Highly selective palladium-catalyzed one-pot, five-fold B–H/C–H cross coupling of monocarboranes with alkenes

Yunjun Shen, Kang Zhang, Xuewei Liang, Rakesh Dontha and Simon Duttwyler

Chem. Sci., 2019, 10, 4177
DOI: 10.1039/C9SC00078J

Impact of deboronation on the electronic characteristics of closo-o-carborane: intriguing photophysical changes in triazole-appended carboranyl luminophores

Mingi Kim, Sehee Im, Chan Hee Ryu, Seok Ho Lee, Ju Hyun Hong and Kang Mun Lee

Dalton Trans., 2021, 50, 3207
DOI: 10.1039/D0DT04038J

Highly efficient dual-state emission and two-photon absorption of novel naphthalimide functionalized cyanostilbene derivatives with finely tuned terminal alkoxyl groups

Yingyong Ni, Longmei Yang, Lin Kong, Chengyuan Wang, Qichun Zhang and Jiaxiang Yang

Mater. Chem. Front., 2022, 6, 3522
DOI: 10.1039/D2QM00937D

A ferrocene–carborane–BODIPY conjugate: synthesis, photophysical, electrochemical and computational analysis

Supriya Routray, Sikha Sayantani, Laxmipriya Nayak, Subhadeep Acharya, Saiprakash Rout, K. S. K. Varadwaj and Rashmirekha Satapathy

New J. Chem., 2025, 49, 15784
DOI: 10.1039/D5NJ01973G

Solid-state temperature-dependent luminescence of C,C′-diaryl-o-carboranes based on restriction of excited-state structural relaxation

Kazuhiro Yuhara and Kazuo Tanaka

Chem. Sci., 2025, 16, 6495
DOI: 10.1039/D5SC00875A

Experimental proof for emission annihilation through bond elongation at the carbon–carbon bond in o-carborane with fused biphenyl-substituted compounds

Junki Ochi, Kazuo Tanaka and Yoshiki Chujo

Dalton Trans., 2021, 50, 1025
DOI: 10.1039/D0DT03618H

Anthracene-(aminomethyl)phenylboronic acid ester-immobilized glass substrates as fluorescent sensing materials based on photo-induced electron transfer for detection and visualization of water

Kazuki Tao, Keiichi Imato and Yousuke Ooyama

Sens. Diagn., 2024, 3, 631
DOI: 10.1039/D3SD00264K

An AIE fluorescent switch with multi-stimuli responsive properties and applications for quantitatively detecting pH value, sulfite anion and hydrostatic pressure

Tingting Lin, Xing Su, Kai Wang, Minjie Li, Hongwei Guo, Lulu Liu, Bo Zou, Yu-Mo Zhang, Yifei Liu and Sean Xiao-An Zhang

Mater. Chem. Front., 2019, 3, 1052
DOI: 10.1039/C8QM00544C

Carborane bridged ferrocenyl conjugated molecules: synthesis, structure, electrochemistry and photophysical properties

Jian-Feng Yan, Gai-Ge Zhu, Ye Yuan, Cai-Xia Lin, Shu-Ping Huang and Yao-Feng Yuan

New J. Chem., 2020, 44, 7569
DOI: 10.1039/D0NJ00826E

Alteration of intramolecular electronic transition via deboronation of carbazole-based o-carboranyl compound and intriguing ‘turn-on’ emissive variation

Seok Ho Lee, Min Sik Mun, Mingi Kim, Ji Hye Lee, Hyonseok Hwang, Wonchul Lee and Kang Mun Lee

RSC Adv., 2021, 11, 24057
DOI: 10.1039/D1RA03716A

Engineering visible-to-ultraviolet emission switching of benzothiazole-based mechanoresponsive materials

Riku Yoshino, Kazuki Kobayashi, Peiyuan Yang, Hiroki Fukumoto, Motohiro Yasui, Shigeyuki Yamada, Tsutomu Konno and Masato Morita

CrystEngComm, 2025, 27, 5398
DOI: 10.1039/D5CE00379B

Fluorescence sensors for detection of water based on tetraphenylethene–anthracene possessing both solvatofluorochromic properties and aggregation-induced emission (AIE) characteristics

Yuta Mise, Keiichi Imato, Takashi Ogi, Nao Tsunoji and Yousuke Ooyama

New J. Chem., 2021, 45, 4164
DOI: 10.1039/D1NJ00186H

Strategic molecular design of closo-ortho-carboranyl luminophores to manifest thermally activated delayed fluorescence

Dong Kyun You, Hyunhee So, Chan Hee Ryu, Mingi Kim and Kang Mun Lee

Chem. Sci., 2021, 12, 8411
DOI: 10.1039/D1SC00791B

Tetraphenylethene–anthracene-based fluorescence emission sensor for the detection of water with photo-induced electron transfer and aggregation-induced emission characteristics

Emiko Nishimoto, Yuta Mise, Takuma Fumoto, Saori Miho, Nao Tsunoji, Keiichi Imato and Yousuke Ooyama

New J. Chem., 2022, 46, 12474
DOI: 10.1039/D2NJ01599D

Rational ligand engineering of AIE-active iridium(iii) complexes for tunable emission, reversible mechanochromism and anti-counterfeiting

Ye Li, Qian-Ting Sun, Zhen-Jian Qi, Han Gu, Ying-Chen Duan, Kai-Yue Zhao, Guo-Gang Shan and Zhong-Min Su

J. Mater. Chem. C, 2025, 13, 12225
DOI: 10.1039/D5TC01093D

Development of highly sensitive fluorescent sensor and fluorescent sensor-doped polymer films for trace amounts of water based on photo-induced electron transfer

Saori Miho, Takuma Fumoto, Yuta Mise, Keiichi Imato, Seiji Akiyama, Mio Ishida and Yousuke Ooyama

Mater. Adv., 2021, 2, 7662
DOI: 10.1039/D1MA00881A

Design for multi-step mechanochromic luminescence property by enhancement of environmental sensitivity in a solid-state emissive boron complex

Satoru Saotome, Kazumasa Suenaga, Kazuo Tanaka and Yoshiki Chujo

Mater. Chem. Front., 2020, 4, 1781
DOI: 10.1039/C9QM00719A

Fluorescent polymer films based on photo-induced electron transfer for visualizing water

Saori Miho, Keiichi Imato and Yousuke Ooyama

RSC Adv., 2022, 12, 25687
DOI: 10.1039/D2RA03894C

o-Carborane-based fluorophores as efficient luminescent systems both as solids and as water-dispersible nanoparticles

Sohini Sinha, Zsolt Kelemen, Evelyn Hümpfner, Imma Ratera, Jean-Pierre Malval, José Piers Jurado, Clara Viñas, Francesc Teixidor and Rosario Núñez

Chem. Commun., 2022, 58, 4016
DOI: 10.1039/D1CC07211K

Tricolor mechanochromic luminescence of an organic two-component dye: visualization of a crystalline state and two amorphous states

Suguru Ito, Genki Katada, Tomohiro Taguchi, Izuru Kawamura, Takashi Ubukata and Masatoshi Asami

CrystEngComm, 2019, 21, 53
DOI: 10.1039/C8CE01698D

2-Phenylpyridine- and 2-(benzo[b]thiophen-2-yl)pyridine-based o-carboranyl compounds: impact of the structural formation of aromatic rings on photophysical properties

Hyomin Jin, Hye Jin Bae, Seonah Kim, Ji Hye Lee, Hyonseok Hwang, Myung Hwan Park and Kang Mun Lee

Dalton Trans., 2019, 48, 1467
DOI: 10.1039/C8DT04367A

Tuning of the height of energy barrier between locally-excited and charge transfer states by altering the fusing position ofo-carborane in phenylnaphthalene

Junki Ochi, Takumi Yanagihara, Kazuo Tanaka and Yoshiki Chujo

Phys. Chem. Chem. Phys., 2023, 25, 11839
DOI: 10.1039/D3CP00334E

Polymer films doped with fluorescent sensor for moisture and water droplet based on photo-induced electron transfer

Takuma Fumoto, Saori Miho, Yuta Mise, Keiichi Imato and Yousuke Ooyama

RSC Adv., 2021, 11, 17046
DOI: 10.1039/D1RA02673A

Regulation of solid-state dual-emission properties by switching luminescence processes based on a bis-o-carborane-modified anthracene triad

Kazuhiro Yuhara, Kazuo Tanaka and Yoshiki Chujo

Mater. Chem. Front., 2022, 6, 1414
DOI: 10.1039/D2QM00211F

Single-component white-color photoluminescence from liquid crystal polymers: Color tuning by a combination of luminescence thermo- and mechanochromism

Osama Younis and Osamu Tsutsumi

Dyes and Pigments, 2021, 188, 109189
DOI: 10.1016/j.dyepig.2021.109189

Dual-state emissive imidazo[1,2-α]pyridines with full color emission, acidochromism, viscosity-dependent fluorescence, and bioimaging applications

Yujie Zhu, Kaihao Liao, Yigao Li, Wenjing Zhang, Bing Song, Xin-Qi Hao and Xinju Zhu

Dyes and Pigments, 2024, 224, 112004
DOI: 10.1016/j.dyepig.2024.112004

Tuning of Sensitivity in Thermochromic Luminescence by Regulating Molecular Rotation Based on Triphenylamine‐Substituted o‐Carboranes

Kenta Nishino, Kazuo Tanaka and Yoshiki Chujo

Asian J Org Chem, 2019, 8, 2228
DOI: 10.1002/ajoc.201900537

Controlling the Dual‐Emission Character of Aryl‐Modified o‐Carboranes by Intramolecular CH⋅⋅⋅O Interaction Sites

Junki Ochi, Kazuhiro Yuhara, Kazuo Tanaka and Yoshiki Chujo

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202200155

Time‐Dependent Emission Enhancement of the Ethynylpyrene‐o‐Carborane Dyad and Its Application as a Luminescent Color Sensor for Evaluating Water Contents in Organic Solvents

Kenta Nishino, Hideki Yamamoto, Junki Ochi, Kazuo Tanaka and Yoshiki Chujo

Chemistry An Asian Journal, 2019, 14, 1577
DOI: 10.1002/asia.201900396

Comparison of luminescent properties of helicene-like bibenzothiophenes with o-carborane and 5,6-dicarba-nido-decaborane

Kenta Nishino, Kazushi Hashimoto, Kazuo Tanaka, Yasuhiro Morisaki and Yoshiki Chujo

Sci. China Chem., 2018, 61, 940
DOI: 10.1007/s11426-018-9258-y

Naphthyl‐ and Quinoline‐Appended o‐Carboranyl Luminophores: Intramolecular Charge Transfer‐Based Radiative Decay Controlled by Structural Geometry around C−C Bond Axis

Chan Hee Ryu, Seok Ho Lee, Sanghee Yi, Ju Hyun Hong, Sehee Im and Kang Mun Lee

Eur J Inorg Chem, 2021, 2021, 4875
DOI: 10.1002/ejic.202100768

Conformation-Dependent Electron Donation of Nido-Carborane Substituents and Its Influence on Phosphorescence of Tris(2,2′-bipyridyl)ruthenium(II) Complex

Kyoya Uemura, Kazuo Tanaka and Yoshiki Chujo

Crystals, 2022, 12, 688
DOI: 10.3390/cryst12050688

Dual-State Emission (DSE) in Organic Fluorophores: Design and Applications

José L. Belmonte-Vázquez, Yoarhy A. Amador-Sánchez, Lizbeth A. Rodríguez-Cortés and Braulio Rodríguez-Molina

Chem. Mater., 2021, 33, 7160
DOI: 10.1021/acs.chemmater.1c02460

Metal‐Free Oxidative B−N Coupling of nido‐Carborane with N‐Heterocycles

Zhongming Yang, Weijia Zhao, Wei Liu, Xing Wei, Meng Chen, Xiao Zhang, Xiaolei Zhang, Yong Liang, Changsheng Lu and Hong Yan

Angewandte Chemie, 2019, 131, 12012
DOI: 10.1002/ange.201904940

A multifunctional quinoxalin-based AIEgen used for fluorescent thermo-sensing and image-guided photodynamic therapy

Yuanyuan Li, Qiuchen Peng, Shijun Li, Yuchen Cai, Bin Zhang, Kai Sun, Junbao Ma, Cuiping Yang, Hongwei Hou, Huifang Su and Kai Li

Sensors and Actuators B: Chemical, 2019, 301, 127139
DOI: 10.1016/j.snb.2019.127139

Correlating the Structural and Photophysical Properties of Ortho, Meta, and Para‐Carboranyl–Anthracene Dyads

Adam V. Marsh, Matthew J. Dyson, Nathan J. Cheetham, Matthew Bidwell, Mark Little, Andrew J. P. White, Colin N. Warriner, Anthony C. Swain, Iain McCulloch, Paul N. Stavrinou, Stefan C. J. Meskers and Martin Heeney

Adv Elect Materials, 2020, 6
DOI: 10.1002/aelm.202000312

Effect of Planarity of Aromatic Rings Appended to o-Carborane on Photophysical Properties: A Series of o-Carboranyl Compounds Based on 2-Phenylpyridine- and 2-(Benzo[b]thiophen-2-yl)pyridine

Hyomin Jin, Seonah Kim, Hye Jin Bae, Ji Hye Lee, Hyonseok Hwang, Myung Hwan Park and Kang Mun Lee

Molecules, 2019, 24, 201
DOI: 10.3390/molecules24010201

Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics

Kang Zhang, Yunjun Shen, Xiaoli Yang, Jiyong Liu, Tao Jiang, Nathaniel Finney, Bernhard Spingler and Simon Duttwyler

Chemistry A European J, 2019, 25, 8754
DOI: 10.1002/chem.201900584

Photophysical Properties of Spirobifluorene-Based o-Carboranyl Compounds Altered by Structurally Rotating the Carborane Cages

Seonah Kim, Hyunhee So, Ji Hye Lee, Hyonseok Hwang, Hyoshik Kwon, Myung Hwan Park and Kang Mun Lee

Molecules, 2019, 24, 4135
DOI: 10.3390/molecules24224135

Full-color-tunable AIE luminogens for 4D code, security patterns, and multicolor LEDs

Yunfei Zuo, Junkai Liu, Pei Li, Kai Li, Jacky W.Y. Lam, Decheng Wu and Ben Zhong Tang

Cell Reports Physical Science, 2023, 4, 101202
DOI: 10.1016/j.xcrp.2022.101202

Fascinating phenomena towards single-component white-light emission through luminescent thermochromism

Osama Younis, Hussain Sami, Yui Maruoka, Kyohei Hisano and Osamu Tsutsumi

Dyes and Pigments, 2021, 194, 109621
DOI: 10.1016/j.dyepig.2021.109621

Rational design for thermochromic luminescence in amorphous polystyrene films with bis‐o‐carborane‐substituted enhanced conjugated molecule having aggregation‐induced luminochromism

Keisuke Wada, Kazushi Hashimoto, Junki Ochi, Kazuo Tanaka and Yoshiki Chujo

Aggregate, 2021, 2
DOI: 10.1002/agt2.93

Direction Switching and Self‐Recovering Mechanochromic Luminescence of Anthracene‐Modified o‐Carboranes

Kazuhiro Yuhara and Kazuo Tanaka

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301189

Cu(I)-Catalyzed Cycloaddition of Vinylacetylene ortho-Carborane and Arylazides in the Design of 1,2,3-Triazolyl-Modified Vinylcarborane Fluorophores

Lidia A. Smyshliaeva, Mikhail V. Varaksin, Ekaterina I. Fomina, Muthipeedika N. Joy, Vasiliy A. Bakulev, Valery N. Charushin and Oleg N. Chupakhin

Organometallics, 2020, 39, 3679
DOI: 10.1021/acs.organomet.0c00478

Conformational emissive states in dual-state emitters with benzotriazole acceptors

Lizbeth A. Rodríguez-Cortés, Federico J. Hernández, Mario Rodríguez, Rubén A. Toscano, Arturo Jiménez-Sánchez, Rachel Crespo-Otero and Braulio Rodríguez-Molina

Matter, 2023, 6, 1140
DOI: 10.1016/j.matt.2023.01.015

Ortho‐Carborane Decorated Multi‐Resonance TADF Emitters: Preserving Local Excited State and High Efficiency in OLEDs

Taehwan Lee, Jee‐Hun Jang, Nhi Ngoc Tuyet Nguyen, Jaehoon Jung, Jeong‐Hwan Lee and Min Hyung Lee

Advanced Science, 2024, 11
DOI: 10.1002/advs.202309016

Fluorescence properties of stable porous Zr(IV)-metal-organic framework based on fluorescent imidazolate-ligand

Huizhi Yang, Yuxin Xie, Xingjuan Zhong and Lei Li

Inorganic Chemistry Communications, 2023, 150, 110522
DOI: 10.1016/j.inoche.2023.110522

Improvement of Solid‐State Excimer Emission of the Aryl–Ethynyl‐o‐Carborane Skeleton by Acridine Introduction

Junki Ochi, Kazuo Tanaka and Yoshiki Chujo

Eur J Org Chem, 2019, 2019, 2984
DOI: 10.1002/ejoc.201900212

Recent Progress in the Development of Solid‐State Luminescent o‐Carboranes with Stimuli Responsivity

Junki Ochi, Kazuo Tanaka and Yoshiki Chujo

Angewandte Chemie, 2020, 132, 9925
DOI: 10.1002/ange.201916666

Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation

Furong Lin, Jing-Lu Yu, Yunjun Shen, Shuo-Qing Zhang, Bernhard Spingler, Jiyong Liu, Xin Hong and Simon Duttwyler

J. Am. Chem. Soc., 2018, 140, 13798
DOI: 10.1021/jacs.8b07872

Rational design of 1, 2, 4, 5-tetraphenyl-1H-imidazole-based AIEgens with tunable intramolecular charge transfer and restricted intramolecular rotation processes for multifunctional sensing

Zhenmin Yin, Henan Hou, Ruishan Ren, Lingyu Zeng, Qi Feng and Haitao Yu

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2025, 329, 125513
DOI: 10.1016/j.saa.2024.125513

Metal‐Free Oxidative B−N Coupling of nido‐Carborane with N‐Heterocycles

Zhongming Yang, Weijia Zhao, Wei Liu, Xing Wei, Meng Chen, Xiao Zhang, Xiaolei Zhang, Yong Liang, Changsheng Lu and Hong Yan

Angew Chem Int Ed, 2019, 58, 11886
DOI: 10.1002/anie.201904940

Dynamic Visualization of Stress/Strain Distribution and Fatigue Crack Propagation by an Organic Mechanoresponsive AIE Luminogen

Zijie Qiu, Weijun Zhao, Mingkui Cao, Yuqi Wang, Jacky W. Y. Lam, Zhe Zhang, Xu Chen and Ben Zhong Tang

Advanced Materials, 2018, 30
DOI: 10.1002/adma.201803924

Deboronation-Induced Ratiometric Emission Variations of Terphenyl-Based Closo-o-Carboranyl Compounds: Applications to Fluoride-Sensing

Hyunhee So, Min Sik Mun, Mingi Kim, Jea Ho Kim, Ji Hye Lee, Hyonseok Hwang, Duk Keun An and Kang Mun Lee

Molecules, 2020, 25, 2413
DOI: 10.3390/molecules25102413

Switching between intramolecular charge transfer and excimer emissions in solids based on aryl-modified ethynyl‒o-carboranes

Hideki Yamamoto, Junki Ochi, Kazuhiro Yuhara, Kazuo Tanaka and Yoshiki Chujo

Cell Reports Physical Science, 2022, 3, 100758
DOI: 10.1016/j.xcrp.2022.100758

Synthesis, luminescent properties and application opportunities of С-substituted ortho-carborane π-conjugated luminophores: a mini review

Timofey D. Moseev, Tair A. Idrisov, Mikhail V. Varaksin, Valery N. Charushin and Oleg N. Chupakhin

Chim.Tech.Acta, 2025, 12
DOI: 10.15826/chimtech.2025.12.2.13

Impact of the Electronic Environment in Carbazole-Appended o-Carboranyl Compounds on the Intramolecular-Charge-Transfer-Based Radiative Decay Efficiency

Seok Ho Lee, Min Sik Mun, Ji Hye Lee, Sehee Im, Wonchul Lee, Hyonseok Hwang and Kang Mun Lee

Organometallics, 2021, 40, 959
DOI: 10.1021/acs.organomet.1c00060

Design of Thermochromic Luminescent Dyes Based on the Bis(ortho‐carborane)‐Substituted Benzobithiophene Structure

Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo

Chemistry An Asian Journal, 2019, 14, 789
DOI: 10.1002/asia.201801529

Modulation of the solid-state luminescent properties of conjugated polymers by changing the connecting points of flexible boron element blocks

Kazuo Tanaka and Yoshiki Chujo

Polym J, 2020, 52, 555
DOI: 10.1038/s41428-020-0316-y

Enhancement of Luminescence Efficiencies by Thermal Rearrangement from ortho‐ to meta‐Carborane in Bis‐Carborane‐Substituted Acenes

Hirofumi Naito, Kyoya Uemura, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo

Eur J Org Chem, 2018, 2018, 1885
DOI: 10.1002/ejoc.201800151

Recent Progress in the Development of Solid‐State Luminescent o‐Carboranes with Stimuli Responsivity

Junki Ochi, Kazuo Tanaka and Yoshiki Chujo

Angew Chem Int Ed, 2020, 59, 9841
DOI: 10.1002/anie.201916666