-t-Butylcalix[4]arene Frameworks and Their Use as Synthons for Nickel-NHC Complexes Tethered to Calix[4]arenes

Michael J. Chetcuti, Haithem Naghmouchi, Abdelwaheb Hamdi and Lydia Karmazin

Molecules, 2023, 28, 5697
DOI: 10.3390/molecules28155697

A novel fused bi-macrocyclic host for sensitive detection of Cr2O72− based on enrichment effect

Ting-Ting Huang, Jin-Fa Chen, Juan Liu, Tai-Bao Wei, Hong Yao, Bingbing Shi and Qi Lin

Chinese Chemical Letters, 2024, 35, 109281
DOI: 10.1016/j.cclet.2023.109281

Copper-catalysed dynamic kinetic asymmetric C−O cross-coupling to access chiral aryl oxime ethers and diaryl ethers

Mei-Ru Zhang, Hao-Ran Wang, Hui-Mei Shan, Long-Long Xi, Chuan-Jun Lu, Xiao-Man Du, Che Sun, Li-Ping Xu and Ren-Rong Liu

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-57804-8

Organocatalytic Enantioselective Synthesis of Inherently Chiral Calix[4]arenes

Yu‐Kun Jiang, Yong‐Le Tian, Jia Feng, Huan Zhang, Lei Wang, Wei‐Ao Yang, Xing‐Dong Xu and Ren‐Rong Liu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202407752

Inherently Chiral Calix[4]Arene Derivatives: Concept and Enantioselective Synthesis

Jia Feng, Long‐Long Xi and Ren‐Rong Liu

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202502247

Enantioselective Synthesis of Inherently Chiral Quinoline‐Fused Calix[4]arenes via Palladium‐Catalyzed C−H Cycloimidoylation†

Yu Luo, Yougen Xu, Xilong Wang, Yuanhang Zhang, Jing Lin, Jinhuang Li, Xiaohan Zhang, Qiang Zhu and Shuang Luo

Chin. J. Chem., 2026, 44, 771
DOI: 10.1002/cjoc.70414

Inherently Chiral Macrocycles: Catalytic Asymmetric Synthesis and Properties

Shuo Tong

Acc. Chem. Res., 2025, 58, 3574
DOI: 10.1021/acs.accounts.5c00609

Enantioselective synthesis of inherently chiral calix[4]arenes via asymmetric C-H bromination of phenols

Mengyao Yuan, Wansen Xie and Xiaoyu Yang

Chinese Chemical Letters, 2025, 112157
DOI: 10.1016/j.cclet.2025.112157

Enantioselective Synthesis of Inherently Chiral Calix[4]arenes via Palladium-Catalyzed Asymmetric Intramolecular C–H Arylations

Yu-Zhen Zhang, Meng-Meng Xu, Xu-Ge Si, Jun-Li Hou and Quan Cai

J. Am. Chem. Soc., 2022, 144, 22858
DOI: 10.1021/jacs.2c10606

Uniform Half‐Substituted Chiral Arylcycloparaphenylene: Synthesis, Crystal Structure, and Chiroptical Properties

Wen Zhang, Jinyi Wang, Xinyu Zhang, Bing Yuan, Pengwei Fang, Nan Yin and Pingwu Du

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202508017

Synthesis and Chiroptical Property of Chiral Heteroatom‐Embedded Zigzag‐Type Hydrocarbon Belts

Zi‐Yue Jin, Mei‐Xiang Wang and Shuo Tong

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500755

A Rational Desymmetrization Approach for Enantioselective Synthesis of Inherently Chiral C1-Symmetric Metal–Organic Cages

Sha Yu, Jia-Yuan Shi, Huoqing Chen, Weibao Cheng, Zhe Zhang, Pingshan Wang and Qi Zhang

J. Am. Chem. Soc., 2026, 148, 7300
DOI: 10.1021/jacs.5c19421

Catalytic Enantioselective Synthesis of Inherently Chiral Molecules: Recent Advances

Mengyao Tang and Xiaoyu Yang

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300738

Alkyne Insertion Enabled Vinyl to Acyl 1,5‐Palladium Migration: Rapid Access to Substituted 5‐Membered‐Dihydrobenzofurans and Indolines

Mingruo Ding, Pengcheng Ou, Xuening Li, Yinghua Yu, Mengmeng Niu, Yongjian Yang, Yewei Huang, Zhi‐Xiang Wang and Xueliang Huang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202300703

Synthetic Strategies and Therapeutic Profile of Some 1,4-benzoxazine Derivatives: A Review

Nada Kheira Sebbar, Lhoussaine El Ghayati, Fouzia Hlimi, Soukaina El Haddad and El Mokhtar Essassi

COC, 2025, 30, 40
DOI: 10.2174/0113852728376259250404151339

Color-tunable fluorescence enabled by the host-guest complexes of cucurbituril and pyrene derivatives

Xianghao Li, Hanren Xu, Hongyu An, Zhen Qi, Yifan Lei, Qian Wang and DaHui Qu

Sci. Sin.-Chim, 2025, 55, 1547
DOI: 10.1360/SSC-2025-0076

Catalytic Enantioselective Synthesis of Inherently Chiral Macrocycles by Dynamic Kinetic Resolution

Qiu-Lin Lu, Xu-Dong Wang, Shuo Tong, Jieping Zhu and Mei-Xiang Wang

ACS Catal., 2024, 14, 5140
DOI: 10.1021/acscatal.4c00598

Circularly polarized luminescence of inherently chiral macrocycles

Yue Zhang, Mei-Xiang Wang and Shuo Tong

Sci. Sin.-Chim, 2026
DOI: 10.1360/SSC-2025-0290

Quaternary Carbon Editing Enabled by Sequential Palladium Migration

Hua Wu, Takuji Fujii, Qian Wang and Jieping Zhu

J. Am. Chem. Soc., 2024, 146, 21239
DOI: 10.1021/jacs.4c07706

Enantioselective Catalytic Synthesis of Inherently Chiral Calixarenes

Wenling Qin and Gianpiero Cera

The Chemical Record, 2025, 25
DOI: 10.1002/tcr.202400237

Calix[4]arenes rigidified by additional single-bond bridge: unusual reactivity as a result of internal strain

Pavel Lhoták

Supramolecular Chemistry, 2025, 36, 326
DOI: 10.1080/10610278.2025.2551677

Carbene-Catalyzed Intramolecular Cyclization to Access Inherently Chiral Saddle-Shaped Lactones: Achiral Bases Alternate Product Chirality

Liwen Wei, Yuhang Chen, Qinglong Zhou, Zhikang Wei, Ting Tu, Shichao Ren, Yonggui Robin Chi, Xinglong Zhang and Xing Yang

J. Am. Chem. Soc., 2025, 147, 30747
DOI: 10.1021/jacs.5c05380

Rapid Access to Fused Tetracyclic N-Heterocycles via Amino-to-Alkyl 1,5-Palladium Migration Coupled with Intramolecular C(sp3)–C(sp2) Coupling

Dianpeng Chen, Jianming Li, Xiuhua Zhang, Gongle Liu, Xin Wang, Yongwei Liu, Xuan Liu and Yingying Shan

Org. Lett., 2023, 25, 6272
DOI: 10.1021/acs.orglett.3c02034

Enantioselective Synthesis of Inherently Chiral Tetraazacalix[4]aromatics from a Chiral Phosphoric Acid-Catalyzed Intramolecular SNAr Reaction

Xing-Chi Li, Ying Cheng, Ruijun Jian, Shuo Tong, Yu Xia and Mei-Xiang Wang

Org. Lett., 2025, 27, 4603
DOI: 10.1021/acs.orglett.5c01289

The 10th macrocylic arene supramolecular chemistry symposium

Shuquan Zhang, Meijin Lin, Andrew C.H. Sue, Liping Cao, Feng Wang, Cheng Yang, Tao Tu, Feihe Huang and Leyong Wang

Chinese Chemical Letters, 2023, 34, 108754
DOI: 10.1016/j.cclet.2023.108754

Alkyne Insertion Enabled Vinyl to Acyl 1,5‐Palladium Migration: Rapid Access to Substituted 5‐Membered‐Dihydrobenzofurans and Indolines

Mingruo Ding, Pengcheng Ou, Xuening Li, Yinghua Yu, Mengmeng Niu, Yongjian Yang, Yewei Huang, Zhi‐Xiang Wang and Xueliang Huang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202300703

Enantioselective Synthesis of Inherently Chiral Calix[4]arenes via Catalytic Asymmetric Lower‐Rim Functionalization

Lei Peng, Yu Chang, Shujun Tong, Wenling Qin, Gianpiero Cera and Hailong Yan

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202518659

Desymmetrized Chiral Calix[4]arenes

Synfacts, 2023, 19, 0354
DOI: 10.1055/s-0042-1751850

Taming the Selective C−H Bond Activation through 1,5‐Palladium Migration

Yaru Fang, Mingruo Ding and Xueliang Huang

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301320

Organocatalytic Enantioselective Synthesis of Seven‐Membered Ring with Inherent Chirality

Jia‐Hao Li, Xiao‐Kai Li, Jia Feng, Wang Yao, Huan Zhang, Chuan‐Jun Lu and Ren‐Rong Liu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202319289

1,n-Metal Migrations Mediated by 3d Transition Metals

Ikuya Fujii and Ryo Shintani

Synthesis, 2026
DOI: 10.1055/a-2802-6100

Enantioselective synthesis of inherently chiral sulfur-containing calix[4]arenes via chiral sulfide catalyzed desymmetrizing aromatic sulfenylation

Xin-Yu Zhang, Deng Zhu, Ren-Fei Cao, Yu-Xuan Huo, Tong-Mei Ding and Zhi-Min Chen

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-54380-1

Palladium-Catalyzed Enantioselective Intramolecular C–H Arylation of o-Chloroaroylferrocenes Enabled by a Chiral Bidentate Ferrocenyl Phosphine-Pyridine Ligand

Shuai-Xi Li and Xiang-Ping Hu

Org. Lett., 2025, 27, 12969
DOI: 10.1021/acs.orglett.5c03857

Configurationally Stepping Confinement Achieved Tunable Chiral Near‐Infrared Luminescence Supramolecular Phenothiazine Organic Framework

Jie Yu, Jie Niu, Xiufang Xu and Yu Liu

Advanced Science, 2024, 11
DOI: 10.1002/advs.202408107

Research Progress and Application of Chiral Macrocycles in Supramolecular Catalysis

Shenglan Huang, Liupan Yang, Lili Wang and Huan Yao

Chinese Journal of Organic Chemistry, 2025, 45, 3624
DOI: 10.6023/cjoc202502040

Secondary Phosphine Oxide Grafted on an Inherently Chiral Calixarene: Synthesis, Resolution, Characterizations, and Catalytic Activity

Romain Membrat, Anne-Doriane Manick, Martin Tlusty, Lucien Lavaud, Gaëtan Herbette, Sara Chentouf, Jean-Valère Naubron, Laurent Giordano, Didier Nuel, Pavel Lhotak and Alexandre Martinez

J. Org. Chem., 2025, 90, 17380
DOI: 10.1021/acs.joc.5c02171

Organocatalytic Enantioselective Synthesis of Inherently Chiral Calix[4]arenes

Yu‐Kun Jiang, Yong‐Le Tian, Jia Feng, Huan Zhang, Lei Wang, Wei‐Ao Yang, Xing‐Dong Xu and Ren‐Rong Liu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202407752

Organocatalytic Enantioselective Synthesis of Seven‐Membered Ring with Inherent Chirality

Jia‐Hao Li, Xiao‐Kai Li, Jia Feng, Wang Yao, Huan Zhang, Chuan‐Jun Lu and Ren‐Rong Liu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202319289

Atroposelective Formal [2 + 5] Macrocyclization Synthesis for a Novel All-Hydrocarbon Cyclo[7] Meta-Benzene Macrocycle

Chao Gao, Hongchen Li, Jing Zhao, Lulu Bu, Mei Sun, Jingrui Wang, Gang Tao, Longde Wang, Li Li, Guilin Wen and Yunhu Hu

Molecules, 2024, 29, 3363
DOI: 10.3390/molecules29143363

Catalytic Asymmetric Synthesis of Inherently Chiral Eight‐Membered O‐Heterocycles through Cross‐[4+4] Cycloaddition of Quinone Methides

Da Xu, Guojie Zhou, Bangli Liu, Shiqi Jia, Yidong Liu and Hailong Yan

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202416873

Asymmetric Electrophilic Amination of Calix[4]arene Amines: Rapid Assembly of Inherently Chiral Diamine Frameworks

Xue Gong, Lu Zhang, Xuannan Liu, Mengjiao Shi, Minhuan Zhang, Tuanli Yao, Qiang Yan and Jiang Nan

Org. Lett., 2025, 27, 12991
DOI: 10.1021/acs.orglett.5c04041

Catalytic Enantioselective Synthesis of Inherently Chiral Calix[4]arenes via Sequential Povarov Reaction and Aromatizations

Shaoze Yu, Mengyao Yuan, Wansen Xie, Zidan Ye, Tianren Qin, Na Yu and Xiaoyu Yang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202410628

Catalytic Asymmetric Synthesis of Inherently Chiral Eight‐Membered O‐Heterocycles through Cross‐[4+4] Cycloaddition of Quinone Methides

Da Xu, Guojie Zhou, Bangli Liu, Shiqi Jia, Yidong Liu and Hailong Yan

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202416873

Synthesis and Optical Resolution of Inherently Chiral Fluorescent Calix[4]arenes and Their Application in Chiral Recognition

Fu-Ming Yang, Jun Luo, Yi-Chieh Chen and Wen-Sheng Chung

Synthesis, 2023, 55, 2786
DOI: 10.1055/s-0042-1751455

Synthesis of Inherently Chiral Homo-heteracalixaromatics

Yue Zhang, Ying Cheng, Dong-Dong Liang, Shuo Tong and Mei-Xiang Wang

Org. Lett., 2024, 26, 7961
DOI: 10.1021/acs.orglett.4c03021

Catalytic enantioselective synthesis of inherently chiral calix[4]arene-type scaffolds

Jia Feng, Long-Long Xi and Ren-Rong Liu

Trends in Chemistry, 2025, 7, 567
DOI: 10.1016/j.trechm.2025.06.007

Bifunctional Calixarene-Decorated BODIPY-based Nanoporous Organic Polymers for the Efficient Photodegradation of Aqueous Organic Pollutants

Xin Wang, Wuzi Zhao, Shiyuan Zhou, Guangfeng Liu, Danfeng Wang, Xiangming Li and Peiyang Gu

ACS Appl. Nano Mater., 2024, 7, 7465
DOI: 10.1021/acsanm.4c00143

Asymmetric Synthesis of Chiral Calix[4]arenes with Both Inherent and Axial Chirality via Cobalt‐Catalyzed Enantioselective Intermolecular C−H Annulation

Pu‐Fan Qian, Gang Zhou, Jia‐Heng Hu, Bing‐Jie Wang, Ao‐Lian Jiang, Tao Zhou, Wen‐Kui Yuan, Qi‐Jun Yao, Jia‐Hao Chen, Ke‐Xin Kong and Bing‐Feng Shi

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202412459

Access to Inherently and Centrally Chiral Calix[4]Arenes via Rhodium‐Catalyzed C─H Activation and Insertion into Diverse Olefins and Alkynes

Yunfei Yao, Fen Wang, Xiao‐Xi Li, Ruijie Mi and Xingwei Li

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202520283

Carbene-Catalyzed Esterification for the Synthesis of Inherently Chiral Saddle-Shaped Eight-Membered Lactones

Yao Chen, Xiaoqing Lai, Huan Gong, Hongzhi Zhuang, Yongchang Hu, Yang Xiao, Jianing An, Jianfeng Xu and Xingkuan Chen

Org. Lett., 2025, 27, 12343
DOI: 10.1021/acs.orglett.5c03940

Catalytic Enantioselective Synthesis of Inherently Chiral Calix[4]arenes via Sequential Povarov Reaction and Aromatizations

Shaoze Yu, Mengyao Yuan, Wansen Xie, Zidan Ye, Tianren Qin, Na Yu and Xiaoyu Yang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202410628

C4-Symmetric Inherently Chiral Macrocycles from Organocatalytic Enantioselective Desymmetrization of Resorcin[4]arenes

Hui Han, Xin-Ge Wang, Shuo Tong, Jieping Zhu and Mei-Xiang Wang

ACS Catal., 2025, 15, 6018
DOI: 10.1021/acscatal.5c00340

Enantioselective Synthesis of Inherently Chiral Calix[4]arenes via Catalytic Asymmetric Lower‐Rim Functionalization

Lei Peng, Yu Chang, Shujun Tong, Wenling Qin, Gianpiero Cera and Hailong Yan

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202518659

Access to Inherently and Centrally Chiral Calix[4]Arenes via Rhodium‐Catalyzed C─H Activation and Insertion into Diverse Olefins and Alkynes

Yunfei Yao, Fen Wang, Xiao‐Xi Li, Ruijie Mi and Xingwei Li

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202520283

Kinetic resolution of inherently chiral tribenzocyclooctanones via enantioselective condensation with phenylhydrazines

Yi Ma, Yu-Zhen Zhang, Qi-Tao Lu, Ming-Shu Li and Quan Cai

Chinese Chemical Letters, 2026, 112515
DOI: 10.1016/j.cclet.2026.112515