Issue 2, 2014

Controlled synthesis of conjugated random copolymers in a droplet-based microreactor

Abstract

We report the highly controlled synthesis of conjugated random copolymers in a droplet-based microfluidic reactor. Using two optically distinct polymers, poly(3-hexylthiophene) (P3HT) and poly(3-hexylselenophene) (P3HS), a series of highly regioregular random copolymers is generated with physical properties intermediate to those of the parent homopolymers. Analysis by 1H nuclear magnetic resonance spectroscopy reveals the co-polymerisation process to follow ideal Bernoullian behavior.

Graphical abstract: Controlled synthesis of conjugated random copolymers in a droplet-based microreactor

Supplementary files

Article information

Article type
Communication
Submitted
25 июл 2013
Accepted
02 окт 2013
First published
10 окт 2013
This article is Open Access
Creative Commons BY license

Mater. Horiz., 2014,1, 214-218

Controlled synthesis of conjugated random copolymers in a droplet-based microreactor

J. H. Bannock, M. Al-Hashimi, S. H. Krishnadasan, J. J. M. Halls, M. Heeney and J. C. de Mello, Mater. Horiz., 2014, 1, 214 DOI: 10.1039/C3MH00066D

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