Fluorinated DOL-based copolymer electrolytes enabling wide electrochemical window and stabilized interphases for lithium batteries

Yachao Yan, Ligang Xu, Jinbo Tang, Hailong Xie, Jingqin Xu, Xianyi Liu, Wenxin He, Yingzhi Chen, Shaojun Wang, Huajie Luo, Mingxue Tang, Lu-Ning Wang and Jipeng Fu

J. Mater. Chem. A, 2025, 13, 38094
DOI: 10.1039/D5TA05599G

Lean-solvent solid electrolytes for safer and more durable lithium batteries: a crucial review

Chenyu Xiong, Yuefeng Meng, Yao Wang, Bingyue Ling, Mengyu Ma, Hao Yan, Feiyu Kang, Dong Zhou and Baohua Li

Energy Environ. Sci., 2025, 18, 1612
DOI: 10.1039/D4EE05293E

In situ polymerized ether-based polymer electrolytes towards practical lithium metal batteries

Sisi Peng, Jialong Fu, Lu Wei and Xin Guo

Chem. Commun., 2025, 61, 868
DOI: 10.1039/D4CC04932B

Synthesis of a crosslinked ether-based polymer for high-performance semi-solid lithium metal batteries via in situ integration

Dezhi Yang, Yanan Yang, Yeying Cui, Yiyang Sun and Tao Zhang

J. Mater. Chem. A, 2024, 12, 27043
DOI: 10.1039/D4TA04857A

Overcoming misconceptions in lithium metal polymer electrolyte batteries

John B. Waugh, Mikhail Redko, Xiuyu Jin, Gabriel Muldoon, Evgenii L. Kovrigin, Betar M. Gallant, Yuzhang Li, Gao Liu and John Muldoon

Energy Environ. Sci., 2025, 18, 9312
DOI: 10.1039/D5EE03530A

Upcycling waste polyoxymethylene to value-added chemicals using reusable polymeric acid catalysts at ppm levels

Abhijit Sen, Aya Ohno, Andrew Chapman, Yina Xu, Jingxuan Zhang, Nobutaka Maeda, Jordan T. Carlson and Yoichi M. A. Yamada

Green Chem., 2026, 28, 2814
DOI: 10.1039/D5GC06065F

Do weaker solvation effects mean better performance of electrolytes for lithium metal batteries?

Liang Li, Kaixiang Ren, Wenjun Xie, Qi Yu, Shilin Wu, Hai-Wen Li, Meng Yao, Zhipeng Jiang and Yongtao Li

Chem. Sci., 2025, 16, 7981
DOI: 10.1039/D5SC01495F

Recent advances in garnet-based electrolytes for solid-state lithium metal batteries: interfacial challenges and engineering strategies

Yuezhen Mao, Jilong Liu, Wei Chen, Wei Zhang and Chunwen Sun

Mater. Horiz., 2025, 12, 6082
DOI: 10.1039/D5MH00583C

In situ polymerization-driven quasi-solid electrolytes for Li-metal batteries

Jinxuan Liu, Yinglei Wu, Zhenying Chen, Zhixin Xu, Jinhui Zhu and Xiaodong Zhuang

Mater. Chem. Front., 2025, 9, 1971
DOI: 10.1039/D5QM00116A

Decoupling Interfacial Stability and Ion Transport in Solid Polymer Electrolyte by Tailored Ligand Chemistry for Lithium Metal Battery

Ruifan Lin, Yingmin Jin, Yumeng Li, Mengyu Fu, Yuxin Gong, Lei Lei, Yong Zhang, Jijian Xu and Yueping Xiong

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202421880

Entropy‐Driven Modulation of Ion Clustering and Polymer Crystallinity for Low‐Temperature Lithium Metal Batteries

Junze Guo, Weifeng Zou, Yaoxian Song, Xuyin Zhu, Haodong Zhou, Weidong Zhang, Fanghao Zhou and Tiefeng Li

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202511612

Lithium-exchanged molecular sieve-functionalized liquid crystal elastomer solid-state electrolyte for high-performance lithium metal batteries

Fan Xi, Qunzheng Zhang, Zemin He, Rui Yan, Ping Yu, Teng Du, Yuhu Feng, Bei Qin and Xingxing Zhang

Journal of Energy Storage, 2025, 137, 118717
DOI: 10.1016/j.est.2025.118717

Anchored Weakly‐Solvated Polymer Electrolyte for Operating Lithium‐Metal Batteries Under Extreme Cold Conditions

Jin Tan, Pengcheng Wang, Hanbing Yan, Chenguang Bao, Wei Wu, Xiaohong Xia, Qi Liu and Baohua Li

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202523646

Prospects for interfacial and mechanical optimization in polymer-based lithium batteries with specifying the role of intermolecular chemistry

Qiqi Sun, Tao Zhang, Leyuan Ma, Miaofa Yuan, Xuehui Li, Rutao Wang, Zhiwei Zhang, Jiafeng Li, Longwei Yin and Chengxiang Wang

Energy Storage Materials, 2025, 81, 104536
DOI: 10.1016/j.ensm.2025.104536

Prolonging Storage Shelf‐Life of Lithium Metal Batteries with Phase‐Change Electrolyte

Herao Wang, Zicheng Luo, Yangyang Cheng, Menghong Li, Yulong He, Yuxuan Gao, Zhiguo Du, Shubin Yang and Bin Li

Advanced Energy Materials, 2026, 16
DOI: 10.1002/aenm.202505116

Li–Ga Alloy-Contained Hybrid Solid Electrolyte Interphase Induced by In Situ Polymerization for High-Performance Lithium Metal Batteries

Binyu Lu, Liuyi Hu, Wenkui Zhang, Jun Zhang, Yang Xia, Yongping Gan, Xinping He, Xinhui Xia, Ruyi Fang and Hui Huang

ACS Appl. Mater. Interfaces, 2024
DOI: 10.1021/acsami.4c10855

Solid Polymer Electrolyte with Compatible Cathode‐Electrolyte Interfacial Design Enabling Lithium Metal Batteries Operation at 4.8 V with Long Cycle Life

Jiajia Li, Haiman Hu, Jiufu Zhu, Xinyu Ma, Yin Hu, Haitao Zhang, Fengming Liu, Suojiang Zhang and Xiaoyan Ji

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202501659

Zn(TFSI)2-Mediated Ring-Opening Polymerization for Electrolyte Engineering Toward Stable Aqueous Zinc Metal Batteries

Zhenjie Liu, Murong Xi, Rui Sheng, Yudai Huang, Juan Ding, Zhouliang Tan, Jiapei Li, Wenjun Zhang and Yonggang Wang

Nano-Micro Lett., 2025, 17
DOI: 10.1007/s40820-025-01649-9

Regulated solvation structure and solid electrolyte interfaces via imidazolium ionic gel electrolytes with high Li-ion transference number for Li-metal batteries

Xiuling Dong, Wei Chen, Xinyi Ge, Shuai Wang, Xinyuan Zhang, Zheng Xing, Qingguo Zhang and Zhong-Xia Wang

Journal of Colloid and Interface Science, 2025, 682, 124
DOI: 10.1016/j.jcis.2024.11.214

Achieving high-performance all-solid-state lithium metal batteries through three-dimensional conductive ceramic-enhanced nanofibers

Yiyuan Yan, Shen Liu, Dezhi Yan, Shichao Zhang, Shuai Yin, Jun Xia, Fangchao Han, Qiang Lu, Wangwei Ren, Xiaomeng Wu, Qianfan Zhang, Yalan Xing and Puheng Yang

Nano Research, 2025, 18, 94907651
DOI: 10.26599/NR.2025.94907651

Anion Modulation: Enabling Highly Conductive Stable Polymer Electrolytes for Solid‐State Li‐Metal Batteries

Liyi Zhao, Qingyu Dong, Yueqi Wang, Guoyong Xue, Xuechun Wang, Zhiyun Li, Hui Shao, Hongwei Chen, Yanbin Shen and Liwei Chen

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202412280

Fluorine-free gel polymer electrolyte for lithium oxide-rich solid electrolyte interphase and stable Li metal batteries

Weijian Xu, Lingxi Zhou, Songxin Lu, Jiahui He, Yongbin Xu and Lei Tian

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-64345-7

Microenvironment Regulation Unlocks High Li⁺ Conduction in Polyether Electrolytes for High‐Performance Quasi‐Solid‐State Batteries

Hongyao Wang, Lanting Qian, Yun Zheng, Song Duan, Bingsen Qin, Zewen Liu, Zhenghao Li, Qianyi Ma, Yidong Jiang, Wei Yan and Jiujun Zhang

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202510197

Upgrading Ion Migration and Interface Chemistry via a Cyano-Containing COF in a Single-Ion Conductive Polymer toward High-Voltage Lithium–Metal Batteries

Xiaosa Xu, Junjie Chen, Jin Li, Jiadong Shen, Pengzhu Lin, Zhenyu Wang, Zixiao Guo, Jing Sun, Baoling Huang and Tianshou Zhao

J. Am. Chem. Soc., 2025, 147, 25896
DOI: 10.1021/jacs.5c08267

In‐Situ Cross‐linked F‐ and P‐Containing Solid Polymer Electrolyte for Long‐Cycling and High‐Safety Lithium Metal Batteries with Various Cathode Materials

Nuo Xu, Yang Zhao, Minghan Ni, Jie Zhu, Xingchen Song, Xingqi Bi, Jinping Zhang, Hongtao Zhang, Yanfeng Ma, Chenxi Li and Yongsheng Chen

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202404400

Engineering Molecule‐Designed In Situ Polymerization on Al‐Doped Molecular‐Sieve Framework Enables Robust Quasi‐Solid‐State Lithium Batteries

Xiaosa Xu, Junjie Chen, Jin Li, Zhenyu Wang, Jiadong Shen, Pengzhu Lin, Jing Sun, Baoling Huang and Tianshou Zhao

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202415298

Robust and Antioxidative Quasi‐Solid‐State Polymer Electrolytes for Long‐Cycling 4.6 V Lithium Metal Batteries

Congping Li, Yue Zhong, Rongfeng Liao, Tan Yi, Minghong Zhou, Ruliang Liu, Shaohong Liu and Dingcai Wu

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202500142

A review of functional group selection and design strategies for gel polymer electrolytes for metal batteries

Weizhong Liang, Kun Zhao, Liuzhang Ouyang, Min Zhu and Jun Liu

Materials Science and Engineering: R: Reports, 2025, 164, 100973
DOI: 10.1016/j.mser.2025.100973

Solvation Structures in Solid Polymer Electrolytes for Lithium‐Based Batteries

Tao Chen, Yuncong Liu and Chao Wang

Batteries & Supercaps, 2025, 8
DOI: 10.1002/batt.202500006

Functionalized carboxylate molecule-enabled quasi-localized high concentration electrolyte for high-stability lithium-ion batteries

Xiangshao Yin, Junru Wu, Mengyuan Zhou, Xianshu Wang, Liang Luo, Xiaoping Yang, Jianguo Duan, Peng Dong, Yingjie Zhang, Zhenghui Pan and Ding Wang

Nano Research Energy, 2025, 5, e9120200
DOI: 10.26599/NRE.2025.9120200

Lean‐Water Gel Electrolyte Enables Zinc Ion Battery at −70 °C

Zeping Liu, Yu Zhang, Meng Li, Haoran Li, Jiachi Zhang, Yu Zhao, Guangning Xu, Jie Hu, Tiesong Lin and Naiqing Zhang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202511520

High-Voltage-Resistant Highly Stable Solid Polymer Electrolyte via In Situ Integrated Construction with Fast Ion Migration

Jianzhou Lin, Weijian Xu, Weiliang Dong, Jiji Tan, Ruixue Wang, Zhili Zhang, Qiang Liu, Gang Yin, Caizhen Zhu, Jian Xu and Lei Tian

ACS Appl. Mater. Interfaces, 2025, 17, 7750
DOI: 10.1021/acsami.4c18432

Lean‐Water Gel Electrolyte Enables Zinc Ion Battery at −70 °C

Zeping Liu, Yu Zhang, Meng Li, Haoran Li, Jiachi Zhang, Yu Zhao, Guangning Xu, Jie Hu, Tiesong Lin and Naiqing Zhang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202511520

Weakly Solvating Electrolytes for Safe and Fast-Charging Sodium Metal Batteries

Mingzhu Wu, Mingchen Yang, Jiangtao Yu, Xinyu Ma, Shipeng Sun, Yupo She, Jinhua Yang, Xiuyang Zou, Yin Hu and Feng Yan

J. Am. Chem. Soc., 2024, 146, 35229
DOI: 10.1021/jacs.4c12353

“Rigid Exterior, Soft Interior” Design Enables High‐Voltage Polyether Electrolytes for Quasi‐Solid‐State Batteries

Song Duan, Lifen Zhang, Yun Zheng, Zhenghao Li, Zewen Liu, Can Liao, Hongyao Wang, Wei Yan and Jiujun Zhang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202502728

Anion Modulation: Enabling Highly Conductive Stable Polymer Electrolytes for Solid‐State Li‐Metal Batteries

Liyi Zhao, Qingyu Dong, Yueqi Wang, Guoyong Xue, Xuechun Wang, Zhiyun Li, Hui Shao, Hongwei Chen, Yanbin Shen and Liwei Chen

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202412280

Why Will Polymers Win the Race for Solid‐State Batteries?

Zhiyong Li, Sisi Peng, Lu Wei and Xin Guo

Advanced Science, 2025, 12
DOI: 10.1002/advs.202510481

Garnets Initiate Grafting of Methyl Methacrylate Brushes onto Fluoropolymers for Electrochemically Stable and Fast‐Ion‐Conducting Composite Solid‐State Electrolytes

Xiong Xiong Liu, Pengcheng Yuan, Haotian Zhang, Yuan Zhang, Mufan Cao, Min Gao, Yaping Wang, Tomasz Wejrzanowski, Wei Zhang, Long Pan and ZhengMing Sun

ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202500044

Cyclic ethers-based solid electrolyte derived from in situ ring-opening polymerization strategy

Wubin Du, Yong Wu, Hao Cheng, Ran Bu, Kang Shen, Yuanzhong Tan, Zhijun Wu, Hongge Pan, Yifan Wang and Yingying Lu

Green Energy & Environment, 2025, 10, 1359
DOI: 10.1016/j.gee.2024.09.005

Polymerized-ionic-liquid-based solid polymer electrolyte for ultra-stable lithium metal batteries enabled by structural design of monomer and crosslinked 3D network

Lingwang Liu, Jiangyan Xue, Yiwen Gao, Shiqi Zhang, Haiyang Zhang, Keyang Peng, Xin Zhang, Suwan Lu, Shixiao Weng, Haifeng Tu, Yang Liu, Zhicheng Wang, Fengrui Zhang, Daosong Fu, Jingjing Xu, Qun Luo and Xiaodong Wu

Materials Reports: Energy, 2025, 5, 100311
DOI: 10.1016/j.matre.2024.100311

Phase separation enables dual ionic and thermal transport in solid‐state cathodes

Guangzeng Cheng, Yonghui Wang, Ziwei Lu, Jing Shi, Jingwei Chen, Weiqian Tian, Yue Zhu, Danqi He, Jingyi Wu and Huanlei Wang

InfoMat, 2026
DOI: 10.1002/inf2.70135

In-situ polymerization technology for all-solid state lithium batteries: Current status and future development

Zhaojun Chen, Yongqi Wang, Yongshun Liang, Liang Shan, Ying Wang, Jiyue Hou, Ziyi Zhu, Xue Li and Yiyong Zhang

Chinese Chemical Letters, 2026, 37, 112020
DOI: 10.1016/j.cclet.2025.112020

Construction of self-supporting PDOL electrolyte membranes for stable solid-state lithium metal batteries

Wei Zhang, WenSheng Tian, Xue Chen, Sen Ma, Xing Chen, QingBo Li, YangJie Liu, XiaoMeng Wu, ZhenHai Wen, YongMin Wu and Xiang Hu

Journal of Colloid and Interface Science, 2025, 699, 138224
DOI: 10.1016/j.jcis.2025.138224

Slide‐Crosslinked Polyrotaxane Topological Networks: Quasi‐Solid Electrolyte for High‐Voltage Lithium Metal Batteries

Huirong Zhu, Xiaoyue Zeng, Xuewei Liu, Jiaxing Zhu, Jinghao Hua, Jinle Lan, Yunhua Yu and Xiaoping Yang

Advanced Science, 2025, 12
DOI: 10.1002/advs.202508598

In-situ construction of solid polymer electrolyte with regulated Li-polymer interaction for high-performance solid-state Li metal batteries

Tongbin Zhang, Yan Wang, Xiaoen Wang, Dan Luo, Shufeng Jia, Xuancheng Liu, Yongguang Zhang and Zhongwei Chen

Nano Energy, 2025, 139, 110915
DOI: 10.1016/j.nanoen.2025.110915

Dilute Electrolytes with Fluorine‐Free Ether Solvents for 4.5 V Lithium Metal Batteries

Yusi Yang, Xiaofang Wang, Jiacheng Zhu, Lulu Tan, Nan Li, Yifan Chen, Linlin Wang, Ziqiang Liu, Xiayin Yao, Xuefeng Wang, Xiao Ji and Yujie Zhu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202409193

In Situ Electrochemical Polymerization of Cathode Electrolyte Interphase Enabling High‐Performance Lithium Metal Batteries

Shipeng Sun, Jiangtao Yu, Xinyu Ma, Pengda Fang, Mingchen Yang, Jinhua Yang, Mingzhu Wu, Yin Hu and Feng Yan

Small, 2024, 20
DOI: 10.1002/smll.202403145

Interphase Optimum via Synergistic Effect of Poly(1,3‐dioxolane) Electrolytes and Lithium Difluorophosphate for Stable Lithium Metal Batteries

Anyi Hu, Zhu Liao, Qirui Yang, Jun Huang, Zhuangzhuang Wei, Yukun Sun, Enyou Zhao, Zhengxi Zhang, Li Yang, Nagahiro Saito and Akihiro Orita

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202410282

Simultaneously boosting ionic conductivity, Li+ transference number and oxidative stability in solid polymer electrolytes via ionic coordination regulation

Guoyong Xue, Jie Lu, Yulu He, Ruilong Liu, Qiuyi Zhang, Nannan Qin, Chenji Hu, Fuqiang Huang and Liwei Chen

Journal of Energy Chemistry, 2026, 116, 617
DOI: 10.1016/j.jechem.2026.01.022

Improved gel polymer electrolyte via imidazolium ionic liquid for stabilizing the interface of Li metal batteries

Xiuling Dong, Xinyi Ge, Wei Chen, Shuangqing Li, Zheng Xing, Qingguo Zhang and Zhong-Xia Wang

Polymer, 2025, 334, 128766
DOI: 10.1016/j.polymer.2025.128766

Multifunctional Subnanowires Modulating In Situ Polymerization for High-Voltage Solid-State Batteries

Haoran Xu, Hong Zhang, Wei Peng, Shijie Feng, Chenhui Dong, Zixin Xiao, Wei Yang, Ahmed Eissa Abdelmaoula, Salah Abdelghany Eleissawy Salman, Chunhua Han and Lin Xu

ACS Appl. Mater. Interfaces, 2025, 17, 33796
DOI: 10.1021/acsami.5c00588

A Low‐Concentration All‐Phosphate Electrolyte for High‐Voltage and High‐Safety Lithium‐Ion Batteries

Jiawei Lai, Xueyi Zeng, Yuxin Yao, Chao Xu, Qianhui He, Rui Qiu, Wenming Yang, Jiahui Chen, Kui Ding, Liang Ma, Luyi Chen, Atsuo Yamada and Qifeng Zheng

Advanced Materials, 2026, 38
DOI: 10.1002/adma.202521034

Terminally functionalized polymer electrolytes with enhanced interfacial compatibility for robust solid-state lithium metal batteries

Zhiyuan Lin, Yunhang Li, Wenbin Zhang, Guanghua Guo, Weihan Chen, Li Zhang, Shanran Yang, Yonggao Xia and Guofa Cai

Journal of Materials Science & Technology, 2026, 247, 119
DOI: 10.1016/j.jmst.2025.04.075

Solid polymer electrolytes regulated by ion-dipole interactions for high voltage lithium batteries

Tao Chen, Yuncong Liu, Zhekai Jin, Lin Sun, Zeyu Liu, Hao Xu, Zhiguo Zhao and Chao Wang

Giant, 2024, 19, 100310
DOI: 10.1016/j.giant.2024.100310

Understanding Electrolytes and Interface Chemistry for Sustainable Nonaqueous Metal–CO2 Batteries

Bijiao He, Yunnian Ge, Fang Zhang, Huajun Tian, Yan Xin, Yong Lei and Yang Yang

Nano-Micro Lett., 2025, 17
DOI: 10.1007/s40820-025-01801-5

In Situ Polymerized Polyfluorinated Crosslinked Polyether Electrolytes for High‐Voltage Lithium Metal Batteries

Shimei Li, Hu Hong, Xinru Yang, Dedi Li, Qi Xiong, Dechao Zhang, Shixun Wang, Zhaodong Huang, Haiming Lv and Chunyi Zhi

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202504333

Designing Isocyanate‐Containing Elastomeric Electrolytes for Antioxidative Interphases in 4.7 V Solid‐State Lithium Metal Batteries

Seongmin Kim, Michael J. Lee, Seung Ho Kwon, Jinseok Park, Youyoung Byun, Jaeyoung Choi, Hyeonseok Seong, Hyun Soo Kwon, Eunji Lee, Seung Woo Lee and Bumjoon J. Kim

Advanced Energy Materials, 2024, 14
DOI: 10.1002/aenm.202403846

Regulating the Solvation Structure in Polymer Electrolytes for High‐Voltage Lithium Metal Batteries

Yuncong Liu, Zhekai Jin, Zeyu Liu, Hao Xu, Furong Sun, Xue‐Qiang Zhang, Tao Chen and Chao Wang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202405802

Selective interfacial polymerization improves reversibility of Si anodes

Wen Yang, Shuwei Li, You Liu, Yanyan Li, Ping Jiang, Xiaobo Hong, Gaofeng Li, Bo Fan, Fang Chen, Liangdong Lin, Zhijun Qiao and Dianbo Ruan

Chemical Engineering Journal, 2025, 514, 163168
DOI: 10.1016/j.cej.2025.163168

Generative Artificial Intelligence Navigated Development of Solvents for Next Generation High‐Performance Magnesium Batteries

Xiang Gao, Ao‐Qi Yang, Wen‐Bei Yu, Jia‐Cong Zhou, Mao‐Jun Pei, Jia‐Cheng Chen, Wei Yan, Guo‐Qiang Luo, Yao Liu, Jian‐Hua Xiao and Jiujun Zhang

Advanced Materials, 2026, 38
DOI: 10.1002/adma.202510083

Closed-loop recyclable interfacial growth polymerization enables scalable and economical quasi-solid-state lithium metal batteries

Xinyang Li, Jie Feng, Na Li, Fengxu Zhen, Yingbin Wu, Yanan Li, Xiaofeng Cui, Dongyang Zhang, Yuankun Wang and Shujiang Ding

Joule, 2026, 10, 102276
DOI: 10.1016/j.joule.2025.102276

Solvent-coordination-regulated gel polymer electrolyte for stable high-voltage lithium metal batteries

Daiqian Chen, Ziheng Zhang, Jie Wang, Xinsheng Li, Yu Wu, Hesheng Yu, Fei Ma, Fuyong Liu, Jing Feng, Liping Wang, Yuping Wu, Fei Wang, Yuanfu Chen and Jiarui He

eScience, 2026, 100568
DOI: 10.1016/j.esci.2026.100568

In Situ Gel Polymer Electrolyte with Rapid Li+ Transport Channels and Anchored Anion Sites for High‐Current‐Density Lithium‐Ion Batteries

Xunzhi Miao, Jianhe Hong, Shuo Huang, Can Huang, Yushi Liu, Min Liu, Quanquan Zhang and Hongyun Jin

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202411751

Long‐Lasting Solid‐State Aluminum Battery with High‐Areal‐Capacity Enabled by In Situ Polymerization Strategy

Gangyong Li, Zhaodi Wang, Zhi Li, Xiaoyi Zheng, Yucan Zhu, Bao Zhang and Zhaohui Hou

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202416755

In-situ collaborative design of crosslinking and fluorination toward poly(1,3-dioxolane) for high-performance semi-solid lithium metal batteries

Dezhi Yang, Yaqiong Zhu, Yanan Yang, Yiyang Sun and Tao Zhang

Journal of Energy Chemistry, 2026, 112, 880
DOI: 10.1016/j.jechem.2025.08.090

SiO2-Decorated-Montmorillonite reinforced Poly(1,3-dioxolane) as a multifunctional solid electrolyte for High-Performance lithium batteries

Guojian Lin, Tianqi Yang, Haiyuan Zhang, Hongjie Wang, Wenkui Zhang, Hui Huang, Yang Xia, Xinhui Xia, Xinyong Tao and Jun Zhang

Chemical Engineering Journal, 2024, 488, 151161
DOI: 10.1016/j.cej.2024.151161

Polyether-based composite solid-state electrolyte to realize stable high-rate cycling for high-voltage lithium metal batteries at room temperature

Xinhao Li, Chen Wang, Wenzheng Nan, Sikan Peng, Jin Liu and Shaojiu Yan

Materials Today Chemistry, 2024, 40, 102219
DOI: 10.1016/j.mtchem.2024.102219

“Rigid Exterior, Soft Interior” Design Enables High‐Voltage Polyether Electrolytes for Quasi‐Solid‐State Batteries

Song Duan, Lifen Zhang, Yun Zheng, Zhenghao Li, Zewen Liu, Can Liao, Hongyao Wang, Wei Yan and Jiujun Zhang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202502728

In‐Situ Polymerized Solid/Quasi‐Solid Polymer Electrolyte for Lithium‐Metal Batteries: Recent Progress and Perspectives

Hangyu Zhang, Xijun Xu, Weizhen Fan, Jingwei Zhao and Yanping Huo

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202402798

Stabilizing Residual Monomers within In Situ Polymerized Electrolytes for High-Voltage Lithium Metal Batteries

Zejun Sun, Jinlin Yang, Yao Wu, Fanbin Meng, Yuxiang Niu, Hongfei Xu, Yupeng Zhu, Bolong Hong, Zhiyu Chen, Jinlong Zhu, Qian He, Gang Wu and Wei Chen

J. Am. Chem. Soc., 2025, 147, 18064
DOI: 10.1021/jacs.5c03911

Strong Lewis-acid coordinated PEO electrolyte achieves 4.8 V-class all-solid-state batteries over 580 Wh kg−1

Hanwen An, Menglu Li, Qingsong Liu, Yajie Song, Jiaxuan Liu, Zhihang Yu, Xingjiang Liu, Biao Deng and Jiajun Wang

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-53094-8

Molecular Interlocking Multidimensional Modulations of Cathode‐Electrolyte Interface for Constructing High Energy Density Quasi‐Solid‐State Batteries

Xinyou He, Haozhe Qin, Junxiang Liu, Jiaqi Wang, Zhiming Xiao, Lei Ming, Tongchao Liu, Khalil Amine and Xing Ou

Advanced Energy Materials, 2025, 15
DOI: 10.1002/aenm.202502363

In-situ curing poly(N,N'-Methylenebisacrylamide)-based composite electrolyte reinforced with high-strength glass fiber skeleton for solid state lithium ion batteries

Yuxiang Zhang, Shijie Lu, Zhikun Zhao, Xinyu Zhang, Haijian Lv, Zhuolin Yang, Wenbin Sun, Man Xie and Daobin Mu

Chemical Engineering Journal, 2024, 487, 150474
DOI: 10.1016/j.cej.2024.150474

Recent progress in gel polymer electrolyte for lithium metal batteries

Changxing Han, Xiong Shui, Guansheng Chen, Gaojie Xu, Jun Ma, Shanmu Dong, Shitao Wang, Xinhong Zhou, Zili Cui, Lixin Qiao and Guanglei Cui

Giant, 2024, 20, 100337
DOI: 10.1016/j.giant.2024.100337

Directionally Aligned “Mechanical Balance” Design Enables Near-Frictionless Li+ Transport in Polymer Electrolytes

Song Duan, Zongtao Lu, Yun Zheng, Xiang Liu, Lifen Zhang, Zhenghao Li, Zewen Liu, Yiyuan Luo, Bingsen Qin, Yao Liu, Maojun Pei, Jiaming Xu, Xiuzhou Lin, Wei Yan and Jiujun Zhang

J. Am. Chem. Soc., 2026, 148, 2972
DOI: 10.1021/jacs.5c13961

Hierarchical composite solid electrolyte for stabilizing lithium anode and constructing cathode ion conductive network

Huanhui Chen, Xing Cao, Liang Yu, Xiangzhong Ren, Gaowei Zhang, Shoujing Wei, Ya Liu, Liubiao Zhong and Yejun Qiu

Journal of Energy Storage, 2024, 100, 113602
DOI: 10.1016/j.est.2024.113602

High Li+ Coordination Entropy Reducing the Interaction between Li+ and Polymer Chains to Improve Li+ Transport for Solid‐State Lithium Metal Batteries

Shengbo Yang, Jin Yan, Jia Chou, Hong Zhang, Zhixing Wang, Huajun Guo, Xinhai Li, Guochun Yan, Wenjie Peng, Guangchao Li, Zhenghui Liu, Jiexi Wang, Ruizhi Yu and Hui Duan

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202502741

A modified separator based on ternary mixed-oxide for stable lithium metal batteries

Zhanghua Fu, Guang Xia, Jiajia Ye, Zhiqiang Zheng, Jing Wang, Zhongwen Zhang, Cheng Hu and Chuanzhong Chen

Journal of Colloid and Interface Science, 2025, 679, 830
DOI: 10.1016/j.jcis.2024.10.127

Selectively Coordinating Solid Polymer Electrolytes Enable Nonmodified 4.6 V-LiCoO2 for High-Capacity and Long-Cycling Lithium Batteries

Lingfei Tang, Qiang Li, Xiaoxuan Liu, Yawen Xie, Liang Zhang, Yixiao Zhang, Qinfeng Zheng, Changqi Ma, Qi Chen and Liwei Chen

ACS Energy Lett., 2025, 10, 5447
DOI: 10.1021/acsenergylett.5c02202

In‐Situ Cross‐linked F‐ and P‐Containing Solid Polymer Electrolyte for Long‐Cycling and High‐Safety Lithium Metal Batteries with Various Cathode Materials

Nuo Xu, Yang Zhao, Minghan Ni, Jie Zhu, Xingchen Song, Xingqi Bi, Jinping Zhang, Hongtao Zhang, Yanfeng Ma, Chenxi Li and Yongsheng Chen

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202404400

Helical Branched Gel Polymer Electrolytes for 4.6V‐Class Lithium Metal Batteries

Wang Xu, Anjun Hu, Ruixin Zheng, Yuanjian Li, Kai Chen, Jingze Chen, Zhen Wang, Ruize Xu, Jian Wang, Fei Li, Jianping Long and Feixiang Wu

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202511135

Construction of solid-state lithium batteries with high energy density and high safety by in-situ polymerization

Zhenxiang Zhu, Mingzhe Xue, Xianbin Wu, Jieyun Zheng, Qiyu Wang, Cunman Zhang and Zhen Geng

Chemical Engineering Journal, 2025, 514, 163402
DOI: 10.1016/j.cej.2025.163402

Dilute Electrolytes with Fluorine‐Free Ether Solvents for 4.5 V Lithium Metal Batteries

Yusi Yang, Xiaofang Wang, Jiacheng Zhu, Lulu Tan, Nan Li, Yifan Chen, Linlin Wang, Ziqiang Liu, Xiayin Yao, Xuefeng Wang, Xiao Ji and Yujie Zhu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202409193

Solid–Polymer–Electrolyte Interphase Inductively Formed by Surface Chemistry to Stabilize the High Ni Cathode in Sulfide‐Based All‐Solid‐State Lithium Batteries

Guo Tang, Gengzhong Lin, Yicheng Deng, Hui Li, Yuliang Cao, Yongjin Fang, Hanxi Yang and Xinping Ai

Carbon Energy, 2026, 8
DOI: 10.1002/cey2.70076

In-situ polymerized ether-ester copolymer electrolytes with regulated solvation structure for quasi-solid-state lithium metal batteries

Guocheng Wang, Yongjie Dan, Xinyu Lin, Qi Liu, Yanhua Niu and Guangxian Li

Chemical Engineering Journal, 2025, 525, 170706
DOI: 10.1016/j.cej.2025.170706

A crosslinked polycarbonate-based hybrid electrolyte enhanced by covalent bonding-driven MOF for dendrite-free solid-state lithium metal batteries

Jiaxing Zhu, Xuewei Liu, Xiaoyue Zeng, Huirong Zhu, Shuanglin Jia, Yufeng Qiao, Luyao Ren, Jianlin Long, Jinle Lan, Yunhua Yu and Xiaoping Yang

Journal of Colloid and Interface Science, 2025, 697, 137993
DOI: 10.1016/j.jcis.2025.137993

Opportunities for Polymer Electrolytes in Sustaining High‐Voltage Lithium Metal Batteries

Minkang Jiang, Yuhao Ma, Chuang Bao, Hao Wang, Fengrui Zhang, Heng Zhang and Liping Wang

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202523096

Tailoring polymer electrolyte solvation for 600 Wh kg−1 lithium batteries

Xue-Yan Huang, Chen-Zi Zhao, Wei-Jin Kong, Nan Yao, Zong-Yao Shuang, Pan Xu, Shuo Sun, Yang Lu, Wen-Ze Huang, Jin-Liang Li, Liang Shen, Xiang Chen, Jia-Qi Huang, Lynden A. Archer and Qiang Zhang

Nature, 2025, 646, 343
DOI: 10.1038/s41586-025-09565-z

Practical 4.7 V solid-state 18650 cylindrical lithium metal batteries with in-situ fabricated localized high-concentration polymer electrolytes

Xingchen Song, Ruiqi Zhao, Jie Zhu, Jinping Zhang, Nuo Xu, Jie Liu, Yansong Liu, Hongtao Zhang, Yanfeng Ma, Chenxi Li and Yongsheng Chen

National Science Review, 2025, 12
DOI: 10.1093/nsr/nwaf016

Reshaping Li+-Polyethylene Glycol Interactions to Boost Li+ Transport in Solid Polymer Electrolytes

Guang Chen, Shun-Ran Peng, Ying Du, Wei Liu, Zhe Wang, Zong-Bin Lu, Fan Gao, Wei-Qiang Huang, Long-Hai Wang, Chun-Yan Hong, Ze Zhang and Ye-Zi You

ACS Appl. Mater. Interfaces, 2025, 17, 59715
DOI: 10.1021/acsami.5c10559

A binary contact-curved nano-shield design for separators to suppress dendrite formation for stable lithium-metal batteries

Manxian Li, Ziwei Yuan, Xiaochuan Chen, Junxiong Wu, So Yeon Kim, Xiaoyan Li, Jingyue Zhao, Zulin Li, Xuan Li, Lijuan Tong, Chuanping Li, Yiu-Wing Mai and Yuming Chen

Energy Storage Materials, 2025, 82, 104613
DOI: 10.1016/j.ensm.2025.104613

In Situ Electrochemical Polymerization Enabling High‐Performance Quasi‐Solid‐State Batteries

Jiacheng Zhu, Bingyun Ma, Cong Zhong, Ziwei Wang, Chunxi Tian, Suting Weng, Shuwei Li, Mengyan Cao, Zhaoxiang Wang, Yejing Li, Hong Li, Tao Cheng and Xuefeng Wang

Advanced Energy Materials, 2026, 16
DOI: 10.1002/aenm.202504413

Nano LiF-Enabled In Situ Synergistic Catalytic Polymeric Electrolytes for Stable Lithium Metal Batteries

Wenqin Ma, Xue Wang, Yuzhou Bai, Wujie Dong, Yufeng Tang, Ling Zhang and Fuqiang Huang

ACS Appl. Mater. Interfaces, 2025, 17, 8682
DOI: 10.1021/acsami.4c21349

An Asymmetric Electrolyte with Dielectric Polarization for High‐Energy‐Density Solid‐State Lithium Metal Batteries

Yuezhen Mao, Zihan Zhu, Zhijun Zhang and Chunwen Sun

Small, 2025, 21
DOI: 10.1002/smll.202507467

Entropy‐Driven Modulation of Ion Clustering and Polymer Crystallinity for Low‐Temperature Lithium Metal Batteries

Junze Guo, Weifeng Zou, Yaoxian Song, Xuyin Zhu, Haodong Zhou, Weidong Zhang, Fanghao Zhou and Tiefeng Li

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202511612

Anion‐Trapping Induced Solvation Optimization for High‐Performance Polyester‐Based Quasi‐Solid‐State Lithium Metal Batteries

Yizheng Ma, Shengtao Xu, Xiaoyu Guo, Zhimeng Sheng, Jinting Xu, Yan Zhang, Guodong Qi, Shuaiqi Gong, Qunjie Xu, Penghui Shi, Sheng Zhu and Yulin Min

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202516507

A MOF-Reinforced Hybrid Crosslinked Quasi-Solid Electrolytes via In Situ Polymerization for Stable Lithium Metal Batteries

Shen Liu, Yiyuan Yan, Shichao Zhang, Dezhi Yan, Chao Jin, Shuai Yin, Qiang Lu, Wangwei Ren, Qianfan Zhang and Yalan Xing

Energy Storage Materials, 2026, 86, 104944
DOI: 10.1016/j.ensm.2026.104944

Regulating the Solvation Structure in Polymer Electrolytes for High‐Voltage Lithium Metal Batteries

Yuncong Liu, Zhekai Jin, Zeyu Liu, Hao Xu, Furong Sun, Xue‐Qiang Zhang, Tao Chen and Chao Wang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202405802

High-modulus solid electrolyte interphase layer with gradient composition enables long-cycle all-solid-state lithium-sulfur batteries

Huanhuan Duan, Jinhai Liu, Jiafeng He, Linyuan Ma, Yuanfu Deng and Guohua Chen

Journal of Energy Chemistry, 2024, 98, 87
DOI: 10.1016/j.jechem.2024.06.026

The interface compatibility between solid-state electrolytes and lithium/silicon anodes: Challenges, recent progress and perspectives

Jingwen Cui, Ling Zhang, Meng Wang, Yuanxing Zhang, Tao Liu, Jiaying Bi, Borong Wu, Yuefeng Su and Feng Wu

Journal of Energy Storage, 2024, 101, 113774
DOI: 10.1016/j.est.2024.113774

In situ polymerized solid polymer electrolyte for safe winding-type lithium metal battery

Runyi Dai and Guangdi Hu

Journal of Alloys and Compounds, 2025, 1033, 180804
DOI: 10.1016/j.jallcom.2025.180804

Polymer Electrolytes for Compatibility With NCM Cathodes in Solid‐State Lithium Metal Batteries: Challenges and Strategies

Zhiyuan Lin, Yunhang Li, Peipei Ding, Chenxiao Lin, Fang Chen, Ruoxin Yu and Yonggao Xia

Battery Energy, 2025, 4
DOI: 10.1002/bte2.20240063

Coordination‐Induced Plastic Ceramic‐Ether Coupling Electrolyte for High‐Voltage Lithium Metal Batteries

Ya‐Nan Yang, Zhi‐Qian Hou, De‐Zhi Yang, Ya‐Qiong Zhu, Yu Zhuang, Ye Zeng, Xi Gong and Tao Zhang

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202506241

Molecular design for in-situ polymerization of hybrid polymer electrolyte enables high-voltage and high-energy-density quasi-solid-state lithium metal batteries

Qi Liu, Yongjie Dan, Yanhua Niu and Guangxian Li

Energy Storage Materials, 2025, 78, 104277
DOI: 10.1016/j.ensm.2025.104277

Low‐Concentration Electrolyte Engineering for Rechargeable Batteries

Zijun Wang, Xiaolin Guo, Yueyao Dong, Wenjie Qu, Ke Wang, Liwei Dong, Chunhui Yang, Zuotao Lei and Jia‐Yan Liang

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202501215

Local charge homogenization strategy enables ultra-high voltage tolerance of polyether electrolytes for 4.7 V lithium metal batteries

Yuanlong Wu, Piao Luo, Kexin Su, Mao Yu, Xin Song, Lianzhan Huang, Shaocong Zhang, Huiyu Song, Li Du, Weishu Liu and Zhiming Cui

National Science Review, 2025, 12
DOI: 10.1093/nsr/nwae436

Reconstructing Inorganic‐Rich Interphases by Nonflammable Electrolytes for High‐Voltage and Low‐Temperature LiNi0.5Mn1.5O4 Cathodes

Xin‐Yu Fan, Mengting Liu, Tian‐Lin Chen, Wenyu Hao, Zhigang Cao, Nan Jiang, Qiang Liu, Yi‐Hu Feng, Hao Qin, Si‐Fan Chen, Sufu Liu, Xiao Ji, Yao Xiao, Shulei Chou and Peng‐Fei Wang

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202400996

Enabling fast ion conduction at both interface and bulk for low-temperature quasi-solid-state batteries via fluorinated weak-solvent additives

Fangrun He, Zhaoxu Qiu, Naikuan Zhang and Na Li

Chemical Engineering Journal, 2025, 524, 169748
DOI: 10.1016/j.cej.2025.169748

Enthalpy‐Driven Molecular Engineering Enables High‐Performance Quasi‐Solid‐State Electrolytes for Long Life Lithium Metal Batteries

Zilong Wang, Longyun Shen, Yilin Ma, Ho Mei Law, Shengjun Xu, Yixin Bi, Matthew J. Robson, Yuhao Wang, André Gröschel, Qing Chen and Francesco Ciucci

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202419335

Collaborative Design of Multi‐Molecules Boosts the Performance of the Full‐Range Three‐Dimensional Quasi‐Solid Polymer Electrolyte for Lithium Metal Batteries

Hong Teng, Aotian Zhang, Ying Liu, Shiyuan Zhang, Nan Zhang, Tianzong Ma, Ruonan Jing, Haiming Xie and Liqun Sun

Small, 2025, 21
DOI: 10.1002/smll.202501226

Isocyanurate‐Derivative Enables Highly Compatible Poly‐Dioxane Electrolyte for Dendrite‐Free Li Metal Batteries

Peng Wang, Yaru Liu, Jie Cui, Long Zhao, Dong Li, Yunfei Du and Hao Li

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202414430

Trilogy design of cross-linked polyether electrolytes for high-voltage and wide-temperature lithium metal batteries

Hanqin Zou, Wenming Yang, Yihao Wang, Zitao Feng, Jingwen Lai, Guangchao Luo, Yang Liu, Ye Xiao, Jiawei Lai, Yajun Yue, Luyi Chen and Qifeng Zheng

eScience Energy, 2026, 2, 100025
DOI: 10.1016/j.esen.2025.100025