Carlo Sambiagio, David Schönbauer, Remi Blieck, Toan Dao-Huy, Gerit Pototschnig, Patricia Schaaf, Thomas Wiesinger, Muhammad Farooq Zia, Joanna Wencel-Delord, Tatiana Besset, Bert U. W. Maes and Michael Schnürch

Chem. Soc. Rev., 2018, 47, 6603
DOI: 10.1039/C8CS00201K

Computational Study of the Ni-Catalyzed C–H Oxidative Cycloaddition of Aromatic Amides with Alkynes

Humair M. Omer and Peng Liu

ACS Omega, 2019, 4, 5209
DOI: 10.1021/acsomega.9b00030

Palladium‐Catalyzed 8‐Aminoquinoline‐Aided sp2δ‐C−H Intramolecular Amidation/Annulation: A Route to Tricyclic Quinolones

Rayavarapu Padmavathi and Srinivasarao Arulananda Babu

Asian J Org Chem, 2019, 8, 899
DOI: 10.1002/ajoc.201900109

Ni‐Catalyzed Chelation‐AssistedDirect Functionalization of Inert C—H Bonds

Yan‐Hua Liu, Yu‐Nong Xia and Bing‐Feng Shi

Chin. J. Chem., 2020, 38, 635
DOI: 10.1002/cjoc.201900468

Pd(II)-Catalyzed, Picolinamide-Assisted, Z-Selective γ-Arylation of Allylamines To Construct Z-Cinnamylamines

Ramarao Parella and Srinivasarao Arulananda Babu

J. Org. Chem., 2017, 82, 6550
DOI: 10.1021/acs.joc.7b00535

Synthesis of diaryl sulfides through C H bond functionalization of arylamides with cobalt salt and elemental sulfur

Jian-Ye Li, Jun Huang, Shi-Jin Zhang, Chunna Yao, Wen-Wu Sun, Bin Liu, Yingbi Zhou and Bin Wu

Tetrahedron Letters, 2019, 60, 895
DOI: 10.1016/j.tetlet.2019.02.032

Late‐Stage Diversification of Non‐Steroidal Anti‐Inflammatory Drugs by Transition Metal‐Catalyzed C–H Alkenylations, Thiolations and Selenylations

Wenbo Ma, Hongbo Dong, Daoxin Wang and Lutz Ackermann

Adv Synth Catal, 2017, 359, 966
DOI: 10.1002/adsc.201600937

Copper-Catalyzed 8-Aminoquinoline Assisted Aryl Chalcogenation of Ferroceneamide with Aryl Disulfides, Diselenides, and Ditellurides

Moh. Sattar, Muhammed Shareef, Krishna Patidar and Sangit Kumar

J. Org. Chem., 2018, 83, 8241
DOI: 10.1021/acs.joc.8b00974

Cobalt-Catalyzed Direct C–H Thiolation of Aromatic Amides with Disulfides: Application to the Synthesis of Quetiapine

Mingliang Li and Jun “Joelle” Wang

Org. Lett., 2018, 20, 6490
DOI: 10.1021/acs.orglett.8b02812

Pd(II)-Catalyzed Direct Sulfonylation of Benzylamines Using Sodium Sulfinates

Ujjwal Karmakar and Rajarshi Samanta

J. Org. Chem., 2019, 84, 2850
DOI: 10.1021/acs.joc.8b03098

Nickel‐Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates

Nai‐Wei Liu, Shuai Liang, Natalie Margraf, Saad Shaaban, Vanessa Luciano, Marcella Drost and Georg Manolikakes

Eur J Org Chem, 2018, 2018, 1208
DOI: 10.1002/ejoc.201701478

Nickel‐Catalyzed Sulfonylation of C(sp2)–H Bonds with Sodium Sulfinates

Shuang‐Liang Liu, Xue‐Hong Li, Shu‐Sheng Zhang, Sheng‐Kai Hou, Guang‐Chao Yang, Jun‐Fang Gong and Mao‐Ping Song

Adv Synth Catal, 2017, 359, 2241
DOI: 10.1002/adsc.201700290

Palladium(II)/Copper(II)‐Catalyzed C–H Sulfidation or Selenation of Arenes Leading to Unsymmetrical Sulfides and Selenides

Kota Nishino, Shouya Tsukahara, Yohei Ogiwara and Norio Sakai

Eur J Org Chem, 2019, 2019, 1588
DOI: 10.1002/ejoc.201801765

Oxidative Remote C−H Trifluoromethylation of Quinolineamides on the C5 Position with Iodobenzene Diacetate as the Oxidizing Agent

Zhaoyang Wu, Yongqin He, Chaowei Ma, Xiaoqiang Zhou, Xingxing Liu, Yamin Li, Ting Hu, Ping Wen and Guosheng Huang

Asian J Org Chem, 2016, 5, 724
DOI: 10.1002/ajoc.201600128

Highly efficient synthesis of arylsulfide derivatives from coupling reaction of aryl titanium reagents with N-aryl thiosuccinimides catalyzed by copper under ligand-free conditions

Zhi-Hao Zhang, Jia-Xia Pu, Xiao-Ying Jia, Jin-Song Hou, Li-Rong Han, Chuan Wu and Qing-Han Li

Journal of Organometallic Chemistry, 2024, 1014, 123192
DOI: 10.1016/j.jorganchem.2024.123192

Recent Advances in the Catalytic Synthesis of Arylsulfonyl Compounds

Devaneyan Joseph, Muhammad Aliyu Idris, Jiajia Chen and Sunwoo Lee

ACS Catal., 2021, 11, 4169
DOI: 10.1021/acscatal.0c05690

NCN Nickel(II) Pincer Complexes of 5‐tert‐Butyl‐1,3‐bis(N‐substituted benzimidazol‐2′‐yl)benzenes: Solid and Solution State Behaviour

Varsha Rani, Harkesh B. Singh and Ray J. Butcher

ChemistrySelect, 2018, 3, 11970
DOI: 10.1002/slct.201802644

Nickel‐Catalyzed C−H Chalcogenation of Anilines

Thomas Müller and Lutz Ackermann

Chemistry A European J, 2016, 22, 14151
DOI: 10.1002/chem.201603092

Chelation-Assisted Nickel-Catalyzed C−H Functionalizations

Shrikant M. Khake and Naoto Chatani

Trends in Chemistry, 2019, 1, 524
DOI: 10.1016/j.trechm.2019.06.002

Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

Irina P. Beletskaya and Valentine P. Ananikov

Chem. Rev., 2022, 122, 16110
DOI: 10.1021/acs.chemrev.1c00836

Visible light induced regioselective C5 halogenation of 8-aminoquinolines with 1,3-dihalo-5,5-dimethylhydantoin in continuous flow

Quan Shu, Yaming Li, Tong Liu, Siyu Zhang, Linlin Jiang, Kun Jin, Rong Zhang and Chunying Duan

Tetrahedron, 2019, 75, 3636
DOI: 10.1016/j.tet.2019.05.037

Synthesis of Benzo[b]thiophenes through Rhodium‐Catalyzed Three‐Component Reaction using Elemental Sulfur

Sanghun Moon, Moena Kato, Yuji Nishii and Masahiro Miura

Adv Synth Catal, 2020, 362, 1669
DOI: 10.1002/adsc.202000112

Remote C−H Activation of Quinolines through Copper‐Catalyzed Radical Cross‐Coupling

Jun Xu, Chao Shen, Xiaolei Zhu, Pengfei Zhang, Manjaly J. Ajitha, Kuo‐Wei Huang, Zhongfu An and Xiaogang Liu

Chemistry An Asian Journal, 2016, 11, 882
DOI: 10.1002/asia.201501407

Ruthenium(II)‐Catalyzed C−H Chalcogenation of Anilides

Wenbo Ma, Zhengyun Weng, Torben Rogge, Linghui Gu, Jiafu Lin, Ai Peng, Xiang Luo, Xiaojun Gou and Lutz Ackermann

Adv Synth Catal, 2018, 360, 704
DOI: 10.1002/adsc.201701147

Remote C−H Functionalization of 8‐Aminoquinolinamides

Bhuttu Khan, Himangsu Sekhar Dutta and Dipankar Koley

Asian J Org Chem, 2018, 7, 1270
DOI: 10.1002/ajoc.201800276

Synthesis of Benzoisoselenazolone Derivatives by Nickel-Catalyzed Dehydrogenative Direct Selenation of C(sp2)–H Bonds with Elemental Selenium in Air

Masayuki Iwasaki, Natsumi Miki, Yuta Tsuchiya, Kiyohiko Nakajima and Yasushi Nishihara

Org. Lett., 2017, 19, 1092
DOI: 10.1021/acs.orglett.7b00116

Copper‐Catalyzed Remote C−H Functionalization of 8‐Aminoquinolines with Sodium and Lithium Sulfinates

Shuai Liang and Georg Manolikakes

Adv Synth Catal, 2016, 358, 2371
DOI: 10.1002/adsc.201600388

Ligand‐Free Palladium(II)‐Catalyzed ortho‐C–H Chalcogenations of N‐Arylsulfonamide via Weak Coordination

Linghui Gu, Xinyue Fang, Zhengyun Weng, Yupin Song and Wenbo Ma

Eur J Org Chem, 2019, 2019, 1825
DOI: 10.1002/ejoc.201900050

Utilizing 2‐phenylpropanal as coupling partner for C‐S bond formation via sequential thioarylation and decarbonylation process: A novel strategy for the synthesis of aryl alkyl sulfides

Elham Shaikhi Shahidzadeh, Najmeh Nowrouzi and Mohammad Abbasi

Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.5211

ChemInform Abstract: Nickel‐Catalyzed Synthesis of Diarylsulfides and Sulfones via C—H Bond Functionalization of Arylamides.

Vutukuri Prakash Reddy, Renhua Qiu, Takanori Iwasaki and Nobuaki Kambe

ChemInform, 2015, 46
DOI: 10.1002/chin.201545098

Selective Mono‐ and Di‐C(aryl)−H Sulfenylation of Benzamides by One‐Pot Assembly of 8‐Aminoquinoline, Benzoyl chlorides, and Thiophenols

Yunyun Liu, Meiying Huang and Li Wei

Asian J Org Chem, 2017, 6, 41
DOI: 10.1002/ajoc.201600491

Pd(II)-Catalyzed Arylation and Intramolecular Amidation of γ-C(sp3)–H Bonds: En Route to Arylheteroarylmethane and Pyrrolidone Ring Annulated Furan/Thiophene Scaffolds

Ramarao Parella and Srinivasarao Arulananda Babu

J. Org. Chem., 2017, 82, 7123
DOI: 10.1021/acs.joc.7b00582

Copper-Mediated Remote C–H Bond Chalcogenation of Quinolines on the C5 Position

Longzhi Zhu, Renhua Qiu, Xin Cao, Song Xiao, Xinhua Xu, Chak-Tong Au and Shuang-Feng Yin

Org. Lett., 2015, 17, 5528
DOI: 10.1021/acs.orglett.5b02511

Direct Synthesis of Primary Anilines via Nickel‐mediated C(sp2)‐H Aminations

Lin Yu, Xiang Chen, Da Liu, Liang Hu, Yongqi Yu, Hang Huang, Ze Tan and Qingwen Gui

Adv Synth Catal, 2018, 360, 1346
DOI: 10.1002/adsc.201701371

Ligand‐Promoted RhIII‐Catalyzed Thiolation of Benzamides with a Broad Disulfide Scope

Yan‐Shang Kang, Ping Zhang, Min‐Yan Li, You‐Ke Chen, Hua‐Jin Xu, Jing Zhao, Wei‐Yin Sun, Jin‐Quan Yu and Yi Lu

Angew Chem Int Ed, 2019, 58, 9099
DOI: 10.1002/anie.201903511

Copper(II)‐Catalyzed and Chelation‐Induced Remote C‐H Halogenation of Quinolines under Neutral Conditions

Sheng Zhang, Aziz Ullah, Yoshinori Yamamoto, Abdulrahman I. Almansour, Natarajan Arumugam, Raju Suresh Kumar and Ming Bao

ChemistrySelect, 2017, 2, 3414
DOI: 10.1002/slct.201700454

Transition Metals Catalyzed Direct C-H Chalcogenation of Arenes and Heteroarenes

Atanu Mahata, Madhusudan Garain, Totan Roy, Dilip Gorai and Debasish Kundu

COS, 2024, 21, 764
DOI: 10.2174/1570179420666230428122124

Ligand-Free, Copper-Catalyzed Coupling Reaction of Aryl Aluminum Reagents with N-Aryl Thiosuccinimides

Zhihao Zhang, Xiaoying Jia, Jiaxia Pu, Lirong Han, Jinsong Hou and Qinghan Li

LOC, 2024, 21, 1055
DOI: 10.2174/0115701786298931240408083720

Functionalization of Quinolines through Copper‐Catalyzed Regioselective Halogenation Reaction

Harekrishna Sahoo, Isai Ramakrishna and Mahiuddin Baidya

ChemistrySelect, 2016, 1, 1949
DOI: 10.1002/slct.201600532

Construction of Tertiary Amides: NiII‐Catalyzed N‐Arylation of Secondary Acyclic Amides (2‐Picolinamides) with Aryl Halides

Rathinam Sankar and Srinivasarao Arulananda Babu

Asian J Org Chem, 2017, 6, 269
DOI: 10.1002/ajoc.201600596

4-Amino-2,1,3-benzothiadiazole as a Removable Bidentate Directing Group for the Pd(II)-Catalyzed Arylation/Oxygenation of sp2/sp3 β-C–H Bonds of Carboxamides

Chennakesava Reddy, Narendra Bisht, Ramarao Parella and Srinivasarao Arulananda Babu

J. Org. Chem., 2016, 81, 12143
DOI: 10.1021/acs.joc.6b01831

Pd(II)‐Catalyzed, γ‐C(sp2)−H Alkoxylation in α‐Methylbenzylamine, Phenylglycinol, 3‐Amino‐3‐Phenylpropanol Toward Enantiopure Aryl Alkyl Ethers

Yashika Aggarwal, Rayavarapu Padmavathi, Prabhakar Singh and Srinivasarao Arulananda Babu

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200327

3d Transition Metals for C–H Activation

Parthasarathy Gandeepan, Thomas Müller, Daniel Zell, Gianpiero Cera, Svenja Warratz and Lutz Ackermann

Chem. Rev., 2019, 119, 2192
DOI: 10.1021/acs.chemrev.8b00507

Direct Thiolation and Selenation of Aryl C-H Bonds Catalyzed by Palladium or Nickel

Masayuki Iwasaki and Yasushi Nishihara

J. Syn. Org. Chem., Jpn., 2018, 76, 11
DOI: 10.5059/yukigoseikyokaishi.76.11

Advances in transition-metal catalyzed thioetherification reactions of aromatic compounds

Arash Ghaderi

Tetrahedron, 2016, 72, 4758
DOI: 10.1016/j.tet.2016.06.067

Directing Group Assisted Copper‐Catalyzed C−H sulfanylation of Alkenyl Carbonyl Compounds with Disulfides

Yan‐Mei Bai, Lu‐Lu Ai, Xin‐Mei Zhang, Fang‐Hui Wu and Yan‐Shang Kang

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202301206

Nickel-Catalyzed Aromatic C–H Functionalization

Junichiro Yamaguchi, Kei Muto and Kenichiro Itami

Top Curr Chem (Z), 2016, 374
DOI: 10.1007/s41061-016-0053-z

Nickel-mediated C(sp2)-H amidation in synthesis of secondary sulfonamides via sulfonyl azides as amino source

Peng Xu, Peng-Fei Ding, Mei-Qi Zhang, Yu-Shi Xia and Ting Xie

Tetrahedron Letters, 2021, 66, 152825
DOI: 10.1016/j.tetlet.2021.152825

Copper‐Catalyzed ortho‐Thiomethylation of Benzamides via 8‐Aminoquinoline‐Assisted C‐H Activation with Dimethyl Sulfoxide

Xinfeng Cui, Xingxing Liu, Xiajun Wang, Wanfa Tian, Daidong Wei and Guosheng Huang

ChemistrySelect, 2017, 2, 8607
DOI: 10.1002/slct.201702046

Nickel-Catalyzed Reaction of Benzamides with Bicylic Alkenes: Cleavage of C–H and C–N Bonds

Aymen Skhiri and Naoto Chatani

Org. Lett., 2019, 21, 1774
DOI: 10.1021/acs.orglett.9b00351

Construction of β‐Phenylalanine Derivatives through Pd‐Catalyzed, C(sp2)−H (ortho) Functionalization

Urja Narang, Prabhakar Singh and Srinivasarao Arulananda Babu

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300463

Recent Trends in Nickel‐Catalyzed C−S Bond Formation

U. S. Kanchana, Elizabeth J. Diana and Thomas V. Mathew

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200038

Computational Study of Ni-Catalyzed C–H Functionalization: Factors That Control the Competition of Oxidative Addition and Radical Pathways

Humair M. Omer and Peng Liu

J. Am. Chem. Soc., 2017, 139, 9909
DOI: 10.1021/jacs.7b03548

Iron-mediated remote C–H bond benzylation of 8-aminoquinoline amides

Mian Cui, Jing-Hui Liu, Xiao-Yu Lu, Xi Lu, Zhen-Qi Zhang, Bin Xiao and Yao Fu

Tetrahedron Letters, 2017, 58, 1912
DOI: 10.1016/j.tetlet.2017.02.090

Ruthenium(II)-Catalyzed Chelation-Assisted Desulfitative Arylation of Benzo[h]quinolines with Arylsulfonyl Chlorides

Yi-Xin Xu, Yu-Qing Liang, Zhong-Jian Cai and Shun-Jun Ji

Org. Lett., 2022, 24, 2601
DOI: 10.1021/acs.orglett.2c00542

Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones

Shuai Liang, Kamil Hofman, Marius Friedrich, Julian Keller and Georg Manolikakes

ChemSusChem, 2021, 14, 4878
DOI: 10.1002/cssc.202101635

Recent Advances in Transition‐Metal‐Mediated Chelation‐ Assisted Sulfonylation of Unactivated C−H Bonds

Jidan Liu and Liyao Zheng

Adv Synth Catal, 2019, 361, 1710
DOI: 10.1002/adsc.201801307

Metal–free C5‐H Bromination of Quinolines for One‐pot C−X (X=C, O, S) Bond Formations

You Li, Longzhi Zhu, Xin Cao, Chak‐Tong Au, Renhua Qiu and Shuang‐Feng Yin

Adv Synth Catal, 2017, 359, 2864
DOI: 10.1002/adsc.201700391

Ruthenium‐Catalyzed C–H Selenylations of Benzamides

Wenbo Ma, Zhengyun Weng, Xinyue Fang, Linghui Gu, Yupin Song and Lutz Ackermann

Eur J Org Chem, 2019, 2019, 41
DOI: 10.1002/ejoc.201801532

Ligand‐Promoted RhIII‐Catalyzed Thiolation of Benzamides with a Broad Disulfide Scope

Yan‐Shang Kang, Ping Zhang, Min‐Yan Li, You‐Ke Chen, Hua‐Jin Xu, Jing Zhao, Wei‐Yin Sun, Jin‐Quan Yu and Yi Lu

Angewandte Chemie, 2019, 131, 9197
DOI: 10.1002/ange.201903511

Ni‐Catalyzed/mediated C−X (X=N, O, S) Bond Formation Chelation‐Assisted by Bidentate Directing Groups

Peng Xu and Shengxian Zhao

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202305125

Nickel-Catalyzed Reaction of C–H Bonds in Amides with I2: ortho-Iodination via the Cleavage of C(sp2)–H Bonds and Oxidative Cyclization to β-Lactams via the Cleavage of C(sp3)–H Bonds

Yoshinori Aihara and Naoto Chatani

ACS Catal., 2016, 6, 4323
DOI: 10.1021/acscatal.6b00964

Assembling of Polyaryls (Terphenyls, Tetraphenyls, Pentaphenyls, and Hexaphenyls) through Pd(II)‐catalyzed C−H Arylation of Biaryl Carboxamides with Iodobiaryls

Arup Dalal, Srinivasarao Arulananda Babu and Shefali Banga

Asian J Org Chem, 2024, 13
DOI: 10.1002/ajoc.202300508

Expedient C–H Chalcogenation of Indolines and Indoles by Positional-Selective Copper Catalysis

Parthasarathy Gandeepan, Julian Koeller and Lutz Ackermann

ACS Catal., 2017, 7, 1030
DOI: 10.1021/acscatal.6b03236