A review on the active sites for titanium species in zeolites: coordination structure, synthetic strategies and activity

Yihao Wang, Kaiwei Wang, Fumin Wang, Yi Zhai, Changhao Bing, Xiaolu Fan, Qi Shen and Xubin Zhang

Mater. Chem. Front., 2025, 9, 8
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High-efficiency synthesis of enhanced-titanium and anatase-free TS-1 zeolite by using a crystallization modifier

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Inorg. Chem. Front., 2021, 8, 3077
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Au supported defect free TS-1 for enhanced performance of gas phase propylene epoxidation with H2 and O2

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Sustainable Energy Fuels, 2022, 6, 2462
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Alcohol-assisted synthesis of framework Ti-rich TS-1 zeolites for the epoxidation of 1-hexene

Ruihua Zhang, Hong Li, Wenting Lv, Sen Wang, Weiyong Jiao, Yanlu Guo, Fengmin Sun, Huixiang Wang, Qi Zhang and Baoliang Lv

Catal. Sci. Technol., 2025, 15, 6049
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Research progress on the preparation of transition metal-modified zeolite catalysts and their catalytic performance for the purification of engine exhausts

Xinyu Chen, Shengran Zhou, Xinyu Zhang, Siyuan Chen, Lanyi Wang, Chunlei Zhang, Siyu Gao, Di Yu, Xiaoqiang Fan, Ying Cheng, Yinguang Zhang, Xuehua Yu and Zhen Zhao

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Hierarchical Ti-beta with a three-dimensional ordered mesoporosity for catalytic epoxidation of bulky cyclic olefins

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New J. Chem., 2021, 45, 10303
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Functional mother liquor reversed titanium species for the green synthesis of anatase-free hollow TS-1 with tunable titanium micro-environment via a kinetic-thermodynamic co-regulatory pathway

Yi Zhai, Fumin Wang, Xubin Zhang, Guojun Lv, Zhiguo Zhu, Kaiwei Wang, Zhibo Xu and Linfang Jiang

Mater. Chem. Front., 2022, 6, 2072
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Regulation of TS-1 zeolite morphology by crystallization modifiers to boost the oxidative reactions

Jiani Zhang, Risheng Bai, Shiyu Zhou and Jiyang Li

Inorg. Chem. Front., 2025, 12, 1874
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Hierarchically porous zeolite featuring an alveolus-like microsphere for efficient oxidative desulfurization

Xing-Yu Yue, Yuan-Yuan Wang, Shen Yu, Chun-Mu Guo, Zhan Liu, Yi-Long Wang, Zhi-Yi Hu, Yu Li, Li-Hua Chen and Bao-Lian Su

Inorg. Chem. Front., 2025, 12, 5701
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Crystallization-controlled microstructure of titanium species in TS-1 zeolite for tailored catalytic performance

Siqi Chen, Jingxuan Wang, Tianjun Zhang and Risheng Bai

Inorg. Chem. Front., 2025, 12, 3864
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Impact of a polymer modifier on directing the non-classical crystallization pathway of TS-1 zeolite: accelerating nucleation and enriching active sites

Jiani Zhang, Risheng Bai, Yida Zhou, Ziyi Chen, Peng Zhang, Jiyang Li and Jihong Yu

Chem. Sci., 2022, 13, 13006
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Engineering framework Ti and Sn dual sites in Beta zeolite via interzeolite transformation for efficient tandem catalysis

Aohua Xiang, Ziqi Zhang, Yan Zhang, Shufang Lv, Lili Cao, Sixian Shi, Yan Li and Tianjun Zhang

Chem. Commun., 2026, 62, 7961
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Evaluation of the collaboration between intrinsic activity and diffusion: a descriptor for alkene epoxidation catalyzed by TS-1

Di Pan, Jiayu Yu, Ke Du, Kexin Yan, Ling Ding, Yahong Zhang and Yi Tang

Chem. Sci., 2025, 16, 5931
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Heteroatom Lewis acid zeolites: synthesis, characterization and application in the conversion of biomass-derived oxygenates

Zijun Yang, Qingfeng Ge and Xinli Zhu

Green Chem., 2024, 26, 8068
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Titanosilicate zeolite precursors for highly efficient oxidation reactions

Risheng Bai, M. Teresa Navarro, Yue Song, Tianjun Zhang, Yongcun Zou, Zhaochi Feng, Peng Zhang, Avelino Corma and Jihong Yu

Chem. Sci., 2020, 11, 12341
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Pollen-templated bio-TS-1: a sustainable catalyst with hierarchical porosity for propylene epoxidation

Shaodi Sun, Yichen Liao, Zhuang Wang, Chuanhu Wang and Daohua Sun

Green Chem., 2025, 27, 4732
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Selective synthesis of epichlorohydrin via liquid-phase allyl chloride epoxidation over a modified Ti-MWW zeolite in a continuous slurry bed reactor

Luoyi Ding, Jinpeng Yin, Wen Tong, Rusi Peng, Jingang Jiang, Hao Xu and Peng Wu

New J. Chem., 2021, 45, 331
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Iron-loaded pure silica -SVR zeolite for the hydroxylation of phenol

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A nanoarchitectured 2D–2D heterointerface of Pt@Ti3C2Tx–rGO aerogels via in situ γ-radiolysis induced self-assembly: interplay between strain and ligand effects in electrocatalytic interfaces

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Constructing TiO6-rich hierarchical TS-1 zeolites via biuret-assisted synthesis for improved selective oxidation catalysis

Yumeng Hu, Yulin Yao, Zhenheng Diao, De Sun and Yuanyuan Dong

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The synthesis of pure and uniform nanosized TS-1 crystals with a high titanium content and a high space–time yield

Lejian Zhang, Xiaoxiao Zhu, Xinping Wang and Chuan Shi

Inorg. Chem. Front., 2021, 8, 5260
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Preparation of open and hierarchical porous TS-1 and its catalytic performance in phenol hydroxylation

Deng-Gao Huang, Shi-Lin Hu, Zi-Sheng Chao, Dong Wu and Hao Ruan

J Porous Mater, 2024, 31, 2113
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New penta- and hexa-coordinated titanium sites in titanium silicalite-1 catalyst for propylene epoxidation

Yanli Wang, Hong Yang, Yi Zuo, Dongxu Tian, Guangjin Hou, Yaqiong Su, Zhaochi Feng, Xinwen Guo and Can Li

Applied Catalysis B: Environmental, 2023, 325, 122396
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Electron-deficient titanium single-atom electrocatalyst for stable and efficient hydrogen production

Injoon Jang, Kyungmin Im, Hyeyoung Shin, Kug-Seung Lee, Hyungjun Kim, Jinsoo Kim and Sung Jong Yoo

Nano Energy, 2020, 78, 105151
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Effect of ammonium salt on the distribution of titanium species in the synthesis of TS-1 zeolites

Hao-hao SHE, Guo-qiang DING, Xian-qing LI, Hong-xing WANG, Dong-bo CAO, Yu-lei ZHU and Yong-wang LI

Journal of Fuel Chemistry and Technology, 2021, 49, 1148
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In-Situ Growth of Embryonic TS-1 on Amorphous Silica via Steam-Assisted Crystallization: Correlation of Structural Properties and Catalytic Performance of Embryonic, Crystalline, and Amorphous Titanosilicate Catalysts

ZeynabAlsadat Khatami Shal, Cheuk-Wai Tai, Michael Goepel, Roger Gläser and Mozaffar Shakeri

Crystal Growth & Design, 2023, 23, 4883
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Facile synthesis of anatase-free hierarchical TS-1 zeolite containing highly active TiO6 species for alkene epoxidation and oxidative desulfurization

Zicong Wang, Jing Zhao, Weijiong Dai, Linquan Li, Yan Wang, Jiajun Zheng and Ruifeng Li

Fuel Processing Technology, 2026, 287, 108455
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Framework Ti-rich titanium silicalite-1 zeolite nanoplates for enhanced photocatalytic H2 production from CH3OH

Pengxian Tao, Xiao Wang, Qiao Zhao, Hongxia Guo, Li Liu, Xiwei Qi and Wenquan Cui

Applied Catalysis B: Environmental, 2023, 325, 122392
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Resolving the Reaction Mechanism and Active Sites for Oxidation–Hydration of Ethylene toward Ethylene Glycol Synthesis over Bifunctional Al/TS-1 Catalysts

Xiaowa Nie, Wenchao Yang, Chunshan Song and Xinwen Guo

Ind. Eng. Chem. Res., 2024
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Electronic and Atomic Structural Properties Associated with Enhanced Photodegradation Activity in Mo-Doped TiO2 Nanoparticles

Chiao-Yu Cheng, Yu-Min Shen, Wei-Hsiang Huang, Chun-Chi Chang, Chang-Chih Tsai, Chin-Jung Lin, Yan-Gu Lin, Ying-Rui Lu, Chung-Li Dong, Wei-Nien Su, Shih-Yun Chen, Krishna Kumar, Han-Yi Chen, Cho-Jen Tsai and Chi-Liang Chen

Langmuir, 2024, 40, 19506
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Silica waste with different surface properties for solvent-free synthesis of TS-1 and its efficient epoxidation of chloropropene

Saisai Ran, Hanfang Liu, Xiaolong Li, Huijie Xie, Wei Xu, Bin Li, Yu Yang, Yongming Chai and Lei Wang

Microporous and Mesoporous Materials, 2023, 347, 112350
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Two-step synthesis of Ti-rich surface TS-1 with controllable microenvironment of titanium species

Linfang Jiang, Fumin Wang, Yi Zhai, Kaiwei Wang, Zhibo Xu, Xu Zhang, Mengyue Li, Mengyao Li and Xubin Zhang

Applied Catalysis A: General, 2023, 651, 119023
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Synthesis of Plate-Like TS-1 Zeolites with a Controllable b-Axis Thickness and Ti Coordination States

Hongyu Wang, Fumin Wang, Kaiwei Wang, Xubin Zhang, Changhao Bing, Xiaolu Fan, Tongxue Zhang and Syed Mujtaba ul Hassan

Crystal Growth & Design, 2025, 25, 4112
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Rationally constructed Ti sites of TS-1 for epoxidation reactions

Xiang Feng, Dong Lin, De Chen and Chaohe Yang

Science Bulletin, 2021, 66, 1945
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A Titanium Silicalite‐1 (TS‐1) Catalyst with Abundant Active Ti‐VI Species for Efficient Conversion of Ethylene to Glycol

Huali Tan, Yi Zuo, Gudan Li, Bosong Zhang, Lina Li, Lingling Guo, Jianrong Zeng, Fei Song, Hong Yang and Xinwen Guo

Angewandte Chemie, 2025, 137
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Review and perspectives on TS-1 catalyzed propylene epoxidation

Jimei Yang, Shuling Liu, Yanyan Liu, Limin Zhou, Hao Wen, Huijuan Wei, Ruofan Shen, Xianli Wu, Jianchun Jiang and Baojun Li

iScience, 2024, 27, 109064
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Promoting the catalytic performance of hollow titanosilicate zeolite in phenol hydroxylation by integrating polyetheramine-assisted silanization pore extending and crystalline rearrangement

Shichen Lu, Zhile Zhang, Lingbei Geng, Chao Yang, Qiang Li and Changjiu Xia

Catalysis Today, 2026, 468, 115719
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Regeneration of a Spent TS-1 Zeolite Catalyst for Liquid-Phase Epoxidation of Propylene and H2O2

Yue Li, Yanhui Yi, Xiangsheng Wang, Bize Gao, Yitong Guo, Guoxing Wu, Zhaochi Feng and Hongchen Guo

Ind. Eng. Chem. Res., 2023, 62, 12152
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Furfural oxidation by hierarchical titanium silicate catalyst with NiO nanoparticles: Improved diacid yield and elucidation of reaction pathway

Astrid Kjær Steffensen, Wenting Fang, Leonhard Schill, Sebastian Meier and Anders Riisager

Applied Catalysis A: General, 2025, 704, 120409
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Controlling the Morphology and Titanium Coordination States of TS-1 Zeolites by Crystal Growth Modifier

Xiaojing Song, Xiaotong Yang, Tianjun Zhang, Hao Zhang, Qiang Zhang, Dianwen Hu, Xinyu Chang, Yingying Li, Ziyi Chen, Mingjun Jia, Peng Zhang and Jihong Yu

Inorg. Chem., 2020, 59, 13201
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Impact of raw materials for TS-1 zeolite on its crystallization process, Ti species and catalytic properties

Shunsuke Yamada, Shuhei Yasuda, Willie Yang, Masamichi Hosaki, Takeshi Matsumoto, Junko N. Kondo and Toshiyuki Yokoi

Catalysis Today, 2023, 411-412, 113857
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Axial Coordination of Iron Single-Atom Catalysts on Defective Graphene for Electrocatalytic Conversion of Nitric Oxide to Hydroxylamine: A Theoretical Investigation

Jianhong Hu, Wenqi Ruan, Qixiang Bai, Wei Lin, Xiangyu Guo and Kaining Ding

Langmuir, 2025
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A novel MOFs-induced strategy for preparing anatase-free hierarchical TS-1 zeolite:synthesis routes, growth mechanisms and enhanced catalytic performance

Guoqing An, Chang'an Wang, Hongyi Gao, Ge Wang, Yibin Luo, Zhiyuan Liu, Changjiu Xia, Siqi Liu, Xinxin Peng, Zhixiang Cheng and Xingtian Shu

Journal of Colloid and Interface Science, 2023, 633, 291
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Catalytically active species in bifunctional Aluminum-Containing titanium Silicalite-1 zeolite for ethylene epoxidation

Yanli Wang, Hong Yang, Guangjin Hou, Bosong Zhang, Zhaochi Feng, Xinwen Guo and Can Li

Chemical Engineering Science, 2023, 282, 119241
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Mesoporogen-Free Strategy to Construct Hierarchical TS-1 in a Highly Concentrated System for Gas-Phase Propene Epoxidation with H2 and O2

Juncong Yuan, Zhaoning Song, Dong Lin, Xiang Feng, Yongxiao Tuo, Xin Zhou, Hao Yan, Xin Jin, Yibin Liu, Xiaobo Chen, De Chen and Chaohe Yang

ACS Appl. Mater. Interfaces, 2021, 13, 26134
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Preparation of open and hierarchical porous TS-1 and its catalytic performance in phenol hydroxylation

Deng-Gao Huang, Shi-Lin Hu, Zi-Sheng Chao, Dong Wu and Hao Ruan

J Porous Mater, 2024, 31, 1697
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Volume expansion restriction by TiO 2 structural unit in silicon anodes with yolk–shell structure for lithium-ion batteries

Yuan Li, Shengkai Sun, Junjie Tang, Sihui Han, Yu Yang, Jun Xing, Lingbo Zong, Lei Wang and Bin Li

Nano Research, 2024, 18, 94907474
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Insights into the role of titanium sites in cyclohexanone ammoximation over titanium silicalite-1

Tengteng Wang, Xue Yang, Yufang Ma, Lei Chen, Meikun Shen, Yongdan Chen, Guangliang Song, Lei Wang, Yu Zhou, Jun Wang and Hongjun Zhu

Molecular Catalysis, 2022, 524, 112298
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TS-1 zeolite with homogeneous distribution of Ti atoms in the framework: synthesis, crystallization mechanism and its catalytic performance

Zhen Chen, Lianlin Zhang, Yunkai Yu, Dongxu Liu, Nan Fang, Yuxia Lin, Deyi Xu, Fang Li, Yueming Liu and Mingyuan He

Journal of Catalysis, 2021, 404, 990
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A new stratagem to efficiently synthesize monolithic TS-1 via dry gel conversion in the atmosphere of tripropylamine-water and revealing insight into the structure–activity relationship for propylene epoxidation

Shuang Ji, Gui-Ping Cao, Hui Lv, Peng Gao and Chun-Xue Wang

Journal of Catalysis, 2024, 433, 115445
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Enhancing photocatalytic hydrogen peroxide production of Ti-based metal–organic frameworks: The leading role of facet engineering

Xue-Yang Ji, Yao-Yao Wang, Yun Li, Ke Sun, Meng Yu and Jun Tao

Nano Res., 2022, 15, 6045
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Novel titanium-containing precursors for the fabrication of hierarchical TS-1 and the enhanced catalytic performance for olefins

Chang'an Wang, Ying Ouyang, Yibin Luo, Kunfeng Gao, Xing Chen, Shuya Zhao, Qibin Yang and Hongyi Gao

Chemical Physics Letters, 2024, 835, 140995
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Crystal Morphological Engineering of MFI Nanosheet Assisted by Pyrrolidone Compounds

Kaiwei Wang, Fumin Wang, Xubin Zhang, Mingshuai Sun, Yi Zhai, Yihao Wang, Hongyu Wang, Yang Qin and Hao Ruan

ACS Appl. Mater. Interfaces, 2025, 17, 12553
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Dual-template synthesis of hierarchically layered titanosilicate-1 zeolites for catalytic epoxidation of cyclooctene

Manyun Wang, Xu Wang, Qing You, Yushuai Wu, Xin Yang, Huiyong Chen, Baoyu Liu, Qingqing Hao, Jianbo Zhang and Xiaoxun Ma

Microporous and Mesoporous Materials, 2021, 323, 111207
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Modified Ti-MWW Zeolite as a Highly Efficient Catalyst for the Cyclopentene Epoxidation Reaction

Wen Tong, Jinpeng Yin, Luoyi Ding, Hao Xu and Peng Wu

Front. Chem., 2020, 8
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Zeolite structure descriptor for guiding the synthesis of efficient titanosilicalites through matching Ti sites and framework topologies for 1-Hexene epoxidation

Xuliang Deng, Dong Lin, Yang Xu, Xiang Feng, De Chen, Chaohe Yang and Honghong Shan

Chemical Engineering Journal, 2024, 487, 150338
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A Review on Understanding and Strengthening of Active Species in Titanium Silicalite‐1 (TS‐1) Catalysts

Yan Xue, Shuling Liu, Jiaqi Wang, Huanhuan Zhang, Huijuan Wei, Yanyan Liu, Xiangyu Wang, Jinjun Tian, Jianchun Jiang and Baojun Li

Advanced Science, 2025, 12
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Tailoring of the Properties of Amorphous Mesoporous Titanosilicates Active in Acetone Condensation

Vera R. Bikbaeva, Anna S. Artem’eva, Sergey V. Bubennov, Alexander I. Nikiforov, Viktor Y. Kirsanov, Dmitry V. Serebrennikov, Lubov F. Korzhova, Stanislav G. Karchevsky, Leonard M. Khalilov, Boris I. Kutepov and Nellia G. Grigoreva

Gels, 2024, 10, 732
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Nanosponge TS‐1: A Fully Crystalline Hierarchical Epoxidation Catalyst

Jan Přech, Jaeheon Kim, Michal Mazur, Ryong Ryoo and Jiří Čejka

Adv Materials Inter, 2021, 8
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Shielding effect‐engineered single‐crystalline Ti‐rich nanosized aggregated TS‐1 for 1‐hexene epoxidation

Ze Zong, Xuliang Deng, Dong Lin, Yang Xu, Qiuming He, Zhe Ma, De Chen, Chaohe Yang and Xiang Feng

AIChE Journal, 2024, 70
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Tailoring Porosity and Titanium Species of TS-1 Zeolites via Organic Base-assisted Sequential Post-treatment

Wenjing Xu, Li Li, Tianjun Zhang and Jihong Yu

Chem. Res. Chin. Univ., 2022, 38, 50
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Metal Sites in Zeolites: Synthesis, Characterization, and Catalysis

Qiang Zhang, Shiqin Gao and Jihong Yu

Chem. Rev., 2023, 123, 6039
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Enhancing the accessible TiO6 concentration and the hydrophobicity of hierarchical TS-1 zeolites for alkene epoxidation and oxidative desulfurization

Yulin Yao, Zonghan Yang, Pengfei Zheng and Zhenheng Diao

Chemical Engineering Journal, 2023, 475, 146053
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Suppression of TS-1 Aggregation by Freeze-Drying to Enhance Au Dispersion for Propylene Epoxidation Using H2 and O2

Yanqi Guo, Zhihua Zhang, Jialun Xu, Xuezhi Duan and Xinggui Zhou

Ind. Eng. Chem. Res., 2023, 62, 8654
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Regulating the Coordination Mode of Ti Atoms in the Beta Zeolite Framework to Enhance the 1-Hexene Epoxidation

Xuliang Deng, Yang Xu, Jincheng Liu, Dong Lin, Ze Zong, Juncong Yuan, Zhiyang Li, Guanghui Zhao, Yongjun Zhang, Yibin Liu, Xiaobo Chen, Xiang Feng, De Chen, Chaohe Yang and Honghong Shan

Ind. Eng. Chem. Res., 2024, 63, 3817
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Constructing Highly Efficient Catalysts for the 1‐Butene Epoxidation

Yaqi Dong, Juncong Yuan, Sheng He, Zhe Ma, De Chen, Chaohe Yang and Xiang Feng

ChemCatChem, 2025, 17
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Fully utilizing seeds solution for solvent-free synthesized nanosized TS-1 zeolites with efficient epoxidation of chloropropene

Hanfang Liu, Yu Wang, Tiantian Ye, Fupeng Wang, Saisai Ran, Huijie Xie, Jia Liu, Yichuan Li, Bin Li, Yanru Liu, Yongming Chai and Lei Wang

Journal of Solid State Chemistry, 2022, 307, 122844
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Recent advances in the synthesis of TS-1 zeolite

Huimin Luan, Cheng Xu, Qinming Wu and Feng-Shou Xiao

Front. Chem., 2022, 10
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Amino acid-assisted synthesis of TS-1 zeolites containing highly catalytically active TiO6 species

Yuyao Wang, Li Li, Risheng Bai, Shiqin Gao, Zhaochi Feng, Qiang Zhang and Jihong Yu

Chinese Journal of Catalysis, 2021, 42, 2189
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Hierarchical manganese-containing TS-1 zeolite for the direct oxidation of cyclohexane to adipic acid with molecular oxygen: Synergy between matrix Ti and Mn species

Mingdong Zhang, Xueshuang Wu, Guiying Li and Changwei Hu

Chinese Journal of Catalysis, 2025, 79, 127
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Modification of the textural and Ti speciation of Ti-silicalite by post-synthesis treatments and their effects on the catalytic ammoximation of cyclopentanone to its oxime

Ana Orozco-Saumell, José Manuel Jiménez-Martín, José Iglesias, Rafael Mariscal and Manuel López Granados

Catalysis Today, 2025, 458, 115370
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Enhancing oxidative hydration of ethylene towards ethylene glycol over metal-modified titanosilicate catalysts

Feipeng Cheng, Jihao Cheng, Yang Nan, Yuan Xie, Tongqian Yang, Daojian Cheng, Jiqin Zhu and Haoxiang Xu

Applied Catalysis A: General, 2022, 643, 118752
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Silica islands regulated external Ti‐site environment of TS‐1 for enhanced performance of 1‐hexene epoxidation

Juncong Yuan, Ranfei Fu, Lunrui Fan, Yaqi Dong, Ze Zong, Hui Kang, Hao Yan, Yibin Liu, Xingong Zhang, Guanghui Zhao, Xuliang Deng, Yongjun Zhang, Jincheng Liu, Chaohe Yang, Honghong Shan, De Chen and Xiang Feng

AIChE Journal, 2023, 69
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Biophenol-Mediated Solvent-Free Synthesis of Titanium Silicalite-1 to Improve the Acidity Character of Framework Ti toward Catalysis Application

Lu Wang, Yan Xu, Guanzhong Zhai, Yanmei Zheng, Jiale Huang, Daohua Sun and Qingbiao Li

ACS Sustainable Chem. Eng., 2020, 8, 12177
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Synthesis of 3,4-Dihydropyrimidinone Derivatives by Using Mag@TOS as a Strong and Magnetically Recoverable Nanocatalyst

Marjan Yazdani, Dawood Elhamifar and Masoumeh Shaker

J Inorg Organomet Polym, 2025, 35, 5705
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Addition of polyethylene glycol for the synthesis of anatase-free TS-1 zeolites with excellent catalytic activity in 1-hexene epoxidation

Xinyu Chang, Xiaotong Yang, Xiaojing Song, Lifen Xu, Dianwen Hu, Yuting Sun and Mingjun Jia

J Porous Mater, 2022, 29, 641
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Bulky macroporous titanium silicalite-1 free of extraframework titanium for phenol hydroxylation

Yi Zuo, Yu Chen, Tonghui Li, Jiaojiao Yu, Hong Yang, Min Liu and Xinwen Guo

Microporous and Mesoporous Materials, 2022, 336, 111884
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Recent Advances in Tetra- (Ti, Sn, Zr, Hf) and Pentavalent (Nb, V, Ta) Metal-Substituted Molecular Sieve Catalysis

Steven L. Suib, Jan Přech, Ewelina Szaniawska and Jiří Čejka

Chem. Rev., 2023, 123, 877
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Expanded titanosilicate MWW-related materials synthesized from a boron-containing precursor as an efficient catalyst for cyclohexene oxidation

Zhimou Tang, Yunkai Yu, Zhen Chen, Dongxu Liu, Nan Fang, Haihong Wu, Yueming Liu and Mingyuan He

Microporous and Mesoporous Materials, 2021, 327, 111437
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TS-1 Synthesis via Subcrystal Aggregation: Construction of Highly Active Hydrogen-Bonded Titanium Species for Alkene Epoxidation

Di Pan, Lingtao Kong, Hongbin Zhang, Yahong Zhang and Yi Tang

ACS Appl. Mater. Interfaces, 2023, 15, 28125
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Combining solid state grinding and steam-assisted crystallization for green organotemplate-free synthesis of ZSM-5

Huijie Xie, Wei Xu, Saiai Ran, Xiaolong Li, Bin Li, Yanyan Li and Lei Wang

Microporous and Mesoporous Materials, 2022, 345, 112238
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A novel continuous-flow photocatalytic device for antibiotic degradation

Qi Li, Lantian Zhang, Yue Xin, Shuhui Li, Zicheng Xie, Siyuan Zhang, Jiawen Yu, Rong He and Liangbing Wang

Molecular Catalysis, 2024, 559, 114030
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A review on titanosilicate-1 (TS-1) catalysts: Research progress of regulating titanium species

Baohe Wang, Yanke Guo, Jing Zhu, Jing Ma and Qiaoyun Qin

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Preparation of Hierarchical Ti-Sil-BEA Zeolite by Silanization Modification for the Application in Dicyclopentadiene Epoxidation Reaction

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Efficient Epoxidation of Cyclohexene Catalyzed by W-Substituted Self-Pillared Pentasil Zeolite Nanosheets

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Hydrophobicity Manipulation of Titanium Silicalite-1 with Enhanced Catalytic Performance via Liquid-Mediated Defect Healing Treatment

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Construction of a Cu@hollow TS‐1 nanoreactor based on a hierarchical full‐spectrum solar light utilization strategy for photothermal synergistic artificial photosynthesis

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A simple strategy for synthesis of b-axis-oriented MFI zeolite macro-nanosheets

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Regulating Titanium Species on TS-1 Zeolites by Na+ for Liquid-Phase Epoxidation of Propylene and H2O2

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Mesoporous planar TS-1 supported molybdenum catalyst for green epoxidation of olefins: Synthesis, characterization and catalytic properties

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Immobilized peroxotungstate vs. TS-1 in catalytic epoxidation of organic substrates with hydrogen peroxide

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Constructing Highly Efficient Ti Sites of TS-1 for Alkene Epoxidation

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Synthesis of TS-1 from supported embryonic to nano-/micro-metersized crystalline particles: The impact of accessibility of Ti species on the catalytic performance

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Synthesis of the Hierarchical TS-1 Using TritonX Homologues for Hydroxylation of Benzene

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Photocatalytic Bacterial Inactivation of Acinetobacter baumannli on Cu/TiO2/Diatomite

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Synthesis of micro-mesoporous TS-1 zeolite and its green catalytic oxidation of p-diethylbenzene

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Chemistry of coordinatively unsaturated centers in zeolites

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Amide-assisted synthesis of TS-1 zeolites with active Ti(OH2)2(OH)2(OSi)2 sites toward efficient oxidative desulfurization

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Effect of Sodium Concentration on the Synthesis of Faujasite by Two-step Synthesis Procedure

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Aromatic compounds‐mediated synthesis of anatase‐free hierarchical TS‐1 zeolite: Exploring design strategies via machine learning and enhanced catalytic performance

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Synergetic effects of Sn and Ti incorporated in MWW zeolites on promoting the oxidative hydration of ethylene with H2O2 to ethylene glycol

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Synergizing tetra-coordinated Ti sites anchored onto micropore-free silica with Au sites to boost propylene hydro-oxidation

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CoTiO3 for highly efficient peroxymonosulfate activation: The critical role of Co–O–Ti bond for rapid redox cycles of Co2+/Co3+

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Modified microstructure of Ti and Zn sites in Silicalite-1 catalysts for propane dehydrogenation

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Tailoring zeolites for enhanced post-combustion CO2 capture: A critical review

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Tungsten-substituted Silicalite-1 with an interconnected hollow structure for catalytic epoxidation of cyclohexene

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A Titanium Silicalite‐1 (TS‐1) Catalyst with Abundant Active Ti‐VI Species for Efficient Conversion of Ethylene to Glycol

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The electron-rich [ZnH]+ species stabilized by titanium silicalite-1 zeolite for propane dehydrogenation

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Two-Dimensional Ultrathin Silica Films

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Efficient construction of active TiO6 species in TS-1 zeolite via treatment with amines and ammonium salts for enhanced cyclohexene epoxidation

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Epoxidation of allyl alcohol to glycidol over TPAOH-treated titanium silicalite-1 extrudates

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Rapid synthesis of hierarchical nanosized SSZ-13 zeolite with excellent MTO catalytic performance

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Ammonium-assisted modulation of octahedral Ti sites in Ti-MWW zeolite for green production of ethylene glycol from ethylene with hydrogen peroxide

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Investigation on Titanium Silicalite-1 Zeolite Synthesis Employing ATPAOH as an Organic Structure Directing Agent

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Regulating the microenvironments and the d-band center of hierarchical NiMoS/TS-1 catalyst by ZrO2 to enhance the hydrodesulfurization performance of dibenzothiophene

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Efficient and Eco-friendly Photocatalyst from TS-1 Decorated with Carbon Dots for Degradation of Organic Dyes

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Enhanced catalytic performance of trimethylsilylated Ti-MWW zeolites for the liquid-phase epoxidation of propylene with H2O2

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Microwave‐Positioning Assembly: Structure and Surface Optimizations for Catalysts

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Accelerated Crystallization of Zeolites via Solid Boron Free Radicals

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Tandem photocatalytic production of H2O2 and propylene oxide on 5-Bromoisatin modified carbon nitride

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Anatase-free titanosilicate with quasi-pure octahedral titanium species for efficient selective oxidations with hydrogen peroxide

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Creation of Hierarchical Titanosilicate TS‐1 Zeolites

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Optimization of MOFs-induced strategy for preparing anatase-free hierarchical TS-1 towards 1-hexene epoxidation: TPAOH dosage regulation, silanization and stabilizing acidic sites

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Synthesis of High-Quality TS-1 Zeolites Using Precursors of Diol-Based Polymer and Tetrapropylammonium Bromide for 1-Hexene Epoxidation

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Significant promotion of reducing treatment on Pd/TS-1 zeolite for formaldehyde catalytic purification at ambient temperature

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Selective photocatalytic oxidation of furfural to C4 compounds with metal-TS-1 zeolite

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Ti–N ligand‐directed tunable TiO4/TiO6 active sites in TS‐1 for enhanced olefin epoxidation performance

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Heteroatom Manipulation of Zeolite Crystallization: Stabilizing Zn-FAU against Interzeolite Transformation

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Simple Molecular Synthetic Approach to Dinuclear Titanium Sites in Ti-Containing Silica-Based Catalysts

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Effect of the bipodal Ti species on activity and selectivity of propylene epoxidation with H2O2 over TS-1: A theoretical study

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Molecular Catalysis, 2023, 543, 113147
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Engineering surface framework TiO6 single sites for unprecedented deep oxidative desulfurization

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Recent Advances in the Synthesis and Application of TS‐1 Zeolite for Green Catalytic Oxidation

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Steam-assisted strategy to fabricate Anatase-free hierarchical titanium Silicalite-1 Single-Crystal for oxidative desulfurization

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Bismuth–Titanium–Silicate–Oxide Glass Ceramics for Various Dielectric Applications

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Coordinating cracking and hydrogenation of polyethylene waste via acid-metal site isolation for selective hydrocarbon production

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Tailoring the First Coordination Shell of Isolated Ti(IV) Active Sites in Zeolite Frameworks Boosting Catalytic Activity in Epoxidation

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A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics

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Chinese Chemical Letters, 2024, 35, 108903
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Controllable synthesis of a large TS-1 catalyst for clean epoxidation of a C=C double bond under mild conditions

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