Issue 38, 2018

Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru12–metalloporphyrin precursors

Abstract

Ru nanoparticle catalysts were prepared from Ru12–metalloporphyrin complex precursors containing 3d transition-metal atoms attached to SiO2 surfaces. The single 3d metal atoms at the central position of the Ru12–metalloporphyrin complex precursors exerted a significant influence on the structures and hydrogenation performance of the Ru nanoparticles on the SiO2 surfaces. The Ru12–Cu–porphyrin complex afforded positively charged Ru nanoparticles, which would provide high activity toward aromatic hydrogenation.

Graphical abstract: Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru12–metalloporphyrin precursors

Supplementary files

Article information

Article type
Communication
Submitted
26 дек 2017
Accepted
18 апр 2018
First published
26 апр 2018

Chem. Commun., 2018,54, 4842-4845

Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru12–metalloporphyrin precursors

S. Muratsugu, A. Yamaguchi, G. Yokota, T. Maeno and M. Tada, Chem. Commun., 2018, 54, 4842 DOI: 10.1039/C7CC09862F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements