Electronic effects on polypyridyl Co complex-based water reduction catalysts

Xusheng Guo, Chao Li, Weibo Wang, Baowen Zhang, Yuanjun Hou, Xuesong Wang and Qianxiong Zhou

RSC Adv., 2021, 11, 24359
DOI: 10.1039/D1RA02435C

Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen

Simon N. Child, Radoslav Raychev, Nathan Moss, Benjamin Howchen, Peter N. Horton, Christopher C. Prior, Vasily S. Oganesyan and John Fielden

Dalton Trans., 2019, 48, 9576
DOI: 10.1039/C9DT00773C

Cobalt, nickel, and iron complexes of 8-hydroxyquinoline-di(2-picolyl)amine for light-driven hydrogen evolution

Nadia Alessandra Carmo dos Santos, Mirco Natali, Elena Badetti, Klaus Wurst, Giulia Licini and Cristiano Zonta

Dalton Trans., 2017, 46, 16455
DOI: 10.1039/C7DT02666H

How reliable is DFT for predicting the redox potentials in polypyridine-based hydrogen evolution catalysts?

Sheetal Ranaut and Shivnath Mazumder

Phys. Chem. Chem. Phys., 2026, 28, 3895
DOI: 10.1039/D5CP04297F

Ascorbate as an electron relay between an irreversible electron donor and Ru(ii) or Re(i) photosensitizers

Cyril Bachmann, Benjamin Probst, Miguel Guttentag and Roger Alberto

Chem. Commun., 2014, 50, 6737
DOI: 10.1039/C4CC01500B

Bioinspired motifs in proton and CO2 reduction with 3d-metal polypyridine complexes

Federico Droghetti, Agnese Amati, Albert Ruggi and Mirco Natali

Chem. Commun., 2024, 60, 658
DOI: 10.1039/D3CC05156K

Mononuclear Mn complexes featuring N,S-/N,N-donor and 1,3,5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties

Vishakha Kaim and Sandeep Kaur-Ghumaan

New J. Chem., 2021, 45, 20272
DOI: 10.1039/D1NJ02104D

Bioinspired metal complexes for energy-related photocatalytic small molecule transformation

Hao-Lin Wu, Xu-Bing Li, Chen-Ho Tung and Li-Zhu Wu

Chem. Commun., 2020, 56, 15496
DOI: 10.1039/D0CC05870J

Copper-based electrocatalyst for hydrogen evolution in water

Abdullah M. Abudayyeh, Michael S. Bennington, Johan Hamonnet, Aaron T. Marshall and Sally Brooker

Dalton Trans., 2024, 53, 6207
DOI: 10.1039/D4DT00224E

Electrocatalytic proton reduction by dinuclear cobalt complexes in a nonaqueous electrolyte

Manaswini Raj and Sumanta Kumar Padhi

New J. Chem., 2022, 46, 6027
DOI: 10.1039/D1NJ06003A

Earth-abundant hydrogen evolution electrocatalysts

James R. McKone, Smaranda C. Marinescu, Bruce S. Brunschwig, Jay R. Winkler and Harry B. Gray

Chem. Sci., 2014, 5, 865
DOI: 10.1039/C3SC51711J

Homogeneous vs. heterogeneous catalysis for hydrogen evolution by a nickel(ii) bis(diphosphine) complex

Giovanni Bergamini and Mirco Natali

Dalton Trans., 2019, 48, 14653
DOI: 10.1039/C9DT02846C

Polypyridyl Co complex-based water reduction catalysts: why replace a pyridine group with isoquinoline rather than quinoline?

Xusheng Guo, Chao Li, Weibo Wang, Yuanjun Hou, Baowen Zhang, Xuesong Wang and Qianxiong Zhou

Dalton Trans., 2021, 50, 2042
DOI: 10.1039/C9DT04767K

Structurally modified T-metal complexes and organic dyes as photosensitizers and earth-abundant T-metal catalysts for photo-driven hydrogen evolution in artificial photosynthetic systems

Rahat Gupta, Priya Sahni, Simran Sharma, Anindya Roy and Amlan K. Pal

Sustainable Energy Fuels, 2022, 6, 1891
DOI: 10.1039/D2SE00177B

Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

Nathan Coutard, Nicolas Kaeffer and Vincent Artero

Chem. Commun., 2016, 52, 13728
DOI: 10.1039/C6CC06311J

A computational mechanistic investigation of hydrogen production in water using the [RhIII(dmbpy)2Cl2]+/[RuII(bpy)3]2+/ascorbic acid photocatalytic system

Megumi Kayanuma, Thibaut Stoll, Chantal Daniel, Fabrice Odobel, Jérôme Fortage, Alain Deronzier and Marie-Noëlle Collomb

Phys. Chem. Chem. Phys., 2015, 17, 10497
DOI: 10.1039/C4CP04949G

Ru–protein–Co biohybrids designed for solar hydrogen production: understanding electron transfer pathways related to photocatalytic function

Sarah R. Soltau, Peter D. Dahlberg, Jens Niklas, Oleg G. Poluektov, Karen L. Mulfort and Lisa M. Utschig

Chem. Sci., 2016, 7, 7068
DOI: 10.1039/C6SC03121H

Mimicking 2,2′:6′,2′′:6′′,2′′′-quaterpyridine complexes for the light-driven hydrogen evolution reaction: synthesis, structural, thermal and physicochemical characterizations

Sanil Rajak, Olivier Schott, Prabhjyot Kaur, Thierry Maris, Garry S. Hanan and Adam Duong

RSC Adv., 2019, 9, 28153
DOI: 10.1039/C9RA04303A

Reversible conversion of valence-tautomeric copper metal–organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C–H bonds activation reaction

Chao Huang, Jie Wu, Chuanjun Song, Ran Ding, Yan Qiao, Hongwei Hou, Junbiao Chang and Yaoting Fan

Chem. Commun., 2015, 51, 10353
DOI: 10.1039/C5CC02432C

Nature of ultrafast dynamics in the lowest-lying singlet excited state of [Ru(bpy)3]2+

Chenyu Zeng, Yaqi Li, Hangjing Zheng, Mingxing Ren, Wei Wu and Zhenhua Chen

Phys. Chem. Chem. Phys., 2024, 26, 6524
DOI: 10.1039/D3CP03806H

Photoinduced hydrogen evolution by a pentapyridine cobalt complex: elucidating some mechanistic aspects

Elisa Deponti, Alessandra Luisa, Mirco Natali, Elisabetta Iengo and Franco Scandola

Dalton Trans., 2014, 43, 16345
DOI: 10.1039/C4DT02269F

Magnetic amphiphilic nanocomposites based on silica–carbon for sulphur contaminant oxidation

Aline A. S. Oliveira, Taís Christofani, Ivo F. Teixeira, José D. Ardisson and Flávia C. C. Moura

New J. Chem., 2015, 39, 5445
DOI: 10.1039/C5NJ00593K

Turning it off! Disfavouring hydrogen evolution to enhance selectivity for CO production during homogeneous CO2 reduction by cobalt–terpyridine complexes

Noémie Elgrishi, Matthew B. Chambers and Marc Fontecave

Chem. Sci., 2015, 6, 2522
DOI: 10.1039/C4SC03766A

Electrocatalytic generation of H2 from neutral water in acetonitrile using manganese polypyridyl complexes with ligand assistance

Gyandshwar Kumar Rao, Mohammad Parsa Jamshidi, Jeremy I. G. Dawkins, Wendy Pell, Ilia Korobkov and Darrin Richeson

Dalton Trans., 2017, 46, 6518
DOI: 10.1039/C7DT01039G

Tunable carbocation-based redox active ambiphilic ligands: synthesis, coordination and characterization

Liangyong Mei, José M. Veleta, Jan Bloch, Hannah J. Goodman, Dominic Pierce-Navarro, Alejandro Villalobos and Thomas L. Gianetti

Dalton Trans., 2020, 49, 16095
DOI: 10.1039/D0DT00419G

Electro- and photochemical H2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Fiorella Lucarini, Jennifer Fize, Adina Morozan, Federico Droghetti, Euro Solari, Rosario Scopelliti, Marco Marazzi, Mirco Natali, Mariachiara Pastore, Vincent Artero and Albert Ruggi

Sustainable Energy Fuels, 2023, 7, 3384
DOI: 10.1039/D3SE00295K

Recent findings and future directions in photosynthetic hydrogen evolution using polypyridine cobalt complexes

Federico Droghetti, Fiorella Lucarini, Alessandra Molinari, Albert Ruggi and Mirco Natali

Dalton Trans., 2022, 51, 10658
DOI: 10.1039/D2DT00476C

Exploring the effect of a pendent amine group poised over the secondary coordination sphere of a cobalt complex on the electrocatalytic hydrogen evolution reaction

Afsar Ali, Rajaneesh Kumar Verma, Avijit Das and Sayantan Paria

Dalton Trans., 2024, 53, 8289
DOI: 10.1039/D4DT00009A

Photoinduced hydrogen evolution with new tetradentate cobalt(ii) complexes based on the TPMA ligand

Mirco Natali, Elena Badetti, Elisa Deponti, Marta Gamberoni, Francesca A. Scaramuzzo, Andrea Sartorel and Cristiano Zonta

Dalton Trans., 2016, 45, 14764
DOI: 10.1039/C6DT01705C

Electrocatalytic hydrogen production by dinuclear cobalt(ii) compounds containing redox-active diamidate ligands: a combined experimental and theoretical study

Michael G. Papanikolaou, Alexander Elliott, James McAllister, John K. Gallos, Anastasios D. Keramidas, Themistoklis A. Kabanos, Stephen Sproules and Haralampos N. Miras

Dalton Trans., 2020, 49, 15718
DOI: 10.1039/D0DT02617D

Exploring acidity-dependent PCET pathways in imino-bipyridyl cobalt complexes

Jueun Lee, Daeun Jung and Junhyeok Seo

Dalton Trans., 2025, 54, 2776
DOI: 10.1039/D4DT03221G

A nickel complex of a conjugated bis-dithiocarbazate Schiff base for the photocatalytic production of hydrogen

Catherine F. Wise, Dan Liu, Kathryn J. Mayer, Patrick M. Crossland, Carolyn L. Hartley and William R. McNamara

Dalton Trans., 2015, 44, 14265
DOI: 10.1039/C5DT02042E

Copper catalysts for photo- and electro-catalytic hydrogen production

Abdullah M. Abudayyeh, Olivier Schott, Humphrey L. C. Feltham, Garry S. Hanan and Sally Brooker

Inorg. Chem. Front., 2021, 8, 1015
DOI: 10.1039/D0QI01247E

Hydrogen photogeneration catalyzed by a cobalt complex of a pentadentate aminopyridine-based ligand

Xiaowei Song, Huimin Wen, Chengbing Ma, Hui Chen and Changneng Chen

New J. Chem., 2015, 39, 1734
DOI: 10.1039/C4NJ01858C

Photocatalytic hydrogen evolution from a cobalt/nickel complex with dithiolene ligands under irradiation with visible light

Heng Rao, Zhi-Yuan Wang, Hui-Qin Zheng, Xiao-Bo Wang, Chun-Mei Pan, Yao-Ting Fan and Hong-Wei Hou

Catal. Sci. Technol., 2015, 5, 2332
DOI: 10.1039/C4CY01574F

Mapping free energy regimes in electrocatalytic reductions to screen transition metal-based catalysts

Srinivasan Ramakrishnan, Ross A. Moretti and Christopher E. D. Chidsey

Chem. Sci., 2019, 10, 7649
DOI: 10.1039/C9SC01766F

Synthesis of a pentadentate, polypyrazine ligand and its application in cobalt-catalyzed hydrogen production

Lizhu Chen, Amir Khadivi, Manpreet Singh and Jonah W. Jurss

Inorg. Chem. Front., 2017, 4, 1649
DOI: 10.1039/C7QI00362E

Photocatalytic hydrogen evolution with ruthenium polypyridine sensitizers: unveiling the key factors to improve efficiencies

Elisa Deponti and Mirco Natali

Dalton Trans., 2016, 45, 9136
DOI: 10.1039/C6DT01221C

Understanding light-driven H2 evolution through the electronic tuning of aminopyridine cobalt complexes

Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernández, María González-Béjar, Julia Pérez-Prieto, Josep M. Luis and Julio Lloret-Fillol

Chem. Sci., 2018, 9, 2609
DOI: 10.1039/C7SC04328G

High performance of the flow-type one-compartment hydrogen peroxide fuel cell using buckypaper and narrow fuel pathway under physiological conditions

Sieun Jeon, Heeyeon An and Yongjin Chung

Sustainable Energy Fuels, 2022, 6, 841
DOI: 10.1039/D1SE01784E

Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation

Debashis Basu, Shivnath Mazumder, Jens Niklas, Habib Baydoun, Dakshika Wanniarachchi, Xuetao Shi, Richard J. Staples, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Chem. Sci., 2016, 7, 3264
DOI: 10.1039/C5SC04214C

Photocatalytic hydrogen evolution from neutral aqueous solution by a water-soluble cobalt(ii) porphyrin

Belete B. Beyene and Chen-Hsiung Hung

Sustainable Energy Fuels, 2018, 2, 2036
DOI: 10.1039/C8SE00253C

Ligand dechelation effect on a [Co(tpy)2]2+ scaffold towards electro-catalytic proton and water reduction

Karunamay Majee and Sumanta Kumar Padhi

New J. Chem., 2019, 43, 3856
DOI: 10.1039/C8NJ05712E

Ultrafast reaction mechanisms in multimolecular Ir–Co catalytic assemblies for hydrogen evolution

Lucia Velasco, Asterios Charisiadis, Xiaoyi Zhang and Dooshaye Moonshiram

Chem. Commun., 2026, 62, 955
DOI: 10.1039/D5CC05229G

Coordination chemistry in the design of heterogeneous photocatalysts

Chao Gao, Jin Wang, Hangxun Xu and Yujie Xiong

Chem. Soc. Rev., 2017, 46, 2799
DOI: 10.1039/C6CS00727A

Insights into the mechanism of photosynthetic H2 evolution catalyzed by a heptacoordinate cobalt complex

Fiorella Lucarini, Jennifer Fize, Adina Morozan, Marco Marazzi, Mirco Natali, Mariachiara Pastore, Vincent Artero and Albert Ruggi

Sustainable Energy Fuels, 2020, 4, 589
DOI: 10.1039/C9SE00434C

Ligand tunability versus condition optimization: a guide to the structure–activity/stability nexus and mechanistic insights into photoinduced hydrogen evolution using hexacoordinated cobalt complexes

Ibukun Oluwaseun Shotonwa, Emmanuel Aanu Bankole, Aminu Labaran Muhammad, Oluwatobiloba Emmanuel Ojomo, Emmanuel Anegbe, Peter Osaigie Ifagbuyi, Olubukola Anuoluwapo Alani, Simeon Okechukwu Eze, Busayo Christiana Akano, Tobiloba Mary Omifolajin, Segun Samuel Bamidele, Bakau Olanrewaju Ayoola, Kehinde Elizabeth Onasanya, Onome Ejeromedoghene, Winfried Plass, Adedoyin Oluseyi Adesoji and Sheriff Adewuyi

Catal. Sci. Technol., 2025, 15, 6271
DOI: 10.1039/D5CY00364D

Photocatalytic proton reduction with ruthenium and cobalt complexes immobilized on fumed reversed-phase silica

C. Bachmann, B. Probst, M. Oberholzer, T. Fox and R. Alberto

Chem. Sci., 2016, 7, 436
DOI: 10.1039/C5SC02124C

Bioinspired photo-driven hydrogen evolution systems based on hydrogenases and their mimics

Rahat Gupta and Amlan K. Pal

Sustainable Energy Fuels, 2024, 8, 4709
DOI: 10.1039/D4SE00423J

Cobalt(ii) coordination to an N4-acenaphthene-based ligand and its sodium complex

Vera V. Khrizanforova, Robert R. Fayzullin, Artem S. Bogomyakov, Vladimir I. Morozov, Ruslan G. Batulin, Tatiana P. Gerasimova, Daut R. Islamov and Yulia H. Budnikova

Dalton Trans., 2023, 52, 7876
DOI: 10.1039/D3DT00347G

Towards a comprehensive understanding of visible-light photogeneration of hydrogen from water using cobalt(ii) polypyridyl catalysts

R. S. Khnayzer, V. S. Thoi, M. Nippe, A. E. King, J. W. Jurss, K. A. El Roz, J. R. Long, C. J. Chang and F. N. Castellano

Energy Environ. Sci., 2014, 7, 1477
DOI: 10.1039/C3EE43982H

Bioinspired design of redox-active ligands for multielectron catalysis: effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water

Jonah W. Jurss, Rony S. Khnayzer, Julien A. Panetier, Karim A. El Roz, Eva M. Nichols, Martin Head-Gordon, Jeffrey R. Long, Felix N. Castellano and Christopher J. Chang

Chem. Sci., 2015, 6, 4954
DOI: 10.1039/C5SC01414J

A cobalt complex of a pentadentate aminopyridine ligand as an efficient catalyst for photocatalytic hydrogen generation

Xiao-Wei Song, Yan Meng, Chuan-Lei Zhang, Cheng-Bing Ma and Chang-Neng Chen

Inorganic Chemistry Communications, 2017, 76, 52
DOI: 10.1016/j.inoche.2017.01.011

A Crystalline Copper(II) Coordination Polymer for the Efficient Visible‐Light‐Driven Generation of Hydrogen

Xi‐Yan Dong, Mei Zhang, Ru‐Bo Pei, Qian Wang, Dong‐Hui Wei, Shuang‐Quan Zang, Yao‐Ting Fan and Thomas C. W. Mak

Angew Chem Int Ed, 2016, 55, 2073
DOI: 10.1002/anie.201509744

Enhanced photocatalytic hydrogen evolution by combining water soluble graphene with cobalt salts

Jing Wang, Ke Feng, Hui-Hui Zhang, Bin Chen, Zhi-Jun Li, Qing-Yuan Meng, Li-Ping Zhang, Chen-Ho Tung and Li-Zhu Wu

Beilstein J. Nanotechnol., 2014, 5, 1167
DOI: 10.3762/bjnano.5.128

Homogeneous Photocatalytic H2 Production Using a RuII Bathophenanthroline Metal‐to‐Ligand Charge‐Transfer Photosensitizer

Rony S. Khnayzer, Babatunde S. Olaiya, Karim A. El Roz and Felix N. Castellano

ChemPlusChem, 2016, 81, 1090
DOI: 10.1002/cplu.201600227

Effect of Redox-Active Quinoline on the Reactivity and Mechanism of Hydrogen Evolution Reaction (HER) with Pentadentate Polypyridyl-Quinolyl Ligand-Coordinated Cobalt Complex

Aniruddha Paik, Chandan Das, Sabarni Paul, Amit Biswas, Sakshi Mehta, Abhishake Mondal, Bholanath Maity, Arnab Dutta and Sujoy Rana

ACS Catal., 2024, 14, 15498
DOI: 10.1021/acscatal.4c03819

Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14

Jingqi Tian, Qian Liu, Abdullah M. Asiri and Xuping Sun

J. Am. Chem. Soc., 2014, 136, 7587
DOI: 10.1021/ja503372r

Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands

Hongqiao Wang, Nan Wu, Jing Zheng, Chunyang Zheng and Dunjia Wang

Mendeleev Communications, 2020, 30, 100
DOI: 10.1016/j.mencom.2020.01.033

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand‐Based Proton and Electron Transfer

Emily J. Thompson and Louise A. Berben

Angew Chem Int Ed, 2015, 54, 11642
DOI: 10.1002/anie.201503935

Dinuclear Cobalt Complexes with a Decadentate Ligand Scaffold: Hydrogen Evolution and Oxygen Reduction Catalysis

Carlo Di Giovanni, Carolina Gimbert‐Suriñach, Michael Nippe, Jordi Benet‐Buchholz, Jeffrey R. Long, Xavier Sala and Antoni Llobet

Chemistry A European J, 2016, 22, 361
DOI: 10.1002/chem.201503567

Electrocatalytic Hydrogen Evolution with a Cobalt Complex Bearing Pendant Proton Relays: Acid Strength and Applied Potential Govern Mechanism and Stability

Nicolas Queyriaux, Dongyue Sun, Jennifer Fize, Jacques Pécaut, Martin J. Field, Murielle Chavarot-Kerlidou and Vincent Artero

J. Am. Chem. Soc., 2020, 142, 274
DOI: 10.1021/jacs.9b10407

Nickel Complexes and Carbon Dots for Efficient Light‐Driven Hydrogen Production

Kalliopi Ladomenou, Michael Papadakis, Georgios Landrou, Michel Giorgi, Charalambos Drivas, Stella Kennou, Renaud Hardré, Julien Massin, Athanassios G. Coutsolelos and Maylis Orio

Eur J Inorg Chem, 2021, 2021, 3097
DOI: 10.1002/ejic.202100449

Recent progress in homogeneous molecular photoredox catalysis towards hydrogen evolution reaction and future perspective

Ladapborlang Mawrie, Fazlur Rahman, Md. Ashif Ali and Sarifuddin Gazi

Applied Catalysis A: General, 2023, 651, 119010
DOI: 10.1016/j.apcata.2022.119010

Hydrogen production based on hexacoordinated cobalt scaffolds as electrocatalysts for acid-proton reduction: Electrochemistry and mechanisms

Ibukun O. Shotonwa, Onome Ejeromedoghene, Adedoyin O. Adesoji, Yakubu A. Alli, Caroline Akinremi and Sheriff Adewuyi

Journal of Electroanalytical Chemistry, 2024, 963, 118228
DOI: 10.1016/j.jelechem.2024.118228

Nickel Complexes Based on Thiophosphorylated Calix[4]Resorcinols as Effective Catalysts for Hydrogen Evolution

Vera V. Khrizanforova, Irina R. Knyazeva, Victoria I. Matveeva Sokolova, Irek R. Nizameev, Tatyana V. Gryaznova, Marsil K. Kadirov, Alexander R. Burilov, Oleg G. Sinyashin and Yulia H. Budnikova

Electrocatalysis, 2015, 6, 357
DOI: 10.1007/s12678-015-0251-4

Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

Siyoung Sung, Davinder Kumar, Marcos Gil-Sepulcre and Michael Nippe

J. Am. Chem. Soc., 2017, 139, 13993
DOI: 10.1021/jacs.7b07709

Synthesis and Isomeric Analysis of RuII Complexes Bearing Pentadentate Scaffolds

Marcos Gil-Sepulcre, Jordan C. Axelson, Joan Aguiló, Lluís Solà-Hernández, Laia Francàs, Albert Poater, Lluís Blancafort, Jordi Benet-Buchholz, Gonzalo Guirado, Lluís Escriche, Antoni Llobet, Roger Bofill and Xavier Sala

Inorg. Chem., 2016, 55, 11216
DOI: 10.1021/acs.inorgchem.6b01755

Dinitrosyl iron complexes (DNICs) acting as catalyst for photocatalytic hydrogen evolution reaction (HER)

Chi‐Yen Tung, Wei‐Chih Shih, Tzung‐Wen Chiou, I‐Jui Hsu and Wen‐Feng Liaw

J Chinese Chemical Soc, 2022, 69, 1406
DOI: 10.1002/jccs.202200144

Hydrogen Production Using a Nickel Catalyst Combining Redox Activity and Pendent Base Effects

Scott A. Wicker, Phillips Hutchison, Robert G. Musicante, Meghan T. Kiker, Nicholas C. Suffern, Daniel K. Graham, Liam M. Rhodes, Aby P. Binu, Stephan A. Jean-Francois, Alex S. Graves, William W. Brennessel and William T. Eckenhoff

Inorg. Chem., 2024, 63, 451
DOI: 10.1021/acs.inorgchem.3c03308

Cyclopentadienyl Cobalt Complexes as Precatalysts for Electrocatalytic Hydrogen Evolution

Kate M. Waldie, Sung‐Kwan Kim, Andrew J. Ingram and Robert M. Waymouth

Eur J Inorg Chem, 2017, 2017, 2755
DOI: 10.1002/ejic.201700188

H2-Evolving Cobalt–Protic-NHC Catalysts: Kinetic Zone Diagram Analysis and Mechanistic Insights

Sanajit Kumar Mandal, Anusha Gupta and Joyanta Choudhury

ACS Catal., 2024, 14, 17263
DOI: 10.1021/acscatal.4c05104

Functionalized Membranes for Photocatalytic Hydrogen Production

Stefan Troppmann and Burkhard König

Chemistry A European J, 2014, 20, 14570
DOI: 10.1002/chem.201404480

Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex

Anna Lewandowska-Andralojc, Teera Baine, Xuan Zhao, James T. Muckerman, Etsuko Fujita and Dmitry E. Polyansky

Inorg. Chem., 2015, 54, 4310
DOI: 10.1021/ic5031137

Light-Induced H2 Evolution with a Macrocyclic Cobalt Diketo-Pyrphyrin as a Proton-Reducing Catalyst

Evelyne Joliat-Wick, Nicola Weder, Daniel Klose, Cyril Bachmann, Bernhard Spingler, Benjamin Probst and Roger Alberto

Inorg. Chem., 2018, 57, 1651
DOI: 10.1021/acs.inorgchem.7b02992

Synthesis and characterization of metal-diaminobipyridine complexes as low-cost co-catalysts for photo-sensitized hydrogen evolution

Tarun Chand Vagvala, Takashi Ooyabe, Munetoshi Sakai, Yusuke Funasako, Makoto Inokuchi, Wataru Kurashige, Yuichi Negishi, Vit Kalousek and Keita Ikeue

Inorganica Chimica Acta, 2018, 482, 821
DOI: 10.1016/j.ica.2018.07.022

Efficient and Limiting Reactions in Aqueous Light-Induced Hydrogen Evolution Systems using Molecular Catalysts and Quantum Dots

Carolina Gimbert-Suriñach, Josep Albero, Thibaut Stoll, Jérôme Fortage, Marie-Noëlle Collomb, Alain Deronzier, Emilio Palomares and Antoni Llobet

J. Am. Chem. Soc., 2014, 136, 7655
DOI: 10.1021/ja501489h

The crystal structure of tris(6-methylpyridin-2-yl)phosphine selenide, C18H18N3PSe

Gui-Ling Wu

Zeitschrift für Kristallographie - New Crystal Structures, 2022, 237, 243
DOI: 10.1515/ncrs-2021-0455

Mechanism of Photocatalytic Hydrogen Generation by a Polypyridyl-Based Cobalt Catalyst in Aqueous Solution

Alexander Rodenberg, Margherita Orazietti, Benjamin Probst, Cyril Bachmann, Roger Alberto, Kim K. Baldridge and Peter Hamm

Inorg. Chem., 2015, 54, 646
DOI: 10.1021/ic502591a

Metal–Polypyridyl Catalysts for Electro- and Photochemical Reduction of Water to Hydrogen

David Z. Zee, Teera Chantarojsiri, Jeffrey R. Long and Christopher J. Chang

Acc. Chem. Res., 2015, 48, 2027
DOI: 10.1021/acs.accounts.5b00082

Structure of the CoI Intermediate of a Cobalt Pentapyridyl Catalyst for Hydrogen Evolution Revealed by Time‐Resolved X‐ray Spectroscopy

Grigory Smolentsev, Mikhail A. Soldatov, Benjamin Probst, Cyril Bachmann, Nicolo Azzaroli, Roger Alberto, Maarten Nachtegaal and Jeroen A. van Bokhoven

ChemSusChem, 2018, 11, 3087
DOI: 10.1002/cssc.201801140

Photoinduced Hydrogen Evolution Catalyzed by Co(II) Complexes of N5‐Donor Ligands

Chuanshuai Li, Yong Li, Yusen Luo, Klaudia Michaliszyn, Iria Bolaño Losada, Md. Kamal Hossain, Fatma Elantabli, Meiyuan Guo, Lintang Hizbullah, Derek A. Tocher, Matti Haukka, Petter Persson, Julio Lloret‐Fillol, Benjamin Dietzek‐Ivanšić and Ebbe Nordlander

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404499

Carboxylate pentapyridines: Pathway to surface modification and tuneable catalytic proton reduction

Marissa K. Melvin, Paul K. Eggers and Colin L. Raston

Polyhedron, 2022, 228, 116177
DOI: 10.1016/j.poly.2022.116177

Electrochemical Generation and Spectroscopic Characterization of the Key Rhodium(III) Hydride Intermediates of Rhodium Poly(bipyridyl) H2-Evolving Catalysts

Carmen E. Castillo, Thibaut Stoll, Martina Sandroni, Robin Gueret, Jérôme Fortage, Megumi Kayanuma, Chantal Daniel, Fabrice Odobel, Alain Deronzier and Marie-Noëlle Collomb

Inorg. Chem., 2018, 57, 11225
DOI: 10.1021/acs.inorgchem.8b01811

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

Kristian E. Dalle, Julien Warnan, Jane J. Leung, Bertrand Reuillard, Isabell S. Karmel and Erwin Reisner

Chem. Rev., 2019, 119, 2752
DOI: 10.1021/acs.chemrev.8b00392

Entangled Electrons Foil Synthesis of Elusive Low-Valent Vanadium Oxo Complex

Anthony W. Schlimgen, Charles W. Heaps and David A. Mazziotti

J. Phys. Chem. Lett., 2016, 7, 627
DOI: 10.1021/acs.jpclett.5b02547

Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)]n+ Complexes in Aqueous Solution

Warrick K. C. Lo, Carmen E. Castillo, Robin Gueret, Jérôme Fortage, Mateusz Rebarz, Michel Sliwa, Fabrice Thomas, C. John McAdam, Geoffrey B. Jameson, David A. McMorran, James D. Crowley, Marie-Noëlle Collomb and Allan G. Blackman

Inorg. Chem., 2016, 55, 4564
DOI: 10.1021/acs.inorgchem.6b00391

Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species

Robin Gueret, Carmen E. Castillo, Mateusz Rebarz, Fabrice Thomas, Michel Sliwa, Jérôme Chauvin, Baptiste Dautreppe, Jacques Pécaut, Jérôme Fortage and Marie-Noëlle Collomb

Inorg. Chem., 2019, 58, 9043
DOI: 10.1021/acs.inorgchem.9b00447

Elucidating Two Distinct Pathways for Electrocatalytic Hydrogen Production Using CoII Pincer Complexes

Josh Brown, Jeffrey Ovens and Darrin Richeson

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202102542

Nucleophilic and Electrophilic Molybdenum Terminal Oxo Complexes by Coordination-Induced Bond Weakening of Hydroxo O–H Bonds

H. D. A. Chathumal Jayaweera, C. Christopher Almquist, Thayalan Rajeshkumar, Wen Zhou, Laurent Maron and Warren E. Piers

Inorg. Chem., 2025, 64, 1860
DOI: 10.1021/acs.inorgchem.4c04563

Heptacoordinate CoII Complex: A New Architecture for Photochemical Hydrogen Production

Fiorella Lucarini, Mariachiara Pastore, Serhii Vasylevskyi, Massimo Varisco, Euro Solari, Aurelien Crochet, Katharina M. Fromm, Fabio Zobi and Albert Ruggi

Chemistry A European J, 2017, 23, 6768
DOI: 10.1002/chem.201701427

Ni(bpy)(cod): A Convenient Entryway into the Efficient Hydroboration of Ketones, Aldehydes, and Imines

Amanda E. King, S. Chantal E. Stieber, Neil J. Henson, Stosh A. Kozimor, Brian L. Scott, Nathan C. Smythe, Andrew D. Sutton and John C. Gordon

Eur J Inorg Chem, 2016, 2016, 1635
DOI: 10.1002/ejic.201600143

Exploring Multidimensional Chemical Spaces: Instrumentation and Chemical Systems for the Parallelization of Hydrogen Evolving Photocatalytic Reactions

Eric M. Lopato and Stefan Bernhard

Energy Fuels, 2021, 35, 18957
DOI: 10.1021/acs.energyfuels.1c02168

First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction

Lianpeng Tong, Lele Duan, Aiju Zhou and Randolph P. Thummel

Coordination Chemistry Reviews, 2020, 402, 213079
DOI: 10.1016/j.ccr.2019.213079

Coordination-driven electrocatalysts as an evolving wave of enthusiasm for sustainable hydrogen production

Sangharaj Diyali, Nilankar Diyali and Bhaskar Biswas

Coordination Chemistry Reviews, 2024, 500, 215496
DOI: 10.1016/j.ccr.2023.215496

Competition between electrocatalytic CO2 reduction and H+ reduction by Cu(II), Co(II) complexes containing redox-active ligand

Ning-Ning Shi, Xiao-Meng Yin, Wei-Song Gao, Jin-Miao Wang, Shi-Fu Zhang, Yu-Hua Fan and Mei Wang

Inorganica Chimica Acta, 2021, 526, 120548
DOI: 10.1016/j.ica.2021.120548

Light-Driven Proton Reduction in Aqueous Medium Catalyzed by a Family of Cobalt Complexes with Tetradentate Polypyridine-Type Ligands

Lianpeng Tong, Andrew Kopecky, Ruifa Zong, Kevin J. Gagnon, Mårten S. G. Ahlquist and Randolph P. Thummel

Inorg. Chem., 2015, 54, 7873
DOI: 10.1021/acs.inorgchem.5b00915

Electrochemical and photochemical-driven hydrogen evolution catalyzed by a dinuclear CoII–CoII complex

Ling-Zhi Fu, Ling-Ling Zhou, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

Journal of Power Sources, 2015, 280, 453
DOI: 10.1016/j.jpowsour.2015.01.121

Synthesis, Characterization, and Reactivity of Neutral Octahedral Alkyl-Cobalt(III) Complexes Bearing a Dianionic Pentadentate Ligand

Lucie Nurdin, Warren E. Piers, Jian-Bin Lin and Benjamin S. Gelfand

Organometallics, 2020, 39, 2269
DOI: 10.1021/acs.organomet.0c00223

Parallelization of photocatalytic gas-producing reactions

Rony S. Khnayzer, Douglas R. Martin, Charles L. Codding and Felix N. Castellano

Review of Scientific Instruments, 2015, 86
DOI: 10.1063/1.4915349

Photo‐ and Electrocatalytic H2 Production by New First‐Row Transition‐Metal Complexes Based on an Aminopyridine Pentadentate Ligand

Arnau Call, Zoel Codolà, Ferran Acuña‐Parés and Julio Lloret‐Fillol

Chemistry A European J, 2014, 20, 6171
DOI: 10.1002/chem.201303317

Improved Redox-Responsive Cobalt(II) 19F Magnetic Resonance Imaging Agents through Addition of Hydrogen Bond Donors

Kathleen M. Scott, Brooke L. Davenport, Serhii Vasylevskyi and Emily L. Que

Inorg. Chem., 2025, 64, 11130
DOI: 10.1021/acs.inorgchem.5c01465

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand‐Based Proton and Electron Transfer

Emily J. Thompson and Louise A. Berben

Angewandte Chemie, 2015, 127, 11808
DOI: 10.1002/ange.201503935

Molecular Cobalt Catalysts for H2 Generation with Redox Activity and Proton Relays in the Second Coordination Sphere

Lars Kohler, Jens Niklas, Ryan C. Johnson, Matthias Zeller, Oleg G. Poluektov and Karen L. Mulfort

Inorg. Chem., 2019, 58, 1697
DOI: 10.1021/acs.inorgchem.8b03297

Replacing Pyridine with Pyrazine in Molecular Cobalt Catalysts: Effects on Electrochemical Properties and Aqueous H2 Generation

Lars Kohler, Andrea M. Potocny, Jens Niklas, Matthias Zeller, Oleg G. Poluektov and Karen L. Mulfort

Catalysts, 2021, 11, 75
DOI: 10.3390/catal11010075

Synthesis, crystal structure, characterization of pyrazine diaminotriazine based complexes and their systematic comparative study with pyridyl diaminotriazine based complexes for light-driven hydrogen production

Sanil Rajak, Olivier Schott, Prabhjyot Kaur, Thierry Maris, Garry S. Hanan and Adam Duong

Polyhedron, 2020, 180, 114412
DOI: 10.1016/j.poly.2020.114412

HER catalysed by iron complexes without a Fe2S2 core: A review

Tashika Agarwal and Sandeep Kaur-Ghumaan

Coordination Chemistry Reviews, 2019, 397, 188
DOI: 10.1016/j.ccr.2019.06.019

New Tetracobalt Cluster Compounds for Electrocatalytic Proton Reduction: Syntheses, Structures, and Reactivity

Ping Li, Riccardo Zaffaroni, Bas de Bruin and Joost N. H. Reek

Chemistry A European J, 2015, 21, 4027
DOI: 10.1002/chem.201405052

Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts

Thibaut Stoll, Carmen E. Castillo, Megumi Kayanuma, Martina Sandroni, Chantal Daniel, Fabrice Odobel, Jérôme Fortage and Marie-Noëlle Collomb

Coordination Chemistry Reviews, 2015, 304-305, 20
DOI: 10.1016/j.ccr.2015.02.002

Electrochemical and photochemical-driven hydrogen evolution catalyzed by a dinuclear cobalt(II)–triazenido complex with high turnover number

Ling-Ling Zhou, Ling-Zhi Fu, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2015, 40, 5099
DOI: 10.1016/j.ijhydene.2015.02.072

Mechanistic Insights into Electrocatalytic Hydrogen Evolution by an Exceptionally Stable Cobalt Complex

Maria B. Brands and Joost N. H. Reek

Inorg. Chem., 2024, 63, 8484
DOI: 10.1021/acs.inorgchem.4c01043

Molecular and Electronic Structures of a Series of Dinuclear CoII Complexes Varied by Exogeneous Ligands: Influence of π‐Bonding on Redox Potentials

Felix Depenbrock, Thomas Limpke, Anja Stammler, Jan Oldengott, Hartmut Bögge and Thorsten Glaser

Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202100992

Rational development of molecular earth-abundant metal complexes for electrocatalytic hydrogen production

John Daniel McCool, Shiyuan Zhang, Inen Cheng and Xuan Zhao

Chinese Journal of Catalysis, 2022, 43, 3019
DOI: 10.1016/S1872-2067(22)64150-0

Amine axial ligand-coordinated cobalt phthalocyanine-based catalyst for flow-type membraneless hydrogen peroxide fuel cell or enzymatic biofuel cell

Heeyeon An, Hyewon Jeon, Jungyeon Ji, Yongchai Kwon and Yongjin Chung

Journal of Energy Chemistry, 2021, 58, 463
DOI: 10.1016/j.jechem.2020.10.042

A cobalt mimochrome for photochemical hydrogen evolution from neutral water

Emily H. Edwards, Jennifer M. Le, Alison A. Salamatian, Noelle L. Peluso, Linda Leone, Angela Lombardi and Kara L. Bren

Journal of Inorganic Biochemistry, 2022, 230, 111753
DOI: 10.1016/j.jinorgbio.2022.111753

Ligand-Mediated Hydrogen Evolution by Co(II) Complexes and Assessment of the Mechanism by Computational Studies

Manaswini Raj, Koushik Makhal, Aman Mishra, Bhabani S. Mallik and Sumanta Kumar Padhi

Inorg. Chem., 2023, 62, 10993
DOI: 10.1021/acs.inorgchem.3c00974

A review on nickel cobalt sulphide and their hybrids: Earth abundant, pH stable electro-catalyst for hydrogen evolution reaction

Rubab Zahra, Erum Pervaiz, Minghui Yang, Osama Rabi, Zubia Saleem, Maryum Ali and Sarah Farrukh

International Journal of Hydrogen Energy, 2020, 45, 24518
DOI: 10.1016/j.ijhydene.2020.06.236

Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes

Robert H. Morris

Chem. Rev., 2016, 116, 8588
DOI: 10.1021/acs.chemrev.5b00695

Electrocatalytic Hydrogen Evolution by Cobalt Complexes with a Redox Non-Innocent Polypyridine Ligand

Jiale Liu, Rong-Zhen Liao, Frank W. Heinemann, Karsten Meyer, Randolph P. Thummel, Yaqiong Zhang and Lianpeng Tong

Inorg. Chem., 2021, 60, 17976
DOI: 10.1021/acs.inorgchem.1c02539

Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

Agostina Mazzeo, Sol Santalla, Carina Gaviglio, Fabio Doctorovich and Juan Pellegrino

Inorganica Chimica Acta, 2021, 517, 119950
DOI: 10.1016/j.ica.2020.119950

Electrocatalytic hydrogen evolution from water at low overpotentials with cobalt complexes supported by redox-active bipyridyl-NHC donors

Lizhu Chen, Xiaojun Su and Jonah W. Jurss

Chinese Journal of Catalysis, 2022, 43, 3187
DOI: 10.1016/S1872-2067(22)64151-2

Synthesis, characterization, and catalytic properties of a cobalt(II) complex supported by an amine-bis(phenolate) ligand

Ling-Zhi Tang, Chen-Neng Lin and Shu-Zhong Zhan

Transit Met Chem, 2016, 41, 819
DOI: 10.1007/s11243-016-0083-y

Synthesis and Characterization of a Rare Transition-Metal Oxothiostannate and Investigation of Its Photocatalytic Properties

Assma Benkada, Helge Reinsch, Michael Poschmann, Jan Krahmer, Nicole Pienack and Wolfgang Bensch

Inorg. Chem., 2019, 58, 2354
DOI: 10.1021/acs.inorgchem.8b02773

A novel dinuclear cobalt-bis(thiosemicarbazone) complex as a cocatalyst to enhance visible-light-driven H2 evolution on CdS nanorods and a mechanism discussion

Hao Zhang, Hongjie Zhu, Haitao Zhao, Mingyu Dou, Xingliang Yin, Hua Yang, Dacheng Li and Jianmin Dou

Journal of Photochemistry and Photobiology A: Chemistry, 2022, 426, 113771
DOI: 10.1016/j.jphotochem.2022.113771

Hydrogen Evolution Catalysis by Cobalt Complexes of an Aza‐Bridged Bis‐1,10‐Phenanthroline Ligand Bearing Pendant Basic Sites

Bin Guan, Jiale Liu, Ji‐dong Leng, Ting Fan and Lianpeng Tong

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202401284

Rationalizing Photo‐Triggered Hydrogen Evolution Using Polypyridine Cobalt Complexes: Substituent Effects on Hexadentate Chelating Ligands

Fiorella Lucarini, David Bongni, Philippe Schiel, Gabriele Bevini, Elisabetta Benazzi, Euro Solari, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Marco Marazzi, Mirco Natali, Mariachiara Pastore and Albert Ruggi

ChemSusChem, 2021, 14, 1874
DOI: 10.1002/cssc.202100161

Photochemical Hydrogen Evolution from Neutral Water with a Cobalt Metallopeptide Catalyst

Saikat Chakraborty, Emily H. Edwards, Banu Kandemir and Kara L. Bren

Inorg. Chem., 2019, 58, 16402
DOI: 10.1021/acs.inorgchem.9b02067

Electrocatalytic hydrogen evolution by Co(II) complexes of bistriazolylpyridines

Hai-Bin Cui, Jin-Hua Li, Xiao Zhang, Min Zhou, Zhi-Zhuan Huang, Yu-Chen Lai, Jing-Xia Qiu, Ya-Jie Ren and Hua-Xin Zhang

International Journal of Hydrogen Energy, 2023, 48, 10891
DOI: 10.1016/j.ijhydene.2022.11.242

Exchange coupling states of cobalt complexes to control proton-coupled electron transfer

Jueun Lee, Junseong Lee and Junhyeok Seo

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-53099-3

A Crystalline Copper(II) Coordination Polymer for the Efficient Visible‐Light‐Driven Generation of Hydrogen

Xi‐Yan Dong, Mei Zhang, Ru‐Bo Pei, Qian Wang, Dong‐Hui Wei, Shuang‐Quan Zang, Yao‐Ting Fan and Thomas C. W. Mak

Angewandte Chemie, 2016, 128, 2113
DOI: 10.1002/ange.201509744

Charge Transfer Chromophores Derived from 3d-Row Transition Metal Complexes

Kira I. Pashanova, Irina V. Ershova, Olesya Yu. Trofimova, Roman V. Rumyantsev, Georgy K. Fukin, Artem S. Bogomyakov, Maxim V. Arsenyev and Alexandr V. Piskunov

Molecules, 2022, 27, 8175
DOI: 10.3390/molecules27238175

Porphyrin-Based Electrochemical H2 Evolution: Role of Central Metal Ion on Overpotential and Catalytic Activity

Belete B. Beyene and Chen-Hsiung Hung

Electrocatalysis, 2018, 9, 689
DOI: 10.1007/s12678-018-0477-z

Electrocatalytic H2 Evolution of Bis(3,5-di-methylpyrazol-1-yl)acetate Anchored Hexa-coordinated Co(II) Derivative

Kuheli Das, Belete B. Beyene, Amitabha Datta, Eugenio Garribba and Chen-Hsiung Hung

Catal Lett, 2018, 148, 2703
DOI: 10.1007/s10562-018-2477-2

Stepwise N‐Methylation of Ruthenium and Cobalt 5,15‐Diazaporphyrins: Post‐Functionalization of Porphyrinoid Catalysts

Mayu Nishijo, Shiho Mori, Tsubasa Nishimura, Hiroshi Shinokubo and Yoshihiro Miyake

Chemistry An Asian Journal, 2022, 17
DOI: 10.1002/asia.202200305

Competent Electrocatalytic and Photocatalytic Proton Reduction by a Dechelated [Co(tpy)2]2+ Scaffold

Ejaz Ahmad, Karunamay Majee, Jully Patel, Babulal Das and Sumanta Kumar Padhi

Eur J Inorg Chem, 2017, 2017, 3409
DOI: 10.1002/ejic.201700628

Molecular catalysts of Co, Ni, Fe, and Mo for hydrogen generation in artificial photosynthetic systems

William T. Eckenhoff

Coordination Chemistry Reviews, 2018, 373, 295
DOI: 10.1016/j.ccr.2017.11.002

Two routes to hydrogen evolution for a Co-polypyridyl complex with two open sites

Liqin Xue Toro, Sofia Kiriakidi, Anders Thapper, Sascha Ott and Marcus Lundberg

Electron. Struct., 2022, 4, 034002
DOI: 10.1088/2516-1075/ac7bca

The coordination chemistry of acyclic pentadentate pentaamine ligands

Allan G. Blackman

Polyhedron, 2019, 161, 1
DOI: 10.1016/j.poly.2018.12.004

Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight

Robin Gueret, Carmen E. Castillo, Mateusz Rebarz, Fabrice Thomas, Aaron-Albert Hargrove, Jacques Pécaut, Michel Sliwa, Jérôme Fortage and Marie-Noëlle Collomb

Journal of Photochemistry and Photobiology B: Biology, 2015, 152, 82
DOI: 10.1016/j.jphotobiol.2015.04.010

Cu-based Polyoxometalate Catalyst for Efficient Catalytic Hydrogen Evolution

Hongjin Lv, Yuanzhe Gao, Weiwei Guo, Sarah M. Lauinger, Yingnan Chi, John Bacsa, Kevin P. Sullivan, Marika Wieliczko, Djamaladdin G. Musaev and Craig L. Hill

Inorg. Chem., 2016, 55, 6750
DOI: 10.1021/acs.inorgchem.6b01032

Tuning Second Coordination Sphere Interactions in Polypyridyl–Iron Complexes to Achieve Selective Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide

David Z. Zee, Michael Nippe, Amanda E. King, Christopher J. Chang and Jeffrey R. Long

Inorg. Chem., 2020, 59, 5206
DOI: 10.1021/acs.inorgchem.0c00455

Structure–Activity and Stability Relationships for Cobalt Polypyridyl‐Based Hydrogen‐Evolving Catalysts in Water

Stephan Schnidrig, Cyril Bachmann, Peter Müller, Nicola Weder, Bernhard Spingler, Evelyne Joliat‐Wick, Mathias Mosberger, Johannes Windisch, Roger Alberto and Benjamin Probst

ChemSusChem, 2017, 10, 4570
DOI: 10.1002/cssc.201701511

Redox-Active Ligands in Electroassisted Catalytic H+ and CO2 Reductions: Benefits and Risks

Nicolas Queyriaux

ACS Catal., 2021, 11, 4024
DOI: 10.1021/acscatal.1c00237

Structure‐Functional Analysis of Hydrogen Production Catalyzed by Molecular Cobalt Complexes with Pentadentate Ligands in Aqueous Solutions

Ping Wang, Guangchao Liang, Charles Edwin Webster and Xuan Zhao

Eur J Inorg Chem, 2020, 2020, 3534
DOI: 10.1002/ejic.202000564

Electrocatalytic and photocatalytic hydrogen generation from water by a water-soluble cobalt complex supported by 2-ethyl-2-(2-hydroxybenzylideneamino)propane-1,3-diol

Ling-Zhi Tang, Chen-Neng Lin, Yun-Xiao Zhang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2016, 41, 14676
DOI: 10.1016/j.ijhydene.2016.07.011

Photo- and Electrocatalytic Hydrogen Production Using Valence Isomers of N2S2-Type Nickel Complexes

Satoshi Inoue, Manabu Mitsuhashi, Takeshi Ono, Yin-Nan Yan, Yusuke Kataoka, Makoto Handa and Tatsuya Kawamoto

Inorg. Chem., 2017, 56, 12129
DOI: 10.1021/acs.inorgchem.7b01244

Ligand Substituent Effects on Light‐Driven Hydrogen Evolution by Cobalt(II) Tripodal Iminopyridine Catalysts under Precious‐Metal‐Free Conditions

Chun‐Leung Kwok, Shun‐Cheung Cheng, Pui‐Yu Ho, Shek‐Man Yiu, Vonika Ka‐Man Au, Wing‐Kei Ho, Po‐Keung Tsang, Jing Xiang, Chi‐Fai Leung and Chi‐Chiu Ko

Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202200361

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine‐Rich Environments

Debashis Basu, Shivnath Mazumder, Xuetao Shi, Habib Baydoun, Jens Niklas, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Angew Chem Int Ed, 2015, 54, 2105
DOI: 10.1002/anie.201409813

Decoding the Catalytic Potential of Dinuclear 1st‐Row Transition Metal Complexes for Proton Reduction and Water Oxidation

Manaswini Raj and Sumanta Kumar Padhi

The Chemical Record, 2025, 25
DOI: 10.1002/tcr.202400170

New Rh2(II,II) Architecture for the Catalytic Reduction of H+

Travis A. White, Suzanne E. Witt, Zhanyong Li, Kim R. Dunbar and Claudia Turro

Inorg. Chem., 2015, 54, 10042
DOI: 10.1021/acs.inorgchem.5b01823

Kinetics and mechanistic study of electrocatalytic hydrogen evolution by [Co(Fc-tpy)2]2+

Sumanta Kumar Padhi, Ejaz Ahmad, Surabhi Rai and Binata Panda

Polyhedron, 2020, 187, 114677
DOI: 10.1016/j.poly.2020.114677

Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene)-Catalyzed Proton Reduction

Julien A. Panetier, Christopher S. Letko, T. Don Tilley and Martin Head-Gordon

J. Chem. Theory Comput., 2016, 12, 223
DOI: 10.1021/acs.jctc.5b00968

Visible Light-Driven Hydrogen Evolution from Water Catalyzed by A Molecular Cobalt Complex

Lianpeng Tong, Ruifa Zong and Randolph P. Thummel

J. Am. Chem. Soc., 2014, 136, 4881
DOI: 10.1021/ja501257d

Electronic and Steric Tuning of Catalytic H2 Evolution by Cobalt Complexes with Pentadentate Polypyridyl-Amine Ligands

Ping Wang, Guangchao Liang, M. Ramana Reddy, Melissa Long, Kandria Driskill, Christian Lyons, Bruno Donnadieu, John C. Bollinger, Charles Edwin Webster and Xuan Zhao

J. Am. Chem. Soc., 2018, 140, 9219
DOI: 10.1021/jacs.8b05108

The crystal structure of tris(6-methylpyridin-2-yl)phosphine oxide, C18H18N3OP

Gui-Ling Wu

Zeitschrift für Kristallographie - New Crystal Structures, 2022, 237, 577
DOI: 10.1515/ncrs-2022-0137

Electrocatalytic H2 Evolution by the Co‐Mabiq Complex Requires Tempering of the Redox‐Active Ligand

G. Ceren Tok, Anna T. S. Freiberg, Hubert A. Gasteiger and Corinna R. Hess

ChemCatChem, 2019, 11, 3973
DOI: 10.1002/cctc.201900953

New Transition Metal Oxo‐Thiostannate: Synthesis, Characterization, and Investigation of its Photocatalytic Properties

Assma Benkada, Michael Poschmann, Christian Näther and Wolfgang Bensch

Zeitschrift anorg allge chemie, 2019, 645, 433
DOI: 10.1002/zaac.201800475

S‐Scheme Photocatalytic Systems

Yujie Bao, Shaoqing Song, Guojian Yao and Shujuan Jiang

Solar RRL, 2021, 5
DOI: 10.1002/solr.202100118

A Biomimetic Copper Water Oxidation Catalyst with Low Overpotential

Teng Zhang, Cheng Wang, Shubin Liu, Jin-Liang Wang and Wenbin Lin

J. Am. Chem. Soc., 2014, 136, 273
DOI: 10.1021/ja409267p

Which Oxidation State Initiates Dehalogenation in the B12-Dependent Enzyme NpRdhA: CoII, CoI, or Co0?

Rong-Zhen Liao, Shi-Lu Chen and Per E. M. Siegbahn

ACS Catal., 2015, 5, 7350
DOI: 10.1021/acscatal.5b01502

Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines

Eric S. Wiedner, Aaron M. Appel, Daniel L. DuBois and R. Morris Bullock

Inorg. Chem., 2013, 52, 14391
DOI: 10.1021/ic4025475

Redox-Induced Structural Switching through Sporadic Pyridine-Bridged CoIICoII Dimer and Electrocatalytic Proton Reduction

Sumanta Kumar Padhi, Surabhi Rai and Sk Samim Akhter

Inorg. Chem., 2020, 59, 7810
DOI: 10.1021/acs.inorgchem.0c00911

Electro‐ and Photocatalytic Generation of H2 Using a Distinctive CoII “PN3P” Pincer Supported Complex with Water or Saturated Saline as a Hydrogen Source

Gyandshwar Kumar Rao, Wendy Pell, Bulat Gabidullin, Ilia Korobkov and Darrin Richeson

Chemistry A European J, 2017, 23, 16763
DOI: 10.1002/chem.201704882

Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non‐Innocent N3P2 Ligand: Synthesis, Characterization, and Catalytic Properties

Denan Wang, Danushka M. Ekanayake, Sergey V. Lindeman, Cláudio N. Verani and Adam T. Fiedler

Eur J Inorg Chem, 2018, 2018, 4133
DOI: 10.1002/ejic.201800843

Synergistic interplay between semiconductor nanostructure/quantum dots based photosensitizer and Co/Ni-based catalyst for efficient photocatalytic hydrogen production

Rahat Gupta, Kamalika Bandyopadhyay and Amlan K. Pal

Chemical Engineering Journal, 2025, 520, 166164
DOI: 10.1016/j.cej.2025.166164

Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water

Yujie Sun, Chong Liu, David C. Grauer, Junko Yano, Jeffrey R. Long, Peidong Yang and Christopher J. Chang

J. Am. Chem. Soc., 2013, 135, 17699
DOI: 10.1021/ja4094764

Computational Study on the Proton Reduction Potential of Co, Rh, and Ir Molecular Electrocatalysts for the Hydrogen Evolution Reaction

Murugesan Panneerselvam, Madhavan Jaccob and Luciano T. Costa

ACS Omega, 2024, 9, 48766
DOI: 10.1021/acsomega.4c03260

Ligand-Based Redox: Catalytic Applications and Mechanistic Aspects

Kirti Singh, Abhishek Kundu and Debashis Adhikari

ACS Catal., 2022, 12, 13075
DOI: 10.1021/acscatal.2c02655

Electro- and photocatalytic hydrogen evolution by a cobalt complex based on a tripodal iminopyridine ligand

Xiaowei Song, Huimin Wen, Chengbing Ma and Changneng Chen

Polyhedron, 2014, 81, 639
DOI: 10.1016/j.poly.2014.07.031

A Well-Defined Terminal Vanadium(III) Oxo Complex

Amanda E. King, Michael Nippe, Mihail Atanasov, Teera Chantarojsiri, Curtis A. Wray, Eckhard Bill, Frank Neese, Jeffrey R. Long and Christopher J. Chang

Inorg. Chem., 2014, 53, 11388
DOI: 10.1021/ic5010177

Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water

Amit Das, Zhiji Han, William W. Brennessel, Patrick L. Holland and Richard Eisenberg

ACS Catal., 2015, 5, 1397
DOI: 10.1021/acscatal.5b00045

Kinetic Analysis of Competitive Electrocatalytic Pathways: New Insights into Hydrogen Production with Nickel Electrocatalysts

Eric S. Wiedner, Houston J. S. Brown and Monte L. Helm

J. Am. Chem. Soc., 2016, 138, 604
DOI: 10.1021/jacs.5b10853

Synthesis, structure and electrocatalytic properties of a water‐soluble copper complex supported by 2‐ethyl‐2‐(2‐hydroxybenzylideneamino)propane‐1,3‐diol ligand

Dong Li, Ling‐Zhi Tang, Yan Liu and Shu‐Zhong Zhan

Applied Organom Chemis, 2017, 31
DOI: 10.1002/aoc.3797

Co(II) pincer complexes bearing functionalized pyridyl benzothiazoles/(thio)amides. κ3-SNS versus XNS (where X = N or O) pincer complexes for electrocatalytic hydrogen evolution reaction in acetonitrile

Crystal M. Thompson, Elizabeth A. Tonsel-White, Alvin A. Holder and Mark A.W. Lawrence

Inorganica Chimica Acta, 2025, 588, 122877
DOI: 10.1016/j.ica.2025.122877

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine‐Rich Environments

Debashis Basu, Shivnath Mazumder, Xuetao Shi, Habib Baydoun, Jens Niklas, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Angewandte Chemie, 2015, 127, 2133
DOI: 10.1002/ange.201409813

Visible Light Driven Hydrogen Evolution by Molecular Nickel Catalysts with Time-Resolved Spectroscopic and DFT Insights

Xian Liang Ho, Haiyan Shao, Yik Yie Ng, Rakesh Ganguly, Yunpeng Lu and Han Sen Soo

Inorg. Chem., 2019, 58, 1469
DOI: 10.1021/acs.inorgchem.8b03003

Recent developments in hydrogen evolving molecular cobalt(II)–polypyridyl catalysts

Nicolas Queyriaux, Reuben T. Jane, Julien Massin, Vincent Artero and Murielle Chavarot-Kerlidou

Coordination Chemistry Reviews, 2015, 304-305, 3
DOI: 10.1016/j.ccr.2015.03.014

Catalytic oxidation of aqueous sulfide in the presence of ferrites (MFe2O4, M=Fe, Cu, Co)

Igor T. Cunha, Ivo F. Teixeira, Adriana S. Albuquerque, José D. Ardisson, Waldemar A.A. Macedo, Henrique S. Oliveira, Juliana C. Tristão, Karim Sapag and Rochel M. Lago

Catalysis Today, 2016, 259, 222
DOI: 10.1016/j.cattod.2015.07.023

Elucidating the Key Role of pH on Light-Driven Hydrogen Evolution by a Molecular Cobalt Catalyst

Mirco Natali

ACS Catal., 2017, 7, 1330
DOI: 10.1021/acscatal.6b03087

Synthesis and electro- and photo-catalytic properties of a dinuclear cobalt(III) complex supported by 2-pyridylamino-N,N-bis(2-methylene-4,6-bimethyl)phenol

Ling-Zhi Fu, Ling-Ling Zhou, Qian-Nan Liang, Chang Fang and Shu-Zhong Zhan

Polyhedron, 2016, 107, 83
DOI: 10.1016/j.poly.2015.11.019