Carboxonium derivatives based on closo-dodecaborate anions [1,2-B12H10O2CR]−: synthesis and molecular orbital analysis

Anastasia V. Kolbunova, Ilya N. Klyukin, Alexander S. Novikov, Alexey V. Nelyubin, Andrey P. Zhdanov, Alexey S. Kubasov, Nikita A. Selivanov, Alexander Yu. Bykov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

New J. Chem., 2024, 48, 8361
DOI: 10.1039/D4NJ01048E

Charge-compensatednido-carborane derivatives in the synthesis of iron(ii) bis(dicarbollide) complexes

Marina Yu. Stogniy, Sergey A. Anufriev, Ekaterina V. Bogdanova, Nadezhda A. Gorodetskaya, Alexei A. Anisimov, Kyrill Yu. Suponitsky, Ivan D. Grishin and Igor B. Sivaev

Dalton Trans., 2024, 53, 3363
DOI: 10.1039/D3DT03549B

Theoretical Insight on the Formation Mechanism of a Trisubstituted Derivative of Closo-Decaborate Anion [B10H7O2CCH3(NCCH3)]0

Ilya N. Klyukin, Anastasia V. Kolbunova, Alexander S. Novikov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Inorganics, 2023, 11, 201
DOI: 10.3390/inorganics11050201

Synthesis of Triethylammonium Salts of Amidine Derivatives of closo-Borate Anions [B10H10]2– and [B12H12]2– and Study of Their Cytotoxic Properties

M. N. Ryabchikova, A. V. Nelyubin, I. N. Klyukin, N. Yu. Karpechenko, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2024, 69, 1353
DOI: 10.1134/S0036023624601892

Nucleophilic Addition of Stabilized Phosphorus Ylides to Closo-Decaborate Nitrilium Salts: A Synthetic Route to Boron Cluster-Functionalized Iminoacyl Phosphoranes and Their Application in Potentiometric Sensing

Vera V. Voinova, Eugeniy S. Turyshev, Sergey S. Novikov, Nikita A. Selivanov, Alexander Yu. Bykov, Ilya N. Klyukin, Andrey P. Zhdanov, Mikhail S. Grigoriev, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Molecules, 2026, 31, 231
DOI: 10.3390/molecules31020231

Study of Protonation of Ethyloxy Derivative of closo-Decaborate anion [B10H9OC2H5]2–

I. N. Klyukin, A. V. Kolbunova, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2022, 67, 1567
DOI: 10.1134/S003602362260085X

Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)

A. V. Nelyubin, I. N. Klyukin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Žurnal neorganičeskoj himii, 2023, 68, 768
DOI: 10.31857/S0044457X22602310

Decaborane: From Alfred Stock and Rocket Fuel Projects to Nowadays

Igor B. Sivaev

Molecules, 2023, 28, 6287
DOI: 10.3390/molecules28176287

New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et

A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2024, 69, 1469
DOI: 10.1134/S0036023624601910

Nucleophilic Addition of Polyfunctional Amines to Acetonitrile Derivatives of closo-Borate Anions [BnHn – 1NCCH3]– (n = 10, 12)

A. V. Nelyubin, M. S. Sokolov, N. A. Selivanov, A. Yu. Bykov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2022, 67, 1751
DOI: 10.1134/S003602362260109X

Synthesis and Structures of Lead(II) Complexes with Substituted Derivatives of the Closo-Decaborate Anion with a Pendant N3 Group

Evgenii Yu. Matveev, Olga S. Dontsova, Varvara V. Avdeeva, Alexey S. Kubasov, Andrey P. Zhdanov, Svetlana E. Nikiforova, Lyudmila V. Goeva, Konstantin Yu. Zhizhin, Elena A. Malinina and Nikolay T. Kuznetsov

Molecules, 2023, 28, 8073
DOI: 10.3390/molecules28248073

Synthesis of Disubstituted Carboxonium Derivatives of Closo-Decaborate Anion [2,6-B10H8O2CC6H5]−: Theoretical and Experimental Study

Ilya N. Klyukin, Anastasia V. Kolbunova, Alexander S. Novikov, Alexey V. Nelyubin, Andrey P. Zhdanov, Alexey S. Kubasov, Nikita A. Selivanov, Alexander Yu. Bykov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Molecules, 2023, 28, 1757
DOI: 10.3390/molecules28041757

Mechanochemical Synthesis of closo-Decaborate Anion Derivatives with Pendant Functional Groups

E. Yu. Matveev, A. S. Kubasov, A. I. Nichugovskii, V. V. Avdeeva, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2023, 68, 644
DOI: 10.1134/S0036023623600545

Mechanochemical Synthesis of closo-Decaborate Anion Derivatives with Pendant Functional Groups

E. Yu. Matveev, A. S. Kubasov, A. I. Nichugovskii, V. V. Avdeeva, K. Yu. Zhizhin and N. T. Kuznetsov

Žurnal neorganičeskoj himii, 2023, 68, 724
DOI: 10.31857/S0044457X22602243

Intramolecular proton-hydride activation using the example of cobalt bis(dicarbollide) derivative [8-Et(HO)C HN-3,3′-Co(1,2-C2B9H10)(1′,2′-C2B9H11)]

Ekaterina V. Bogdanova, Marina Yu. Stogniy, Sergey A. Anufriev, Kyrill Yu. Suponitsky, Igor B. Sivaev and Vladimir I. Bregadze

Inorganica Chimica Acta, 2025, 578, 122529
DOI: 10.1016/j.ica.2024.122529

Ring-Closing and Ring-Opening of closo-B12-Fused Carboxonium Ions: PIDA-Mediated Synthesis and Reactivity toward Neutral O-Nucleophiles

Anastasia V. Kolbunova, Ilya N. Klyukin, Alexey V. Nelyubin, Alexey S. Kubasov, Nikita A. Selivanov, Alexander Yu. Bykov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Organometallics, 2025, 44, 2882
DOI: 10.1021/acs.organomet.5c00398

Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)

A. V. Nelyubin, I. N. Klyukvin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2023, 68, 684
DOI: 10.1134/S003602362360048X

Theoretical Investigation of Bond Dissociation Energies of exo-Polyhedral B–H and B–F Bonds of closo-Borate Anions [BnHn−1X]2− (n = 6, 10, 12; X = H, F)

Ilya N. Klyukin, Anastasia V. Kolbunova, Alexander S. Novikov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Computation, 2025, 13, 28
DOI: 10.3390/computation13020028

Development of Approaches for Obtaining Fluorine-Containing Derivatives of Boronated Amidines Based on the closo-Dodecaborate Anion

M. N. Ryabchikova, N. K. Neumolotov, A. V. Nelyubin, N. A. Selivanov, I. N. Klyukin, A. Yu. Bykov, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2023, 68, 1923
DOI: 10.1134/S0036023623603252

Study of Hydrophilic/Hydrophobic Properties of Borylated Iminols [BnHn – 1NHC(OH)R]– (n = 10, 12)

M. N. Ryabchikova, A. V. Nelyubin, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Žurnal neorganičeskoj himii, 2023, 68, 1373
DOI: 10.31857/S0044457X23600895

Theoretical Insight into B–C Chemical Bonding in Closo-Borate [BnHn−1CH3]2− (n = 6, 10, 12) and Monocarborane [CBnHnCH3]− (n = 5, 9, 11) Anions

Ilya N. Klyukin, Anastasia V. Kolbunova, Alexander S. Novikov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Inorganics, 2022, 10, 186
DOI: 10.3390/inorganics10110186

Synthesis of New Boron-Containing Ligands Based on the Nucleophilic Addition of 1,10-Phenanthroline-5-Amine to Nitrile Derivatives of [2-B10H9NCR]– (R = Me, Et, nPr)

A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2024, 69, 818
DOI: 10.1134/S0036023624600758

Basic Hydrolysis of Glycine Ester Derivatives Based on the closo-Dodecaborate Anion: From Thermodynamic to Kinetic Control

A. Sychyov, M. N. Ryabchikova, A. V. Nelyubin, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2025
DOI: 10.1134/S0036023625603976

A new ligand based on the closo-dodecaborate anion (Bu4N)[B12H11NH(CH2COOH)2]: Synthesis, structure, and its Eu(III) coordination compounds

Margarita N. Ryabchikova, Alexey V. Nelyubin, Grigorii A. Buzanov, Alexey S. Kubasov, Ilya N. Klyukin, Andrey P. Zhdanov, Konstantin Yu. Zhizhin, Yulia G. Gorbunova and Nikolay T. Kuznetsov

Polyhedron, 2025, 272, 117462
DOI: 10.1016/j.poly.2025.117462

Nucleophilic Addition Reactions to 10-Acetonitrilium Derivative of nido-Carborane and Intramolecular NH⋯HB Interactions in N-Alkyl Amidines 10-RNHC(Me)=NH-7,8-C2B9H11

Kirill R. Pakholkov, Ekaterina V. Bogdanova, Marina Yu. Stogniy, Kyrill Yu. Suponitsky, Sergey A. Anufriev, Igor B. Sivaev and Vladimir I. Bregadze

Molecules, 2025, 30, 828
DOI: 10.3390/molecules30040828

Preparation of closo-Dodecaborate Anion Conjugate with Ethyl Glycinate and Study of Its Biodistribution in Melanoma Model B16F10

M. N. Ryabchikova, A. V. Nelyubin, A. V. Smirnova, Yu. A. Finogenova, V. A. Skribitsky, K. E. Shpakova, A. S. Kubasov, A. P. Zhdanov, A. A. Lipengolts, E. Yu. Grigorieva, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2024, 69, 811
DOI: 10.1134/S003602362460093X

Derivatives of the closo-Decaborate Anion with Pendant Functional Groups as Inhibitors of Viral Replication

T. V Grebennikova, V. V. Avdeeva, E. A. Malinina, K. Yu. Zhizhin, N. T. Kuznetsov, E. Yu. Matveev, T. M. Garaev, S. S. Novikov, A. I. Nichugovskii, I. E. Sokolov, V. F. Larichev and V. V. Lebedeva

Žurnal neorganičeskoj himii, 2023, 68, 752
DOI: 10.31857/S0044457X22602413

Protonation of Borylated Carboxonium Derivative [2,6-B10H8O2CCH3]−: Theoretical and Experimental Investigation

Ilya N. Klyukin, Anastasia V. Kolbunova, Alexander S. Novikov, Aleksey V. Nelyubin, Nikita A. Selivanov, Alexander Yu. Bykov, Alexandra A. Klyukina, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

IJMS, 2022, 23, 4190
DOI: 10.3390/ijms23084190

Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates

Alexey V. Nelyubin, Nikolay K. Neumolotov, Nikita A. Selivanov, Alexander Yu. Bykov, Ilya N. Klyukin, Alexander S. Novikov, Alexey S. Kubasov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Inorganics, 2023, 12, 2
DOI: 10.3390/inorganics12010002

Synthesis of New Boron-Containing Ligands Based on the Nucleophilic Addition of 1,10-Phenanthroline-5-Amine to Nitrile Derivatives of [2-B10H9NCR]– (R = Me, Et, nPr)

A. V. Nelyubinа, N. A. Selivanovа, A. Y. Bykovа, A. S. Kubasovа, I. N. Klyukinа, A. P. Zhdanovа, K. Y. Zhizhinа and N. T. Kuznetsovа

Žurnal neorganičeskoj himii, 2024, 69, 810
DOI: 10.31857/S0044457X24060021

Synthesis of New Promising BNCT Agents Based on Conjugates of closo-Dodecaborate Anion and Aliphatic Diamino Acids

Margarita N. Ryabchikova, Alexey V. Nelyubin, Ilya N. Klyukin, Nikita A. Selivanov, Alexander Yu. Bykov, Alexey S. Kubasov, Vsevolod A. Skribitsky, Yulia A. Finogenova, Kristina E. Shpakova, Anton A. Kasianov, Alexey A. Lipengolts, Andrey P. Zhdanov, Elena Yu. Grigoreva, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

IJMS, 2024, 26, 68
DOI: 10.3390/ijms26010068

Derivatives of the closo-Decaborate Anion with Pendant Functional Groups as Inhibitors of Viral Replication

E. Yu. Matveev, T. M. Garaev, S. S. Novikov, A. I. Nichugovskii, I. E. Sokolov, V. F. Larichev, V. V. Lebedeva, T. V. Grebennikova, V. V. Avdeeva, E. A. Malinina, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2023, 68, 670
DOI: 10.1134/S0036023623600533

Synthesis and Study of Derivatives of the [B10H10]2– Anion with Primary Amines

E. Yu. Matveev, V. Ya. Levitskaya, S. S. Novikov, A. I. Nichugovskii, I. E. Sokolov, S. V. Lukashevich, A. S. Kubasov, K. Yu. Zhizin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2022, 67, 1928
DOI: 10.1134/S0036023622601532

Amidine Derivatives of Boron Cluster Anions Based on Propargylglycine and Their Reactivity in Copper-Catalyzed Azide-Alkyne Cycloaddition Conditions

M. N. Ryabchikova, A. V. Nelyubin, I. N. Klyukin, N. A. Selivanov, A. Yu. Bykov, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2025
DOI: 10.1134/S0036023625603617

Study of Hydrophilic/Hydrophobic Properties of Borylated Iminols [BnHn – 1NHC(OH)R]– (n = 10, 12)

M. N. Ryabchikova, A. V. Nelyubin, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2023, 68, 1357
DOI: 10.1134/S0036023623700341

Preparation of a сloso-Dodecaborate Anion Conjugate with Ethyl Glycinate and Study of Its Biodistribution in a B16f10 Melanoma Model

M. N. Ryabchikova, A. V. Nelyubin, A. V. Smirnova, Y. A. Finogenova, V. A. Skribitsky, K. E. Shpakova, A. S. Kubasov, A. P. Zhdanov, A. A. Lipengolts, E. Yu. Grigorieva, K. Y. Zhizhin and N. T. Kuznetsov

Žurnal neorganičeskoj himii, 2024, 69, 803
DOI: 10.31857/S0044457X24060015

New Aspects of the Synthesis of closo-Dodecaborate Nitrilium Derivatives [B12H11NCR]− (R = n-C3H7, i-C3H7, 4-C6H4CH3, 1-C10H7): Experimental and Theoretical Studies

Alexey V. Nelyubin, Ilya N. Klyukin, Alexander S. Novikov, Andrey P. Zhdanov, Nikita A. Selivanov, Alexander Yu. Bykov, Alexey S. Kubasov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Inorganics, 2022, 10, 196
DOI: 10.3390/inorganics10110196

Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons

A. P. Zhdanov, A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2024, 69, 1463
DOI: 10.1134/S0036023624601934

Derivatization of Undecahalogenated closo-Dodecaborates [B12X11NH3]− (X = F–I): Attaching Isocyanate, Amidinium, and Formamide Functionalities

Carsten Jenne, Harald Knorke, Marc C. Nierstenhöfer, Jonas Warneke and Ziyan Warneke

Inorg. Chem., 2024, 63, 19227
DOI: 10.1021/acs.inorgchem.4c02855