Issue 13, 2019

Controlled functionalization of o-carborane via transition metal catalyzed B–H activation

Abstract

Carboranes, a class of carbon–boron molecular clusters, are often viewed as three-dimensional analogues of benzene. They are finding increasing applications as useful functional building blocks in materials science, medicine, organometallic/coordination chemistry and more. Thus, functionalization of carboranes has received considerable attention. In comparison with the weakly acidic cage C–H bonds that can be readily functionalized, selective cage B–H functionalization among ten chemically similar BH vertices in o-carboranes is very challenging. Only in the recent few years, considerable progress has been made in transition metal catalyzed vertex-specific BH functionalization. This review summarizes recent advances in this research area.

Graphical abstract: Controlled functionalization of o-carborane via transition metal catalyzed B–H activation

Article information

Article type
Review Article
Submitted
02 мар 2019
First published
15 май 2019

Chem. Soc. Rev., 2019,48, 3660-3673

Controlled functionalization of o-carborane via transition metal catalyzed B–H activation

Y. Quan and Z. Xie, Chem. Soc. Rev., 2019, 48, 3660 DOI: 10.1039/C9CS00169G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements