An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

Robert E. Mulvey

Dalton Trans., 2013, 42, 6676
DOI: 10.1039/c3dt00053b

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complex

Alan R. Kennedy, Robert E. Mulvey, Donna L. Ramsay and Stuart D. Robertson

Dalton Trans., 2015, 44, 5875
DOI: 10.1039/C5DT00247H

Schiff-base -ate derivatives with main group metals: generation of a tripodal aluminate metalloligand

Francisco M. García-Valle, Vanessa Tabernero, Tomás Cuenca, Jesús Cano and Marta E. G. Mosquera

Dalton Trans., 2018, 47, 6499
DOI: 10.1039/C8DT00835C

Boron, aluminium, gallium, indium and thallium

Michael J. Ingleson

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2013, 109, 28
DOI: 10.1039/c3ic90004e

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation–alkylaluminium-trapping reagents?

David R. Armstrong, Elaine Crosbie, Eva Hevia, Robert E. Mulvey, Donna L. Ramsay and Stuart D. Robertson

Chem. Sci., 2014, 5, 3031
DOI: 10.1039/C4SC01108B

Generation of functionalized aryl and heteroaryl aluminum reagents by halogen–lithium exchange

Thomas Klatt, Klaus Groll and Paul Knochel

Chem. Commun., 2013, 49, 6953
DOI: 10.1039/c3cc43356k

Neutron Diffraction Characterization of C–H···Li Interactions in a Lithium Aluminate Polymer

Jacqueline M. Cole, Paul G. Waddell, Andrew E. H. Wheatley, Garry J. McIntyre, Andrew J. Peel, Christopher W. Tate and David J. Linton

Organometallics, 2014, 33, 3919
DOI: 10.1021/om500271p

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

Stuart D. Robertson, Marina Uzelac and Robert E. Mulvey

Chem. Rev., 2019, 119, 8332
DOI: 10.1021/acs.chemrev.9b00047

Arene Activation by Calcium Hydride/Zinc Amide Equilibration

Kyle G. Pearce, Agustín Morales, Michael S. Hill, Mary F. Mahon and Claire L. McMullin

J. Am. Chem. Soc., 2025, 147, 29554
DOI: 10.1021/jacs.5c10735

Tetraamine Me6TREN induced monomerization of alkali metal borohydrides and aluminohydrides

Alan R. Kennedy, Ross McLellan, Greg J. McNeil, Robert E. Mulvey and Stuart D. Robertson

Polyhedron, 2016, 103, 94
DOI: 10.1016/j.poly.2015.08.046

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

Indranirekha Saikia, Arun Jyoti Borah and Prodeep Phukan

Chem. Rev., 2016, 116, 6837
DOI: 10.1021/acs.chemrev.5b00400

Hydrocarbon Soluble Alkali‐Metal‐Aluminium Hydride Surrog[ATES]

Sumanta Banerjee, Peter A. Macdonald, Samantha A. Orr, Alan R. Kennedy, Alexander van Teijlingen, Stuart D. Robertson, Tell Tuttle and Robert E. Mulvey

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201085

Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal Synergistic Syntheses

William Clegg, Elaine Crosbie, Sophie H. Dale-Black, Eva Hevia, Gordon W. Honeyman, Alan R. Kennedy, Robert E. Mulvey, Donna L. Ramsay and Stuart D. Robertson

Organometallics, 2015, 34, 2580
DOI: 10.1021/om5012352

Contrasting Reactivity of Mono- versus Bis-2,2,6,6-tetramethylpiperidide Lithium Aluminates Towards Polydentate Lewis Bases: Co-Complexation Versus Deprotonation

Ross Campbell, Elaine Crosbie, Alan R. Kennedy, Robert E. Mulvey, Rachael A. Naismith and Stuart D. Robertson

Australian Journal of Chemistry, 2013, 66, 1189
DOI: 10.1071/CH13157

Silver(I)-Catalyzed Iodination of Arenes: Tuning the Lewis Acidity of N-Iodosuccinimide Activation

Daugirdas T. Racys, Salaheddin A. I. Sharif, Sally L. Pimlott and Andrew Sutherland

J. Org. Chem., 2016, 81, 772
DOI: 10.1021/acs.joc.5b02761

Aluminum Alkali Metalate Derivatives: Factors Driving the Final Nuclearity in the Crystal Form

M. Teresa Muñoz, Gotzone Barandika, Begoña Bazán, Tomás Cuenca and Marta E. G. Mosquera

Eur J Inorg Chem, 2017, 2017, 1994
DOI: 10.1002/ejic.201601428

ChemInform Abstract: Regioselective Heterohalogenation of 4‐Halo‐anisoles via a Series of Sequential ortho‐Aluminations and Electrophilic Halogenations.

Ben Conway, Elaine Crosbie, Alan R. Kennedy, Robert E. Mulvey and Stuart D. Robertson

ChemInform, 2012, 43
DOI: 10.1002/chin.201235057

Trans‐Metal‐Trapping: Concealed Crossover Complexes En Route to Transmetallation?

Marina Uzelac and Robert E. Mulvey

Chemistry A European J, 2018, 24, 7786
DOI: 10.1002/chem.201800489

Lithium Aluminate Complexes and Alumoles from 1,4-Dilithio-1,3-Butadienes and AlEt2Cl

Yongliang Zhang, Junnian Wei, Wen-Xiong Zhang and Zhenfeng Xi

Inorg. Chem., 2015, 54, 10695
DOI: 10.1021/acs.inorgchem.5b01551

Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization

Francisco M. García-Valle, Vanessa Tabernero, Tomás Cuenca, Jesús Cano and Marta E. G. Mosquera

Molecules, 2018, 23, 3108
DOI: 10.3390/molecules23123108

Reactivity studies and structural outcomes of a bulky dialkylaluminium amide in the presence of the N-heterocyclic carbene, ItBu

Victoria A. Pollard, Maria-Angeles Fuentes, Stuart D. Robertson, Catherine Weetman, Alan R. Kennedy, Josh Brownlie, Fraser J. Angus, Cooper Smylie and Robert E. Mulvey

Polyhedron, 2021, 209, 115469
DOI: 10.1016/j.poly.2021.115469

Insights into LiAlH4 Catalyzed Imine Hydrogenation

Holger Elsen, Jens Langer, Gerd Ballmann, Michael Wiesinger and Sjoerd Harder

Chemistry A European J, 2021, 27, 401
DOI: 10.1002/chem.202003862