Toward decorrelation of surface oxygen groups from metal dispersion effects in Pd/C hydrogenation catalysts

Edgardo A. Leal Villarroel, Cécile Marcelot, Cecilia C. Torres, Katerina Soulantica, Cristian H. Campos and Philippe Serp

Catal. Sci. Technol., 2025, 15, 2034
DOI: 10.1039/D4CY01562B

Synthesis strategies of supported bimetallic catalysts for hydrogenation reactions: review and outlook

An Zhang, Kun Yang, Arthur Prewette and Weijian Diao

Catal. Sci. Technol., 2025, 15, 6318
DOI: 10.1039/D5CY00622H

Cooperativity in supported metal single atom catalysis

Philippe Serp

Nanoscale, 2021, 13, 5985
DOI: 10.1039/D1NR00465D

Single atoms and small clusters of atoms may accompany Au and Pd dendrimer-encapsulated nanoparticles

Juliette W. Strasser and Richard M. Crooks

Soft Matter, 2022, 18, 5067
DOI: 10.1039/D2SM00518B

Connecting the mechanistic steps of cyclic dipeptide formation by a proton-transfer network: pH, temperature, pressure, and nuclear quantum effects

Pimjai Pimbaotham, John K. Villanueva, Siriporn Jungsuttiwong, Masanori Tachikawa and Robert K. Szilagyi

Org. Biomol. Chem., 2026
DOI: 10.1039/D5OB01815C

Significantly enhanced catalytic performance of Pd nanocatalyst on AlOOH featuring abundant solid surface frustrated Lewis pair for improved hydrogen activation

Junwei Li, Hongshuai Yin, Sisi Liu, Chaofa Xu and Zhixiong Cai

RSC Adv., 2024, 14, 12593
DOI: 10.1039/D4RA01852D

Deactivation of Pd/C catalysts by irreversible loss of hydrogen spillover ability of the carbon support

Laurent Vanoye, Boris Guicheret, Camila Rivera-Cárcamo, Jérémy Audevard, Javier Navarro-Ruiz, Iker del Rosal, Iann C. Gerber, Cristian H. Campos, Bruno Fernandes Machado, Jérôme Volkman, Régis Philippe, Philippe Serp and Alain Favre-Réguillon

Journal of Catalysis, 2023, 424, 173
DOI: 10.1016/j.jcat.2023.05.006

“Cocktail”-type catalysis on bimetallic systems for cinnamaldehyde selective hydrogenation: Role of isolated single atoms, nanoparticles and single atom alloys

Jérémy Audevard, Javier Navarro-Ruiz, Vincent Bernardin, Régis Philippe, Anna Corrias, Yann Tison, Alain Favre-Réguillon, Iker Del Rosal, Iann C. Gerber and Philippe Serp

Journal of Catalysis, 2023, 425, 245
DOI: 10.1016/j.jcat.2023.06.023

Yolk-shell Co catalysts with controlled nanoparticle/single-atom ratio for aqueous levulinic acid hydrogenation to γ-valerolactone

Shuai Shao, Zhongzhen Ding, Chunli Shang, Suoying Zhang, Yangchuan Ke, Gangli Zhu and Ying Yang

Chemical Engineering Journal, 2022, 450, 138153
DOI: 10.1016/j.cej.2022.138153

Pd-Catalyzed Hydrogenation of Unsaturated Terpenoids in Two-Chamber Reactors

Yu. V. Gyrdymova

Russ J Gen Chem, 2024, 94, 743
DOI: 10.1134/S1070363224040017

Selective Hydrogenation of Unsaturated Vinyl Ethers in Two‐Chamber Gauge‐Reactor

Yulia V. Gyrdymova, Elina R. Saybulina, Roman M. Mironenko and Konstantin S. Rodygin

Asian J Org Chem, 2024, 13
DOI: 10.1002/ajoc.202400147

Nanoglobular carbon and palladium–nanoglobular carbon catalysts for liquid-phase hydrogenation of organic compounds

R. M. Mironenko, V. A. Likholobov and O. B. Belskaya

RUSS CHEM REV, 2022, 91, RCR5017
DOI: 10.1070/RCR5017

Transforming bulk alkenes and alkynes into fine chemicals enabled by single-atom site catalysis

Ping Guo, Hongyuan Liu and Jie Zhao

Nano Res., 2022, 15, 7840
DOI: 10.1007/s12274-022-4495-z

Acetophenone hydrogenation and consecutive hydrogenolysis with Pd/CNT catalysts: Highlighting the synergy between single atoms and nanoparticles by kinetic modeling

Vincent Bernardin, Laurent Vanoye, Camila Rivera-Cárcamo, Philippe Serp, Alain Favre-Réguillon and Régis Philippe

Catalysis Today, 2023, 422, 114196
DOI: 10.1016/j.cattod.2023.114196

Probing Basal and Prismatic Planes of Graphitic Materials for Metal Single Atom and Subnanometer Cluster Stabilization

Mathieu Vidal, Jyoti Pandey, Javier Navarro‐Ruiz, Joris Langlois, Yann Tison, Takeharu Yoshii, Keigo Wakabayashi, Hirotomo Nishihara, Anatoly I. Frenkel, Eli Stavitski, Martine Urrutigoïty, Cristian H. Campos, Cyril Godard, Tobias Placke, Iker del Rosal, Iann C. Gerber, Valeri Petkov and Philippe Serp

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400669

Hydrogenation of NO into ammonia under ambient conditions: From mechanistic investigation to multiphase catalysis

Junxia Yang, Lei Sun, Tie Yu, Xu Fang, Shengliang Zhai, Ling Zhang, Guoqing Ren, Rui Tu, Dong Zhai, Zhen Li and Weiqiao Deng

Applied Catalysis B: Environmental, 2023, 329, 122548
DOI: 10.1016/j.apcatb.2023.122548

Porous titania nanotube confined ultrafine platinum catalysts synthesized by atomic layer deposition with enhanced hydrolytic dehydrogenation performance

Jiankang Zhang, Wenlong Yu, Dan Feng, Hao Xu and Yong Qin

Applied Catalysis B: Environmental, 2022, 312, 121405
DOI: 10.1016/j.apcatb.2022.121405

Precise Synthesis at the Atomic Scale

Shufang Ji, Caroline Jun, Yuanjun Chen and Dingsheng Wang

Precision Chemistry, 2023, 1, 199
DOI: 10.1021/prechem.3c00022

Hydrogenation of olefinic bonds in nitrile butadiene rubber on single-atom Pd1/CeO2−x catalysts with ultrahigh mass activity and stability

Jiaxin He, Zhi-Hao Zhao, JinJin Li, Zhipeng Ren, Ruyi Jiang, Jichao Zhang and Jian Zhang

Chemical Engineering Journal, 2024, 487, 150427
DOI: 10.1016/j.cej.2024.150427

Laser-driven atomic dispersion strategy: Collective catalysis synergy of atomic clusters and single atoms for enhanced CO₂ hydrogenation

Rongxia Zhao, Furong Liu, Shilin Fan, Zerui Li, Hongfeng Yin, Degao Wang, Lin Li, Yuxiang Liu and Zhu Liu

Chemical Engineering Journal, 2026, 530, 173541
DOI: 10.1016/j.cej.2026.173541

Solvent‐Free Hydrogenation of Squalene Using Parts per Million Levels of Palladium Supported on Carbon Nanotubes: Shift from Batch Reactor to Continuous‐Flow System

Boris Guicheret, Laurent Vanoye, Camila Rivera‐Cárcamo, Claude de Bellefon, Philippe Serp, Régis Philippe and Alain Favre‐Réguillon

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202200916

Mechanism of Hydrogen Spillover on Metal-Doped Carbon Materials: Surface Carboxylic Groups Are Key

Javier Navarro-Ruiz, Jérémy Audevard, Mathieu Vidal, Cristian H. Campos, Iker Del Rosal, Philippe Serp and Iann C. Gerber

ACS Catal., 2024, 14, 7111
DOI: 10.1021/acscatal.4c00293

Process intensification of the catalytic hydrogenation of squalene using a Pd/CNT catalyst combining nanoparticles and single atoms in a continuous flow reactor

Laurent Vanoye, Boris Guicheret, Camila Rivera-Cárcamo, Ruben Castro Contreras, Claude de Bellefon, Valérie Meille, Philippe Serp, Régis Philippe and Alain Favre-Réguillon

Chemical Engineering Journal, 2022, 441, 135951
DOI: 10.1016/j.cej.2022.135951

Heterogeneous Rhodium Single-Atom-Site Catalyst Enables Chemoselective Carbene N–H Bond Insertion

Yuanjun Chen, Ruixue Zhang, Zhiwen Chen, Jiangwen Liao, Xuedong Song, Xiao Liang, Yu Wang, Juncai Dong, Chandra Veer Singh, Dingsheng Wang, Yadong Li, F. Dean Toste and Jie Zhao

J. Am. Chem. Soc., 2024, 146, 10847
DOI: 10.1021/jacs.4c01408

Effects of surface functional groups of the N-containing carbon support on the catalytic properties of supported palladium

Huapeng Cui, Jingxuan Cai, Hui Chen, Yuchuan Fu and Jianyi Shen

Microporous and Mesoporous Materials, 2021, 327, 111400
DOI: 10.1016/j.micromeso.2021.111400

Computational Design of Pd Nanoclusters and Pd Single-Atom Catalysts Supported on O-Functionalized Graphene

Javier Navarro-Ruiz, Camila Rivera-Cárcamo, Bruno Machado, Philippe Serp, Iker Del Rosal and Iann C. Gerber

ACS Appl. Nano Mater., 2021, 4, 12235
DOI: 10.1021/acsanm.1c02743

Fully exposed cobalt nanoclusters anchored on nitrogen-doped carbon synthesized by a host-guest strategy for semi-hydrogenation of phenylacetylene

Qingxia Zhu, Xiaowen Lu, Siqi Ji, Honghong Li, Jun Wang and Zhijun Li

Journal of Catalysis, 2022, 405, 499
DOI: 10.1016/j.jcat.2021.11.021

Yolk-Shell Co Catalysts with Controlled Nanoparticle/Single-Atom Ratio for Aqueous Levulinic Acid Hydrogenation to Γ-Valerolactone

Shuai Shao, Zhongzhen Ding, Chunli Shang, Yangchuan Ke, Suoying Zhang and Ying Yang

SSRN Journal, 2022
DOI: 10.2139/ssrn.4098296

Adjustment of the Single Atom/Nanoparticle Ratio in Pd/CNT Catalysts for Phenylacetylene Selective Hydrogenation

Jérémy Audevard, Javier Navarro‐Ruiz, Vincent Bernardin, Yann Tison, Anna Corrias, Iker Del Rosal, Alain Favre‐Réguillon, Régis Philippe, Iann C. Gerber and Philippe Serp

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300036

Dispersed single-atom Co and Pd nanoparticles forming a PdCo bimetallic catalyst for CO oxidation

Isaias B. Aragão, Flávia R. Estrada, Dean H. Barrett and Cristiane B. Rodella

Molecular Catalysis, 2022, 526, 112377
DOI: 10.1016/j.mcat.2022.112377

Synergy Between Supported Metal Single Atoms and Nanoparticles and their Relevance in Catalysis

Philippe Serp

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300545

Multifunctional Catalytic Properties of Pd/CNT Catalysts for 4‐Nitrophenol Reduction

Jeremy Audevard, Anas Benyounes, Ruben Castro Contreras, Hicham Abou Oualid, Mohamed Kacimi and Philippe Serp

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202101783

Nanoscale Metal Particle Modified Single‐Atom Catalyst: Synthesis, Characterization, and Application

Runze Chen, Shenghua Chen, Liqiang Wang and Dingsheng Wang

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202304713

3D spiderweb-like nanowire networks loading single-atom catalysts in capillary array as high-efficiency microreactor

Gonggang Liu, Zhaocai He, Yuanjuan Bai, Yanran Li, Chongqing Wang, Jinbo Hu, Xianjun Li, Yongfeng Luo and Daoyong Chen

Chemical Engineering Journal, 2023, 453, 139700
DOI: 10.1016/j.cej.2022.139700

Transition metal ‘cocktail’-type catalysis

Darya O. Prima, Natalia S. Kulikovskaya, Alexey S. Galushko, Roman M. Mironenko and Valentine P. Ananikov

Current Opinion in Green and Sustainable Chemistry, 2021, 31, 100502
DOI: 10.1016/j.cogsc.2021.100502

Hydrogenation Reactions with Synergistic Catalysis of Pd single atoms and nanoparticles under Near‐Ambient Conditions

Junxia Yang, Li Yang, Ling Zhang, Tie Yu, Dong Zhai, Honglei Wang, Wei Zhou, Yajuan Li, Guoqing Ren, Lei Sun and Weiqiao Deng

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203108

Beyond confinement effects in Fischer-Tropsch Co/CNT catalysts

Amel Cydric Ghogia, Bruno F. Machado, Simon Cayez, Ange Nzihou, Philippe Serp, Katerina Soulantica and Doan Pham Minh

Journal of Catalysis, 2021, 397, 156
DOI: 10.1016/j.jcat.2021.03.027

Light alloying element-regulated noble metal catalysts for energy-related applications

Hui Chen, Bo Zhang, Xiao Liang and Xiaoxin Zou

Chinese Journal of Catalysis, 2022, 43, 611
DOI: 10.1016/S1872-2067(21)63899-8

Highly Active Isolated Single-Atom Pd Catalyst Supported on Layered MgO for Semihydrogenation of Acetylene

Xin Tao, Bing Nan, Yunan Li, Meng Du, Ling-ling Guo, Chen Tian, Luozhen Jiang, Lu Shen, Nannan Sun and Li-Na Li

ACS Appl. Energy Mater., 2022, 5, 10385
DOI: 10.1021/acsaem.2c02076

l-Arginine-Functionalized Pd–Ni Catalyst Enhances Direct H2O2 Synthesis in Microreactors

Xuan Chen, Zheng Chen, Lang Wu, Feifei Hu, Xin Zhou, Qian Lin, Hongyan Pan, Yongyong Shi and Donghai Jiang

Langmuir, 2025, 41, 12745
DOI: 10.1021/acs.langmuir.5c00997