Improving the high-voltage high-rate performance of a P2 layered oxide cathode by a dual-ion doping strategy for sodium-ion batteries

Huan Xu, Chengde Xie, Huige Chen, Tianyi Song, Yuanqi Lan, Nanzhong Wu, Xiaolong Zhou, Pinit Kidkhunthod, Lei Kang, Xiaoqi Han, Wenjiao Yao and Yongbing Tang

J. Mater. Chem. A, 2024, 12, 21114
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Delineating the impact of Ti/Mg substitution in P2-type Na2/3Ni1/3Mn2/3O2 with an advanced electrolyte for sodium-ion batteries

Joe Darga and Arumugam Manthiram

J. Mater. Chem. A, 2025, 13, 29183
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Mitigating the P2–O2 phase transition-induced structural instability in P2-Nax[Ni1/3Mn2/3]O2 Na-ion battery cathodes: to dope or not to dope, that is the question

Mohamed H. Hassan, Jintao Fu, Jiaxin Liu and Eric Detsi

Mater. Horiz., 2025, 12, 7636
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A high-performance Na-storage cathode enabled by layered P2-type KxMnO2 with enlarged interlayer spacing and fast diffusion channels for sodium-ion batteries

Ningbo Liu, Xiaoying Zhao, Bin Qin, Dongdong Zhao, Huanhuan Dong, Mande Qiu and Liubin Wang

J. Mater. Chem. A, 2022, 10, 25168
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A review of Ni-based layered oxide cathode materials for alkali-ion batteries

Lei Wang, Jiaqing Wang, Yifei Lu, Suqiao Fang, Chao Yang, Xingqiao Wu, Yao Xiao, Yong Wang, Shulei Chou and Shuangqiang Chen

Chem. Soc. Rev., 2025, 54, 4419
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Boosting the capacity of Mg-stabilized Na0.67Ni0.27Mg0.06Mn0.66O2 cathodes via particle size control in an emulsion-based synthesis route

Saúl Rubio, Eva M. Pérez-Soriano, Cristina Arévalo, Xiaoqiong Du, Xuyun Guo, Francisco J. Garcia-Garcia, Isabel Montealegre-Meléndez, Ana M. Beltrán, Valeria Nicolosi and Juan G. Lozano

J. Mater. Chem. A, 2025, 13, 25904
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First-Principles Insights on Solid-State Phase Transitions in P2-NaxMnO2-Based High Energy Cathode during Na-Ion Battery Operations

Aniello Langella, Arianna Massaro, Ana B. Muñoz-García and Michele Pavone

Chem. Mater., 2024, 36, 2370
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Recent Advances on F-Doped Layered Transition Metal Oxides for Sodium Ion Batteries

Hao Wang, Lifeng Zhou, Zhenyu Cheng, Liying Liu, Yisong Wang and Tao Du

Molecules, 2023, 28, 8065
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Enhancing structural flexibility in P2-type Ni-Mn-based Na-layered cathodes for high power-capability and fast charging/discharging performance

Bonyoung Ku, Jinho Ahn, Hoseok Lee, Hobin Ahn, Jihoe Lee, Hyunji Kweon, Myungeun Choi, Hun-Gi Jung, Kyuwook Ihm, Eunji Sim, Jung-Keun Yoo and Jongsoon Kim

Energy Storage Materials, 2025, 74, 103930
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Structure, Electrochemical, and Transport Properties of Li- and F-Modified P2-Na2/3Ni1/3Mn2/3O2 Cathode Materials for Na-Ion Batteries

Xinglong Chen, Wenyue Guo, Rui Li, Peng Du, Xiaowen Zhan and Shan Gao

Coatings, 2023, 13, 626
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Developing high-performance sodium-ion battery cathode materials through regulating the Ni/Fe ratio in Na0.67Ni Fe0.52-Mn0.48O2

Yong Liang, Wanmin Liu, Hu Wu, Zexun Tang and Lv Xu

Journal of Power Sources, 2024, 617, 235159
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Ultra large ion substitute resists Jahn-Teller effects towards high-performance Mn-based P2-Na0.67Ni0.33Mn0.67O2 cathode

Xiang Ding, Caijiang Jiang, Piluan Li, Yong Fan, Zhibin Cheng, Haonan Li, Liangwei Liu, Yi Xiao, Fang Chen and Lili Han

Nano Today, 2026, 66, 102925
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Transition Metal Vacancy in Layered Cathode Materials for Sodium‐Ion Batteries

Xun‐Lu Li, Cui Ma and Yong‐Ning Zhou

Chemistry A European J, 2023, 29
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Na-deficient P2-type layered oxide cathodes for practical sodium-ion batteries

Yu Huang, Weixiong Zeng, Kui Li and Xiaobo Zhu

Microstructures, 2024, 4
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Recent Advances in Layered Metal‐Oxide Cathodes for Application in Potassium‐Ion Batteries

Muthu Gnana Theresa Nathan, Hakgyoon Yu, Guk‐Tae Kim, Jin‐Hee Kim, Jung Sang Cho, Jeha Kim and Jae‐Kwang Kim

Advanced Science, 2022, 9
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Dielectric polarization in MgFe2O4 coating and bulk doping to enhance high-voltage cycling stability of Na2/3Ni1/3Mn2/3O2 cathode material

Xiaoqian Xu, Yizhen Huang, Dan Li, Qichang Pan, Sijiang Hu, Yahao Li, Hongqiang Wang, Youguo Huang, Fenghua Zheng and Qingyu Li

Journal of Energy Chemistry, 2023, 81, 200
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Mainstream Optimization Strategies for Cathode Materials of Sodium‐Ion Batteries

Huan Xu, Qi Yan, Wenjiao Yao, Chun-Sing Lee and Yongbing Tang

Small Structures, 2022, 3
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Polypyrrole-coated sodium manganate microspheres cathode for superior performance Sodium-ion batteries

Pengju Zhang, Junying Weng, Zhengkun Lu, Longchen Li, Bingyang Ji, Minghui Ding, Yiran Sun, Wenyong Yuan, Pengfei Zhou and Hailin Cong

Journal of Colloid and Interface Science, 2024, 674, 428
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Structural reinforcement through high-valence Nb5+ doping to boost the cycling stability of P2–Na0.65Mn0.75Ni0.25O2 cathode materials

Yunqin Yang, Minyi Liao, Fanjun Tang, Donglou Ren and Tianquan Liang

Materials Today Chemistry, 2026, 52, 103353
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Dual-ion regulation of coordination chemistry for high-voltage stabilized P2-type cathode

Jiangnan Huang, Jinqiang Gao, Ningyun Hong, Baichao Zhang, Haoji Wang, Fangjun Zhu, Lianshan Ni, Guoqiang Zou, Hongshuai Hou, Hongyi Chen, Wentao Deng and Xiaobo Ji

Nano Energy, 2024, 126, 109676
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Fluorine Substitution Promotes Air‐Stability of P'2‐Type Layered Cathodes for Sodium‐Ion Batteries

Xuchun Chen, Siyu Zheng, Pei Liu, Zhiqin Sun, Kunjie Zhu, Haixia Li, Yongchang Liu and Lifang Jiao

Small, 2023, 19
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Heteroatom-Substituted P2–Na2/3Ni1/4Mg1/12Mn2/3O2 Cathode with {010} Exposing Facets Boost Anionic Activity and High-Rate Performance for Na-Ion Batteries

Liuyun Zhang, Chaohong Guan, Yangyang Xie, Huangxu Li, Aonan Wang, Shilei Chang, Jingqiang Zheng, Yanqing Lai and Zhian Zhang

ACS Appl. Mater. Interfaces, 2022, 14, 18313
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Synthesis and electrochemical performance of Al-doped P2-type Na0.67Co0.2−Mn0.8Al O2 for sodium-ion battery cathodes

Gongqin Yan, Yuxin Hong, Yanchao Qi, Xianghui Fu, Chunbo Lan and Zhijie Fang

Journal of Electroanalytical Chemistry, 2026, 1003, 119764
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Advancements in the Realm of Structural Engineering for Sodium‐Ion Batteries via Elemental Doping: A Focus on P2‐Phase Nickel–Manganese Layered Oxides

Weipeng Li, Haihan Zhang, Liang Xie, Zhiyang Fan, Taifan Yang, Weibo Hua, Kang Yang, Chengyong Shu, Yongliang Ma, Yuping Wu and Wei Tang

Battery Energy, 2025, 4
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Probing the account of phase transition upon electrochemical cycling of the P2-Na0.67Ni0.15Fe0.2Mn0.65O2 layered oxide cathodes for sodium-ion batteries

Shiyou Li, Xiaoqi Fan, Shimin Wang, Mengya Wang, Yifan Tong, Junfei Zhou, Xin Li, Dongni Zhao and Ningshuang Zhang

Mater. Res. Express, 2024, 11, 035504
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Structural evolution mechanisms and design strategies of layered cathodes for sodium-ion batteries

Li Zhang, Jun Wang, Wenhai Ji, Nuria Tapia-Ruiz, Martin Winter and Jie Li

Next Energy, 2025, 7, 100241
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In‐Plane BO3 Configuration in P2 Layered Oxide Enables Outstanding Long Cycle Performance for Sodium Ion Batteries

Xuan Wang, Xiping Dong, Xiaochen Feng, Qinhao Shi, Jing Wang, Xuemin Yin, Jiujun Zhang and Yufeng Zhao

Small Methods, 2023, 7
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Mitigating Jahn–Teller Effect in Layered Cathode Material Via Interstitial Doping for High‐Performance Sodium‐Ion Batteries

Hui Fang, Haocheng Ji, Jingjun Zhai, Chaoqi Wang, Chen Zhu, Guojie Chen, Mihai Chu, Taolve Zhang, Zhewen Ma, Wenguang Zhao, Wenhai Ji and Yinguo Xiao

Small, 2023, 19
DOI: 10.1002/smll.202301360

Impact of Ti and Zn Dual‐Substitution in P2 Type Na2/3Ni1/3Mn2/3O2 on Ni–Mn and Na‐Vacancy Ordering and Electrochemical Properties

Kei Kubota, Takuya Asari and Shinichi Komaba

Advanced Materials, 2023, 35
DOI: 10.1002/adma.202300714

Synergistic Rigidity–Flexibility Engineering of O3‐Type Sodium Layered Oxide Cathodes Through Site‐Specific High‐Entropy Regulation

Weidong Xu, Chen Cheng, Lei Wang, Tong Chen, Zheng Zhou, Tianran Yan, Shiqi Shen, Pan Zeng and Liang Zhang

Advanced Energy Materials, 2026, 16
DOI: 10.1002/aenm.202504557

Achieving structurally stable O3-type layered oxide cathodes through site-specific cation-anion co-substitution for sodium-ion batteries

Yihao Shen, Chen Cheng, Xiao Xia, Lei Wang, Xi Zhou, Pan Zeng, Jianrong Zeng and Liang Zhang

Journal of Energy Chemistry, 2024, 93, 411
DOI: 10.1016/j.jechem.2024.02.040

Substitution and electrochemistry in layered oxide cathode materials for sodium-ion batteries

Liangtao Yang, Xingxing Yin, Jun Wang, Yanan Sun, Yongchun Li, Zhenggang Zhang, Zhongqing Liu, Si-Min Huang, Philipp Adelhelm and Dong Zhou

Nat Rev Chem, 2026, 10, 196
DOI: 10.1038/s41570-025-00795-3

Ca/Mg dual-doping P2-type Na0.67Ni0.17Co0.17Mn0.66O2 cathode material for sodium ion batteries

Guanqiao Su, Haoqing Zheng, Hong Chen and Shuo Bao

Materials Letters, 2023, 331, 133425
DOI: 10.1016/j.matlet.2022.133425

Ni/Mn stoichiometry engineering in P2-type oxide: Disrupting Na+/vacancy ordering and uncovering ambient-to-cryogenic electrochemical performance reversal

Xuan Wang, Lu Yue, Yantong Lu, Yuxi Gu, Zhengjie Yu, Mingxuan Liu, Yufeng Zhao and Jiujun Zhang

Chemical Engineering Journal, 2025, 525, 169733
DOI: 10.1016/j.cej.2025.169733

Mitigation of ordering constraints in P2-Na0.67Ni0.33Mn0.67O2 cathode via F doping for improved Na-ion storage

Ziyang Song, Di Chen, Hui Ying Yang, Caiyan Yu and Ying Bai

Applied Physics Letters, 2025, 127
DOI: 10.1063/5.0288456

Enhancing capacity, structural stability, and sodium diffusivity by the double role of magnesium in biphasic layered manganese iron oxide cathodes

R. Klee, S. Rubio, P. Lavela and J.L. Tirado

Journal of Alloys and Compounds, 2025, 1020, 179385
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Ultrafast Organic Emulsion‐Based Synthesis of High‐Performance Cathode Materials for Rechargeable Batteries

Francisco J. Garcia‐Garcia, Saúl Rubio, Xiaoqiong Du, Xuyun Guo, Julio E. de la Rosa‐Melian, Eva M. Pérez‐Soriano, Cristina Arévalo, Isabel Montealegre‐Meléndez, Ana M. Beltrán, Valeria Nicolosi and Juan G. Lozano

Batteries & Supercaps, 2025, 8
DOI: 10.1002/batt.202500213

Accelerating electrochemical CO2 reduction via ionic liquid cation enhanced stabilization of CO2 radical anion

Hui Yu, Wenru Zhao, Jiansong Wang, Wei Wang, Liu-Liu Shen, Gui-Rong Zhang and Donghai Mei

Applied Catalysis B: Environment and Energy, 2026, 382, 126006
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High-Entropy Approach vs. Traditional Doping Strategy for Layered Oxide Cathodes in Alkali-Metal-Ion Batteries: A Comparative Study

Yanjiao Ma, Han Du, Siyuan Zheng, Zihao Zhou, Hehe Zhang, Yuan Ma, Stefano Passerini and Yuping Wu

Energy Storage Materials, 2025, 79, 104295
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Slope-structure design towards high-stability P2-Na0.67MnO2 cathode

Xiang Ding, Caijiang Jiang, Yong Fan, Yibing Yang, Liangwei Liu, Yi Xiao and Lili Han

Chemical Engineering Journal, 2024, 499, 156294
DOI: 10.1016/j.cej.2024.156294

Low-cost earth-abundant P2-type cathodes based on manganese through double (Al/F and Mg/F) and triple (Al/Mg/F) co-doping enabling stabilized interlayer repulsion and fast kinetic for Na-ion batteries

Bo Song, Yuhao Xie, Lingzhi Tu, Ruqin Ma, Weilin Huang, Yong Yang, Zhanhua Wei and Gregorio F. Ortiz

Journal of Power Sources, 2026, 666, 239144
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Synergistic Cu Doping and ZnO Encapsulation: Dual-Functional Modification for Enhanced Electrochemical Performance in P2-Type Sodium-Ion Battery Cathodes

Zi-han Ma, Qin-xin Wan, Jia-xuan He, Yu Duan, Shuo Zhang, Ying-ying Huang, Shuo Bao and Jin-lin Lu

J. of Materi Eng and Perform, 2026, 35, 10934
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Stabilizing P2-phase in layered oxides via electronic modulation for high-performance sodium-ion batteries

Zhipeng Xu, Yulei Ren, Zhihong Xiao, Xiangze Kong, Zhongyu Sun, Qingyin Zhang and Zhiqiang Shi

Journal of Energy Chemistry, 2025, 111, 877
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Non-metal doping engineering in sodium layered oxide cathodes

Li Li, Guang-Zhen Zhao, Meng-Ying Li, Yan-Jiang Li, Liang-Xin Zhu, Li-Tao Zhao, Guang Zhu and Yao Xiao

Energy Storage Materials, 2026, 84, 104876
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Lattice Engineered P2-Type Cathodes with Enhanced Phase-Transition Reversibility and Diffusion Kinetics for High-Power Na-Ion Batteries

Mingyi Zhao, Haifeng Yu, Muslum Demir, Qilin Cheng, Ling Chen, Haijiao Zhang and Hao Jiang

ACS Sustainable Chem. Eng., 2026, 14, 1275
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Enhanced High-Voltage Stability in P2–Na0.66Ni0.33Mn0.66–xRuxO2 Cathodes via Ru-Doping for Improved Electrochemical Performance

Shreya Jose and K. Ramesha

Energy Fuels, 2025, 39, 4059
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High-Voltage Sodium Layered Cathode Stabilized by Bulk Complex-Composition Doping to Surface Phosphate Coating Design

Mubao Gu, Shiqi Chen, Junling Xu, Xiaoyan Shi, Lianyi Shao and Zhipeng Sun

ACS Appl. Mater. Interfaces, 2025, 17, 22546
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High‐Voltage Sodium‐Ion Batteries: Challenges and Design Strategies

Yaqin Wu, Binbin Wang, Zixiang Luo, Zixing Hou, Baolei Xu, Liangjun Zhou and Weifeng Wei

Adv Funct Materials, 2025, 35
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Toward the High‐Voltage Stability of Layered Oxide Cathodes for Sodium‐Ion Batteries: Challenges, Progress, and Perspectives

Zhigao Chen, Yuyu Deng, Ji Kong, Weibin Fu, Chenyang Liu, Ting Jin and Lifang Jiao

Advanced Materials, 2024, 36
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Improving rate capability and cycling stability of P2-type sodium-ion layered cathode by synergistic effect of K/Ti co-doping strategy

Shihong Guo, Huawei Han, Shuai Guo, Ningyun Hong, Jiangtao Fan, Zhen Long, Shifu Xiong and Xiaoqing Qiu

Ionics, 2023, 29, 2735
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Atomistic Insights into Solid-State Phase Transition Mechanisms of P2-Type Layered Mn Oxides for High-Energy Na-Ion Battery Cathodes

Aniello Langella, Arianna Massaro, Ana B. Muñoz-García and Michele Pavone

ACS Energy Lett., 2025, 10, 1089
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Review on modification strategy of layered transition metal oxide for sodium ion battery cathode material

Mingjun Xiao and Huizhen Sun

Journal of Energy Storage, 2025, 114, 115824
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A Ni/Co-free high-entropy layered cathode with suppressed phase transition and near-zero strain for high-voltage sodium-ion batteries

Ziqing Wang, Lei Fang, Xiaoguang Fu, Shengfeng Zhang, Huabin Kong, Hongwei Chen and Fang Fu

Chemical Engineering Journal, 2024, 480, 148130
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Disparities in aging mechanisms between sodium-ion and lithium-ion batteries: Implications for predictive modeling

Xinya Tang, Zebo Gu, Jun Cai, Kun Huang, Siyao Zhang, Hao Feng, Hao Chen, Guorong Liu and Jun Chen

Journal of Power Sources, 2026, 677, 239933
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New insights to build Na+/vacancy disordering for high-performance P2-type layered oxide cathodes

Hu-Rong Yao, Wei-Jun Lv, Xin-Guang Yuan, Yu-Jie Guo, Lituo Zheng, Xin-An Yang, Jiaxin Li, Yiyin Huang, Zhigao Huang, Peng-Fei Wang and Yu-Guo Guo

Nano Energy, 2022, 97, 107207
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Interlayer Superstructure Stabilized Oxygen-Redox Ni- and Co-Free Cathodes

Fanjie Xia, Weihao Zeng, Haoyang Peng, Congli Sun, Zhuo Chen, Zhaopei Liu, Mouad Dahbi, Shichun Mu, Jones Alami, Liqiang Mai and Jinsong Wu

J. Am. Chem. Soc., 2026, 148, 13277
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Sustainable Enhanced Sodium-Ion Storage at Subzero Temperature with LiF Integration

Heramba Venkata Sai Rama Murthy Koppisetti, Harsha Rao, Hari Vignesh Ramasamy, Harish Reddy Inta, Sayan Das, Soohwan Kim, Yizhi Zhang, Haiyan Wang, Venkataramanan Mahalingam and Vilas G. Pol

ACS Appl. Mater. Interfaces, 2023, 15, 32291
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Enhancing the structural stability and strength of P2-type layered oxide sodium ion battery cathodes by Zn/F dual-site doping

Dawei Chen, Bin He, Shuai Jiang, Xilong Wang, Jie Song, Hao Chen, Dan Xiao, Qian Zhao, Yan Meng and Yujue Wang

Chemical Engineering Journal, 2025, 510, 161676
DOI: 10.1016/j.cej.2025.161676

Phase tuning of P2/O3-type layered oxide cathode for sodium ion batteries via a simple Li/F co-doping route

Zhengbo Liu, Chaojin Zhou, Jun Liu, Lichun Yang, Jiangwen Liu and Min Zhu

Chemical Engineering Journal, 2022, 431, 134273
DOI: 10.1016/j.cej.2021.134273

Ionic-Potential-Guided Fluoride Engineering of Reversible Mn-Based Cathodes for Sodium-Ion Batteries

Shunli He, Robert Scott Young, Xing Shen, Miao Han, Yaoguang Song, Wenyi Dong, Yiming Zhang, Jili Yue, Jingfeng Wang, Rhodri Jervis, Junmei Zhao and Alexander J. E. Rettie

ACS Nano, 2025, 19, 34890
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Enhanced electrochemical oxidation of 5-hydroxymethylfurfural over tailored nickel nanoparticle assembly

Jiansong Wang, Wenru Zhao, Hui Yu, Wei Wang, Yipu Xu, Liu-Liu Shen, Gui-Rong Zhang and Donghai Mei

Applied Catalysis B: Environment and Energy, 2024, 353, 124086
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Multi‐Element Doping Regulation of the Disordered Phase Transition and Multi‐Step Phase Transition Suppression Effect in O3‐Type Sodium‐Ion Batteries

Zongchang Li, Wen Xi, Zhuo Jiang, Youfang Zhang, Rui Wang, Yansheng Gong, Huanwen Wang and Jun Jin

Small, 2025, 21
DOI: 10.1002/smll.202506854

Review on layered oxide cathodes for sodium‐ion batteries: Degradation mechanisms, modification strategies, and applications

Yong Li, Guoliang Liu, Jiangxuan Che, Liping Chen, Xuan Wang, Guangming Wang, Lanlan Lei, Jie Hou, Shuyue Li, Juan Wang, Yunhua Xu and Yufeng Zhao

Interdisciplinary Materials, 2025, 4, 24
DOI: 10.1002/idm2.12213

Trace doping realizing superior electrochemical performance in P2-type Na0.50Li0.08Mn0.60Co0.16Ni0.16O2 cathode for sodium-ion batteries

Hongying Hou, Jinxu Qiu, Bao Li, Liang Wang, Zhuangzhuang Zhang, Mengmin Jia, Xiaobing Lai, Mingming Han, Pengyao Yan, Dai-Huo Liu, Dongmei Dai and Bao Wang

Chinese Chemical Letters, 2023, 34, 108810
DOI: 10.1016/j.cclet.2023.108810