Gourishetty Srikanth, Anil Ravi, Anusha Sebastian, Jobi Joseph, Monther A. Khanfar, Mohammed I. El‐Gamal, Raed A. Al‐Qawasmeh, Imad A. Abu‐Yousef, Amin F. Majdalawieh and Taleb H. Al‐Tel

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202201354

An efficient synthesis of 3-substituted indole derivates under ultrasound irradiation

Zhengyan Fu and Huawu Shao

Ultrasonics Sonochemistry, 2011, 18, 520
DOI: 10.1016/j.ultsonch.2010.09.007

Rhodium(III)‐Catalyzed Intramolecular Redox‐Neutral Annulation of Tethered Alkynes: Formal Total Synthesis of (±)‐Goniomitine

Bing Zhou, Juanjuan Du, Yaxi Yang and Yuanchao Li

Chemistry A European J, 2014, 20, 12768
DOI: 10.1002/chem.201403973

Application of the Pictet–Spengler reaction to aryl amine substrates linked to deactivated aromatic heterosystems

B. Saha, S. Sharma, D. Sawant and B. Kundu

Tetrahedron, 2008, 64, 8676
DOI: 10.1016/j.tet.2008.07.003

Vinylation of Nitro‐Substituted Indoles, Quinolinones, and Anilides with Grignard Reagents

Riccardo Egris, Mercedes Villacampa and J. Carlos Menéndez

Chemistry A European J, 2009, 15, 10930
DOI: 10.1002/chem.200901322

N‐Heterocyclic‐Carbene‐Catalyzed Synthesis of 2‐Aryl Indoles

M. Todd Hovey, Christopher T. Check, Alexandra F. Sipher and Karl A. Scheidt

Angew Chem Int Ed, 2014, 53, 9603
DOI: 10.1002/anie.201405035

Design, Synthesis, Molecular Docking, and in vitro Cytotoxicity Studies of Marine Natural Product Herdmanine Derivatives as Multitarget Inhibitor for EGFR and HER2 Breast Cancer Proteins

Gunjan, Pradeep Kumar, Nikita Goel, Samarth Ganjoo, Monika Yadav, Anita Kamra Verma and Sunita Bhagat

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202401308

Rhodium‐Catalyzed CH Annulation of Nitrones with Alkynes: A Regiospecific Route to Unsymmetrical 2,3‐Diaryl‐Substituted Indoles

Hao Yan, Haolong Wang, Xincheng Li, Xiaoyi Xin, Chunxiang Wang and Boshun Wan

Angewandte Chemie, 2015, 127, 10759
DOI: 10.1002/ange.201503997

Palladium-Catalyzed Sequential C–H Activation/Amination with Diaziridinone: An Approach to Indoles

Jing Li, Jinhua Chen, Luying Wang and Yian Shi

Org. Lett., 2021, 23, 3646
DOI: 10.1021/acs.orglett.1c01043

Iron-catalyzed synthesis of heterocycles

Krishna C. Majumdar, Nirupam De, Tapas Ghosh and Brindaban Roy

Tetrahedron, 2014, 70, 4827
DOI: 10.1016/j.tet.2014.04.025

Direct Access to (±)‐10‐Desbromoarborescidine A from Tryptamine and Pentane‐1,5‐diol

Apurba Ranjan Sahoo, Gummidi Lalitha, V. Murugesh, Christian Bruneau, Gangavaram V. M. Sharma, Surisetti Suresh and Mathieu Achard

Asian J Org Chem, 2020, 9, 910
DOI: 10.1002/ajoc.202000188

Organocatalytic Chemo-, (E/Z)- and Enantioselective Formal Alkenylation of Indole-Derived Hydroxylactams Using o-Hydroxystyrenes as a Source of Alkenyl Group

Hong-Hao Zhang, Yue-Ming Wang, Yuan-Wei Xie, Zi-Qi Zhu, Feng Shi and Shu-Jiang Tu

J. Org. Chem., 2014, 79, 7141
DOI: 10.1021/jo501293m

Rh(III)‐Catalyzed [3+2] Annulation and C−H Alkenylation of Indoles with 1,3‐Diynes by C−H Activation

Sanjeev Kumar, Saiprasad Nunewar, Khan Mohammad Usama and Vinaykumar Kanchupalli

Eur J Org Chem, 2021, 2021, 2223
DOI: 10.1002/ejoc.202100212

Biomimetic Cyclization of Epoxide Precursors of Indole Mono-, Sesqui- and Diterpene Alkaloids by Lewis Acids

Tetsuya ISAKA, Morifumi HASEGAWA and Hiroaki TOSHIMA

Bioscience, Biotechnology, and Biochemistry, 2011, 75, 2213
DOI: 10.1271/bbb.110511

Catalytic Asymmetric Pictet–Spengler-Type Reaction for the Synthesis of Optically Active Indolo[3,4-cd][1]benzazepines

Dao-Juan Cheng, Hai-Bian Wu and Shi-Kai Tian

Org. Lett., 2011, 13, 5636
DOI: 10.1021/ol202361t

Ruthenium(II)-Catalyzed Regioselective Ortho C–H Allenylation of Electron-Rich Aniline and Phenol Derivatives

Yanni Chen, Liuyu Hu, Liuchun Liang, Fujiang Guo, Yaxi Yang and Bing Zhou

J. Org. Chem., 2020, 85, 2048
DOI: 10.1021/acs.joc.9b02787

Synthesis of pyrimido [4, 5-b] indoles using heteropoly-11-molybdo-1-vanadophosphoric acid supported on montmorillonite K10 clay as catalyst: A Green Approach

M. Kumaresan, K. Selvakumar and P. Sami

Materials Today: Proceedings, 2017, 4, 12437
DOI: 10.1016/j.matpr.2017.10.014

Synthesis of Benzocyclohepta[b]indoles by Lewis Acid Catalyzed Annulation of Two 3-(1H-Isochromen-1-yl)-1H-indoles

Ye-Xiang Xie, Ri-Yuan Tang, Ren-Jie Song, Jian-Nan Xiang and Jin-Heng Li

J. Org. Chem., 2014, 79, 686
DOI: 10.1021/jo4024667

Rhodium(III)‐Catalyzed Regioselective Direct C4‐Alkylation and C2‐Annulation of Indoles: Straightforward Access to Indolopyridone

Aniruddha Biswas and Rajarshi Samanta

Eur J Org Chem, 2018, 2018, 1426
DOI: 10.1002/ejoc.201701755

Tandem Wittig – Reductive annulation decarboxylation approach for the synthesis of indole and 2-substituted indoles

Prajesh S. Volvoikar and S.G. Tilve

Tetrahedron Letters, 2018, 59, 1851
DOI: 10.1016/j.tetlet.2018.04.001

Cis‐Diastereoselectivity in Pictet–Spengler Reactions of L‐Tryptophan and Electronic Circular Dichroism Studies

Naghmana Rashid, Samina Alam, Mashooda Hasan, Naeema Khan, Khalid M. Khan, Helmut Duddeck, Gennaro Pescitelli, Ágnes Kenéz, Sándor Antus, and Tibor Kurtán

Chirality, 2012, 24, 789
DOI: 10.1002/chir.22070

A Cascade Coupling Strategy for One‐Pot Total Synthesis of β‐Carboline and Isoquinoline‐Containing Natural Products and Derivatives

Yan‐Ping Zhu, Mei‐Cai Liu, Qun Cai, Feng‐Cheng Jia and An‐Xin Wu

Chemistry A European J, 2013, 19, 10132
DOI: 10.1002/chem.201301734

Synthesis of Tetracyclic Tetrahydro‐β‐carbolines by Acid‐Promoted One‐Pot Sequential Formation of C−C and C−N Bonds

Vemu Nagaraju, Dalovai Purnachander, Kommuru Goutham, Surisetti Suresh, Balasubramanian Sridhar and Galla V. Karunakar

Asian J Org Chem, 2016, 5, 1378
DOI: 10.1002/ajoc.201600349

Highly Enantioselective Tandem Michael Addition of Tryptamine‐Derived Oxindoles to Alkynones: Concise Synthesis of Strychnos Alkaloids

Weigang He, Jiadong Hu, Pengyan Wang, Le Chen, Kai Ji, Siyu Yang, Yin Li, Zhilong Xie and Weiqing Xie

Angewandte Chemie, 2018, 130, 3868
DOI: 10.1002/ange.201800567

Conjugate Addition of Indoles and Pyrroles to Dihydronitronaphthalenes in Water: Synthesis of 3,4‐Fused Tetrahydro‐β‐carbolines

Rajesh Malhotra, Rajib Ghosh, Tushar K. Dey, Sagar Chakrabarti, Amit Ghosh, Swarup Dutta, Sonika Asijaa, Subho Roy, Shantanu Dutta, Sourav Basu and Saumen Hajra

Eur J Org Chem, 2013, 2013, 772
DOI: 10.1002/ejoc.201201288

Synthesis of Indoles and Pyrroles Utilizing Iridium Carbenes Generated from Sulfoxonium Ylides

Janakiram Vaitla, Annette Bayer and Kathrin H. Hopmann

Angewandte Chemie, 2017, 129, 4341
DOI: 10.1002/ange.201610520

Indolization of N-Aryl Tertiary Amines with Diazoacetates by a Single Organophotocatalyst

Wei Li, Jie Qiu, Hengyuan Li, Wanli Chen, Cheng Hou and Huaifeng Li

Org. Lett., 2023, 25, 3778
DOI: 10.1021/acs.orglett.3c01288

Synthesis of Indoles through Domino Reactions of 2‐Fluorotoluenes and Nitriles

Jianyou Mao, Zhiting Wang, Xinyu Xu, Guoqing Liu, Runsheng Jiang, Haixing Guan, Zhipeng Zheng and Patrick J. Walsh

Angew Chem Int Ed, 2019, 58, 11033
DOI: 10.1002/anie.201904658

Synthesis of indoles via palladium-catalyzed C–H activation of N-aryl amides followed by coupling with alkynes

Feng Zhou, Xiuling Han and Xiyan Lu

Tetrahedron Letters, 2011, 52, 4681
DOI: 10.1016/j.tetlet.2011.07.009

Platinum-Catalyzed Allylation of 2,3-Disubstituted Indoles with Allylic Acetates

Bai-Jing Peng, Wen-Ting Wu and Shyh-Chyun Yang

Molecules, 2017, 22, 2097
DOI: 10.3390/molecules22122097

Palladium-catalyzed synthesis of indole fused coumarins via cross-dehydrogenative coupling

Amrita Dey, Md Ashif Ali, Sourav Jana, Sadhanendu Samanta and Alakananda Hajra

Tetrahedron Letters, 2017, 58, 313
DOI: 10.1016/j.tetlet.2016.12.010

N‐Heterocyclic‐Carbene‐Catalyzed Synthesis of 2‐Aryl Indoles

M. Todd Hovey, Christopher T. Check, Alexandra F. Sipher and Karl A. Scheidt

Angewandte Chemie, 2014, 126, 9757
DOI: 10.1002/ange.201405035

Gold‐catalyzed Rapid Construction of Nitrogen‐containing Heterocyclic Compound Library with Scaffold Diversity and Molecular Complexity

Jin Qiao, Xiuwen Jia, Pinyi Li, Xiaoyan Liu, Jingwei Zhao, Yu Zhou, Jiang Wang, Hong Liu and Fei Zhao

Adv Synth Catal, 2019, 361, 1419
DOI: 10.1002/adsc.201801494

Palladium-Catalyzed Reaction of 2-Alkynylanilines with 2-Vinylaziridines─Access to 3-Allylated Indoles

Xian Xiao and Zhong-Xia Wang

J. Org. Chem., 2025, 90, 16594
DOI: 10.1021/acs.joc.5c02278

A new CAN-catalyzed domino process related to the Nenitzescu reaction: very concise access to fused ortho-indolequinones from simple precursors

Padmakar A. Suryavanshi, Vellaisamy Sridharan and J. Carlos Menéndez

Tetrahedron, 2013, 69, 5401
DOI: 10.1016/j.tet.2013.04.101

Mn(II)-catalyzed synthesis of benzo[f]indole-4,9-diones via vinyl azides and 2-hydroxynaphthoquinone

Shanshan Guo, Binhui Chen, Xiao Guo, Guolin Zhang and Yongping Yu

Tetrahedron, 2015, 71, 9371
DOI: 10.1016/j.tet.2015.08.067

Ru(II)-catalyzed regioselective C-7 hydroxymethylation of indolines with formaldehyde

Yanni Chen, Shili Wan, Yunxiang Wu, Yaxi Yang and Bing Zhou

Tetrahedron Letters, 2019, 60, 1481
DOI: 10.1016/j.tetlet.2019.04.052

Ring-Closing Metathesis/Isomerization/Pictet–Spengler Cascade via Ruthenium/Chiral Phosphoric Acid Sequential Catalysis

Quan Cai, Xiao-Wei Liang, Shou-Guo Wang, Jun-Wei Zhang, Xiao Zhang and Shu-Li You

Org. Lett., 2012, 14, 5022
DOI: 10.1021/ol302215u

FeCl3 catalyzed intermolecular reaction between enol ethers and anilines: Access to 2,3-substituted indoles through aryl group migration

Tapan Kumar Jena and Faiz Ahmed Khan

Tetrahedron Letters, 2020, 61, 152583
DOI: 10.1016/j.tetlet.2020.152583

A one-pot three-component synthesis of fused Spiro-Indoline/Indene derivatives derived from ethynyl azaindole by 1,3-dipolar cycloaddition reaction

Manjunatha Narayanarao, Lokesh Koodlur, Subramanya Gopal, Suman Y. Reddy and Susmita Kamila

Synthetic Communications, 2018, 48, 2441
DOI: 10.1080/00397911.2018.1508722

RECENT PROGRESS IN METAL ASSISTED MULTICOMPONENT SYNTHESES OF HETEROCYCLES

Pradip Kumar Maji, Rafique Ul Islam and Sujit Kumar Bera

HETEROCYCLES, 2014, 89, 869
DOI: 10.3987/REV-13-781

From Cyclic CF3-ketimines to a Family of Trifluoromethylated Nazlinine and Trypargine Analogues

Olga I. Shmatova, Victor N. Khrustalev and Valentine G. Nenajdenko

Org. Lett., 2016, 18, 4494
DOI: 10.1021/acs.orglett.6b02031

Baylis–Hillman Reaction of 1‐Formyl‐β‐carboline: One‐Step Synthesis of the Canthin‐6‐one Framework by an Unprecedented Cascade Cyclization Reaction

Virender Singh, Samiran Hutait and Sanjay Batra

Eur J Org Chem, 2009, 2009, 6211
DOI: 10.1002/ejoc.200900962

Rhodium‐Catalyzed Selective C−H Alkenylation of Indole at C4 Position

Qingyi Wu, Pan Gao and Yu Yuan

Asian J Org Chem, 2021, 10, 749
DOI: 10.1002/ajoc.202000721

Synthesis of 3-Iminoindol-2-amines and Cyclic Enaminones via Palladium-Catalyzed Isocyanide Insertion-Cyclization

Yuan-Yuan Pan, Ya-Nan Wu, Zhen-Zhen Chen, Wen-Juan Hao, Guigen Li, Shu-Jiang Tu and Bo Jiang

J. Org. Chem., 2015, 80, 5764
DOI: 10.1021/acs.joc.5b00727

An Efficient Difluorohydroxylation of Indoles Using Selectfluor as a Fluorinating Reagent

Riyuan Lin, Shengtao Ding, Zhuangzhi Shi and Ning Jiao

Org. Lett., 2011, 13, 4498
DOI: 10.1021/ol201896p

Revised Structure of the Alkaloid Drymaritin

Isolde Wetzel, Lars Allmendinger and Franz Bracher

J. Nat. Prod., 2009, 72, 1908
DOI: 10.1021/np900515b

Palladium‐katalysierte oxidative Cyclisierung von N‐Aryl‐Enaminen: von Anilinen zu Indolen

Sebastian Würtz, Souvik Rakshit, Julia J. Neumann, Thomas Dröge and Frank Glorius

Angewandte Chemie, 2008, 120, 7340
DOI: 10.1002/ange.200802482

Rhodium(III)‐Catalyzed Synthesis of Indole Derivatives From Pyrimidyl‐Substituted Anilines and Diazo Compounds

Ke Yu, Yujie Liang, Bin Li and Baiquan Wang

Adv Synth Catal, 2016, 358, 661
DOI: 10.1002/adsc.201500954

Synthesis of 2,3-Disubstituted NH Indoles via Rhodium(III)-Catalyzed C–H Activation of Arylnitrones and Coupling with Diazo Compounds

Xin Guo, Jianwei Han, Yafeng Liu, Mingda Qin, Xueguo Zhang and Baohua Chen

J. Org. Chem., 2017, 82, 11505
DOI: 10.1021/acs.joc.7b02105

Boron Trichloride‐Mediated Synthesis of Indoles via the Aminoboration of Alkynes

Jiahang Lv, Binlin Zhao, Li Liu, Ying Han, Yu Yuan and Zhuangzhi Shi

Adv Synth Catal, 2018, 360, 4054
DOI: 10.1002/adsc.201800509

Detection of Lysosome by a Fluorescent Heterocycle: Development of Fused Pyrido–Imidazo–Indole Framework via Cu-Catalyzed Tandem N-Arylation

Biswadip Banerji, Satadru Chatterjee, Kadaiahgari Chandrasekhar, Saswati Ghosh, Kaustuv Mukherjee and Chitra Mandal

J. Org. Chem., 2018, 83, 13011
DOI: 10.1021/acs.joc.8b01513

Access to Six- and Seven-Membered 1,7-Fused Indolines via Rh(III)-Catalyzed Redox-Neutral C7-Selective C–H Functionalization of Indolines with Alkynes and Alkenes

Xuan Wang, Huanyu Tang, Huijin Feng, Yuanchao Li, Yaxi Yang and Bing Zhou

J. Org. Chem., 2015, 80, 6238
DOI: 10.1021/acs.joc.5b00684

Metal-catalyzed dehydrogenative synthesis of pyrroles and indoles from alcohols

Giorgio Chelucci

Coordination Chemistry Reviews, 2017, 331, 37
DOI: 10.1016/j.ccr.2016.09.014

Convenient Synthesis of 3-Alkoxy-3-aryloxindoles by Intramolecular Arylation of Mandelic Amides

J. Mikael Hillgren and Stephen P. Marsden

J. Org. Chem., 2008, 73, 6459
DOI: 10.1021/jo8010842

Reductive aromatization of oxindoles to 3-substituted indoles

Tirtha Mandal, Gargi Chakraborti and Jyotirmayee Dash

Tetrahedron Letters, 2020, 61, 152109
DOI: 10.1016/j.tetlet.2020.152109

Iridium-Catalyzed Synthesis of Indole Derivatives from N-Aryl-2-aminopyridines and Vinylene Carbonate

Zhen Liang, Weiyan Xu, Yi Chen, Huayu Qiu, Yezhe Zhao, Jiabin Shen and Min Wang

Chinese Journal of Organic Chemistry, 2025, 45, 2149
DOI: 10.6023/cjoc202411025

Site-Selective Cross-Coupling of Dichlorinated Benzo-Fused Nitrogen-Heterocycles with Grignard Reagents

Hideyuki Konishi, Tatsuya Itoh and Kei Manabe

Chem. Pharm. Bull., 2010, 58, 1255
DOI: 10.1248/cpb.58.1255

A [4+1] Cyclative Capture Approach to 3H‐Indole‐N‐oxides at Room Temperature by Rhodium(III)‐Catalyzed CH Activation

Yaxi Yang, Xuan Wang, Yuanchao Li and Bing Zhou

Angew Chem Int Ed, 2015, 54, 15400
DOI: 10.1002/anie.201508702

A Fast Track to Indoles and Annulated Indoles through ortho- vs ipso-Amination of Aryl Halides

Farnaz Jafarpour, Mehran Ghasemi, Farid Mohaghegh, Sara Asgari and Azizollah Habibi

Org. Lett., 2019, 21, 10143
DOI: 10.1021/acs.orglett.9b04202

Three-component domino reaction synthesis of highly functionalized bicyclic pyrrole derivatives

Xue-Bing Chen, Xiao-Ying Wang, Dan-Dan Zhu, Sheng-Jiao Yan and Jun Lin

Tetrahedron, 2014, 70, 1047
DOI: 10.1016/j.tet.2013.12.062

Chiral-Phosphoric-Acid-Catalyzed C6-Selective Pictet–Spengler Reactions for Construction of Polycyclic Indoles Containing Spiro Quaternary Stereocenters

Xin-Wei Wang, Wen-Jun Huang, Han Wang, Bo Wu and Yong-Gui Zhou

Org. Lett., 2022, 24, 1727
DOI: 10.1021/acs.orglett.2c00368

Alkoxylation Followed by Iodination of Oxindole with Alcohols Mediated by Hypervalent Iodine Reagent in the Presence of Iodine

Rajendraprasad Kotagiri and Ramesh Adepu

Eur J Org Chem, 2018, 2018, 4556
DOI: 10.1002/ejoc.201800723

Chemo‐ and Regioselective Synthesis of Functionalized 1H‐imidazo[1,5‐a]indol‐3(2H)‐ones via a Redox‐Neutral Rhodium(III)‐Catalyzed [4+1] Annulation between Indoles and Alkynes

Fei Zhao, Jing Chen, Jin Qiao, Yangbin Lu, Xiaoning Zhang, Hui Mao, Shiyao Lu, Xin Gong, Siyu Liu, Xiaowei Wu and Long Dai

Adv Synth Catal, 2021, 363, 4380
DOI: 10.1002/adsc.202100555

Regiocontrolled Direct C−H Arylation of Indoles at the C4 and C5 Positions

Youqing Yang, Pan Gao, Yue Zhao and Zhuangzhi Shi

Angew Chem Int Ed, 2017, 56, 3966
DOI: 10.1002/anie.201612599

Preparation of Fully Substituted Anilines for the Synthesis of Functionalized Indoles

Armin H. Stoll and Paul Knochel

Org. Lett., 2008, 10, 113
DOI: 10.1021/ol7025872

Palladium‐Catalyzed Oxidative Cyclization of N‐Aryl Enamines: From Anilines to Indoles

Sebastian Würtz, Souvik Rakshit, Julia J. Neumann, Thomas Dröge and Frank Glorius

Angew Chem Int Ed, 2008, 47, 7230
DOI: 10.1002/anie.200802482

Direct C‐2 Carboxylation of 3‐Substituted Indoles Using a Combined Brønsted Base Consisting of LiO‐tBu/CsF/18‐crown‐6

Masanori Shigeno, Itsuki Tohara, Kanako Nozawa‐Kumada and Yoshinori Kondo

Eur J Org Chem, 2020, 2020, 1987
DOI: 10.1002/ejoc.202000272

Metal-free cascade boron–heteroatom addition and alkylation with diazo compounds

Jiahang Lv, Binlin Zhao, Ying Han, Yu Yuan and Zhuangzhi Shi

Chinese Chemical Letters, 2021, 32, 691
DOI: 10.1016/j.cclet.2020.06.028

One‐Pot Copper‐Catalyzed Cascade Bicyclization Strategy for Synthesis of 2‐(1H‐Indol‐1‐yl)‐4,5‐dihydrothiazoles and 2‐(1H‐Indol‐1‐yl)thiazol‐5‐yl Aryl Ketones with Molecular Oxygen as an Oxygen Source

Jialin Xie, Zhonglin Guo, Yuanqiong Huang, Yi Qu, Hongjian Song, Haibin Song, Yuxiu Liu and Qingmin Wang

Adv Synth Catal, 2019, 361, 490
DOI: 10.1002/adsc.201801193

HFIP-directed dehydrative cross-coupling: efficient synthesis of unsymmetrical triarylmethanes

Dongsheng Xiang, Abdul Basit, Kaijin Sun, Rui Xiao and Ying-Guo Liu

Tetrahedron Letters, 2026, 181, 156116
DOI: 10.1016/j.tetlet.2026.156116

Synthesis and biological activities of novel chiral fluorinated β‐carboline derivatives

Jin Chang Ding, Xiao Bo Huang, Hua Yue Wu, Jie Zhi Chen, Ming Tiao Cai and Miao Chang Liu

Journal of Heterocyclic Chem, 2008, 45, 1783
DOI: 10.1002/jhet.5570450635

Transition-Metal-Catalyzed Directing-Group-Assisted C4-H Carbon–Carbon Bond Formation of Indole

Shubhajit Basak, Tripti Paul, Prabhat Kumar Maharana, Bijoy Debnath and Tharmalingam Punniyamurthy

Synlett, 2023, 34, 759
DOI: 10.1055/a-1928-3466

Boron Trifluoride‐Catalyzed Synthesis of 3‐Alkylidene‐3H‐indole N‐Oxides via Tandem Reaction of Propargylic Alcohols and Nitrosobenzenes

Sengodagounder Muthusamy, Alagesan Balasubramani and Eringathodi Suresh

Adv Synth Catal, 2017, 359, 786
DOI: 10.1002/adsc.201601151

Construction of C5‐Indole Unnatural Amino Acid Motifs via Diastereoselective Pd(II)‐Catalyzed β‐C(sp3)‐H Functionalization

Pooja Patel, Srinivasarao Arulananda Babu and Radha Tomar

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400190

Synthesis of Indoles through Highly Efficient Cascade Reactions of Sulfur Ylides and N‐(ortho‐Chloromethyl)aryl Amides

Qing‐Qing Yang, Cong Xiao, Liang‐Qiu Lu, Jing An, Fen Tan, Bin‐Jie Li and Wen‐Jing Xiao

Angew Chem Int Ed, 2012, 51, 9137
DOI: 10.1002/anie.201203657

Synthesis of 2‐Substituted Indoles through Visible Light‐Induced Photocatalytic Cyclizations of Styryl Azides

Xu‐Dong Xia, Jun Xuan, Qiang Wang, Liang‐Qiu Lu, Jia‐Rong Chen and Wen‐Jing Xiao

Adv Synth Catal, 2014, 356, 2807
DOI: 10.1002/adsc.201400527

Trifluoromethylated 5-aminoderivatives of (indol-3-yl)acetic acid

D. V. Vorobyeva, T. P. Vasilyeva and S. N. Osipov

Russ Chem Bull, 2018, 67, 1459
DOI: 10.1007/s11172-018-2240-2

Metal complexes involving indole rings: Structures and effects of metal–indole interactions

Yuichi Shimazaki, Tatsuo Yajima, Masako Takani and Osamu Yamauchi

Coordination Chemistry Reviews, 2009, 253, 479
DOI: 10.1016/j.ccr.2008.04.012

Facile Synthesis of 2- and 3-Substituted Indoles Using a Catalytic Amount of Pd/C and 1-Octene System

Xu Dong, Ryosuke Matsubara and Masahiko Hayashi

Synthesis, 2025, 57, 800
DOI: 10.1055/a-2464-6964

Tandem Iridium-Catalyzed Decarbonylative C–H Activation of Indole: Sacrificial Electron-Rich Ketone-Assisted Bis-arylsulfenylation

Subban Kathiravan, Prasad Anaspure, Tianshu Zhang and Ian A. Nicholls

Org. Lett., 2021, 23, 3331
DOI: 10.1021/acs.orglett.1c00829

Cascade Oxidative Dearomatization/Semipinacol Rearrangement: An Approach to 2‐Spirocyclo‐3‐oxindole Derivatives

Jin‐Bao Peng, Yue Qi, Ai‐Jun Ma, Yong‐Qiang Tu, Fu‐Min Zhang, Shao‐Hua Wang and Shu‐Yu Zhang

Chemistry An Asian Journal, 2013, 8, 883
DOI: 10.1002/asia.201300032

Cobalt(III)‐katalysierte redoxneutrale Synthese von freien Indolen durch N‐N‐Bindungsspaltung

Andreas Lerchen, Suhelen Vásquez‐Céspedes and Frank Glorius

Angewandte Chemie, 2016, 128, 3261
DOI: 10.1002/ange.201510705

Construction of Chiral Tetrahydro‐β‐Carbolines: Asymmetric Pictet–Spengler Reaction of Indolyl Dihydropyridines

Shou‐Guo Wang, Zi‐Lei Xia, Ren‐Qi Xu, Xi‐Jia Liu, Chao Zheng and Shu‐Li You

Angewandte Chemie, 2017, 129, 7548
DOI: 10.1002/ange.201703178

Intramolecular Cooperative CC Bond Cleavage Reaction of 1,3‐Dicarbonyl Compounds with 2‐Iodoanilines to Give o‐(N‐Acylamino)aryl Ketones and Multisubstituted Indoles

Qi Xing , Hui Lv, Chungu Xia and Fuwei Li

Chemistry A European J, 2015, 21, 8591
DOI: 10.1002/chem.201500272

Ruthenium(II)‐Catalyzed C−H Bond [3+2] Annulation of N‐Nitrosoanilines with Alkynes in Water

Xun Chen, Xue Cui, Lili Bai, Ying Wang, Ying Xie, Shuojin Wang, Ruirui Zhai, Ke Zhao, Dulin Kong and Youbin Li

Asian J Org Chem, 2019, 8, 2209
DOI: 10.1002/ajoc.201900553

Mechanistic Insights into Cobalt-Catalyzed Regioselective C4-Alkenylation of 3-Acetylindole: A Detailed Theoretical Study

Jin-Feng Li, Bing Yin and Ji-Jiang Wang

J. Org. Chem., 2022, 87, 14125
DOI: 10.1021/acs.joc.2c01696

Enantioselective BINOL-Phosphoric Acid Catalyzed Pictet−Spengler Reactions of N-Benzyltryptamine

Nishant V. Sewgobind, Martin J. Wanner, Steen Ingemann, René de Gelder, Jan H. van Maarseveen and Henk Hiemstra

J. Org. Chem., 2008, 73, 6405
DOI: 10.1021/jo8010478

Aromatic Enamide/Ene Metathesis toward Substituted Indoles and Its Application to the Synthesis of Indomethacins

Yayoi Kasaya, Kosuke Hoshi, Yukiyoshi Terada, Atsushi Nishida, Satoshi Shuto and Mitsuhiro Arisawa

Eur J Org Chem, 2009, 2009, 4606
DOI: 10.1002/ejoc.200900520

Base-promoted domino reaction for the synthesis of 2,3-disubstituted indoles from 2-aminobenzaldehyde/2-amino aryl ketones, tosylhydrazine, and aromatic aldehydes

Yan-Dong Wu, Jun-Rui Ma, Wen-Ming Shu, Kai-Lu Zheng and An-Xin Wu

Tetrahedron, 2016, 72, 4821
DOI: 10.1016/j.tet.2016.06.046

Ruthenium(II)-Catalyzed Redox-Neutral [3+2] Annulation of Indoles with Internal Alkynes via C–H Bond Activation: Accessing a Pyrroloindolone Scaffold

Yanan Xie, Xiaowei Wu, Chunpu Li, Jiang Wang, Jian Li and Hong Liu

J. Org. Chem., 2017, 82, 5263
DOI: 10.1021/acs.joc.7b00575

Recent Advances of Producing Biobased N-Containing Compounds via Thermo-Chemical Conversion with Ammonia Process

Lujiang Xu, Chenchen Shi, Zijian He, Huan Zhang, Mingying Chen, Zhen Fang and Ying Zhang

Energy Fuels, 2020, 34, 10441
DOI: 10.1021/acs.energyfuels.0c01993

Evaluation of the 5-ethynyl-1,3,3-trimethyl-3H-indole ligand for molecular materials applications

David Jago, David C. Milan, Alexandre N. Sobolev, Simon J. Higgins, Andrea Vezzoli, Richard J. Nichols, George A. Koutsantonis and Martyn Coles

Australian Journal of Chemistry, 2023, 76, 209
DOI: 10.1071/CH23069

Highly Enantioselective Michael Addition of Malonates to β‐CF3‐β‐(3‐Indolyl)nitroalkenes: Construction of Trifluoromethylated All‐Carbon Quaternary Stereogenic Centres

Chun‐Hui Ma, Tai‐Ran Kang, Long He and Quan‐Zhong Liu

Eur J Org Chem, 2014, 2014, 3981
DOI: 10.1002/ejoc.201402243

Synthesis of 2‐Methylindoles through Ruthenium(II)‐Catalyzed Reaction of Aniline Derivatives with Allylamines

Xue‐Yi He and Zhong‐Xia Wang

Adv Synth Catal, 2023, 365, 355
DOI: 10.1002/adsc.202201181

Catalytic Atroposelective Dynamic Kinetic Resolution of Substituted Indoles

Ahreum Kim and Yongseok Kwon

Synlett, 2022, 33, 201
DOI: 10.1055/a-1694-4695

Toward Acetylene Renaissance: Functionally Rich N-Aminoindoles from Acetylene Gas, Ketones, and Hydrazines in Two Steps

Elena Yu. Schmidt, Nadezhda V. Semenova, Inna V. Tatarinova, Igor’ A. Ushakov, Alexander V. Vashchenko and Boris A. Trofimov

Org. Lett., 2019, 21, 4275
DOI: 10.1021/acs.orglett.9b01452

CF3‐Carbenoid C–H Functionalization of (Hetero)arenes under Chelation‐Controlled RhIII Catalysis

Irina E. Iagafarova, Daria V. Vorobyeva, Alexander S. Peregudov and Sergey N. Osipov

Eur J Org Chem, 2015, 2015, 4950
DOI: 10.1002/ejoc.201500545

Morita–Baylis–Hillman reaction of 3-formyl-9H-pyrido[3,4-b]indoles and fluorescence studies of the products

Nisha Devi and Virender Singh

Beilstein J. Org. Chem., 2022, 18, 926
DOI: 10.3762/bjoc.18.92

Rhodium(I)‐Catalyzed Cycloisomerization of Nitrogen‐Tethered Indoles and Alkylidenecyclopropanes: Convenient Access to Polycyclic Indole Derivatives

Di‐Han Zhang, Xiang‐Ying Tang, Yin Wei and Min Shi

Chemistry A European J, 2013, 19, 13668
DOI: 10.1002/chem.201302331

Co(III), Rh(III) & Ir(III)‐Catalyzed Direct C−H Alkylation/Alkenylation/Arylation with Carbene Precursors

Saiprasad Nunewar, Sanjeev Kumar, Srilakshmi Talakola, Srinivas Nanduri and Vinaykumar Kanchupalli

Chemistry An Asian Journal, 2021, 16, 443
DOI: 10.1002/asia.202001219

2,3-Difunctionalized Indoles via Radical Acylation or Trifluoromethylation of ortho-Alkynylphenyl Isonitriles

Dirk Leifert, Frauke Weidlich, Florin Adler, Constantin G. Daniliuc, Fatmah A. Alasmary and Armido Studer

Org. Lett., 2022, 24, 284
DOI: 10.1021/acs.orglett.1c03916

β‐Carboline‐Based pH Fluorescent Probe and Its Application for Monitoring Enzymatic Ester Hydrolysis

Rong Huang, Xian‐Dong Zhang, Xing Wu and Ji‐Kai Liu

Chemistry & Biodiversity, 2021, 18
DOI: 10.1002/cbdv.202000829

Palladium‐Catalyzed Synthesis of 2‐Fluoroalkyl‐3‐methylene‐3H‐indoles Through a Domino Carbopalladation/CH Activation Process

Zixian Chen, Jiangtao Zhu, Haibo Xie, Shan Li, Yongming Wu and Yuefa Gong

Adv Synth Catal, 2011, 353, 325
DOI: 10.1002/adsc.201000689

Specific Synthesis of 3H-Indole Derivatives via Rh(III)-Catalyzed Cascade Annulation between N-Phenylbenzimidamides and Pyridotriazoles

Hui-Bei Xu, Yan-Ying Zhu and Lin Dong

J. Org. Chem., 2019, 84, 16286
DOI: 10.1021/acs.joc.9b02468

RhIII‐Catalyzed Directed Selective C7‐Hydroxylation and Acetoxylation of Indolines

Wenchao Zhai, Bin Li and Baiquan Wang

ChemistrySelect, 2018, 3, 8035
DOI: 10.1002/slct.201801425

Copper‐Catalyzed Sequential C(sp2)/C(sp3)−H Amination of 2‐Vinylanilines with N‐Fluorobenzenesulfonimide

Wen‐Bin Cao, Xiao‐Ping Xu and Shun‐Jun Ji

Adv Synth Catal, 2019, 361, 1771
DOI: 10.1002/adsc.201801710

A Facile Route to Polysubstituted Indoles via Three-Component Reaction of 2-Ethynylaniline, Sulfonyl Azide, and Nitroolefin

Zhiyuan Chen, Danqing Zheng and Jie Wu

Org. Lett., 2011, 13, 848
DOI: 10.1021/ol102775s

Design and Enantioselective Synthesis of β-Vinyl Tryptamine Building Blocks for Construction of Privileged Chiral Indole Scaffolds

Tao-Yan Lin, Hai-Hong Wu, Jian-Jun Feng and Junliang Zhang

ACS Catal., 2017, 7, 4047
DOI: 10.1021/acscatal.7b00870

Palladium-Catalyzed Intramolecular Trapping of the Blaise Reaction Intermediate for Tandem One-Pot Synthesis of Indole Derivatives

Ju Hyun Kim and Sang-gi Lee

Org. Lett., 2011, 13, 1350
DOI: 10.1021/ol200045q

A Cascade Rh(III)‐catalyzed C−H Activation/Chemodivergent Annulation of N‐carbamoylindoles with Sulfoxonium Ylides for the Synthesis of Dihydropyrimidoindolone and Tricyclic [1,3]Oxazino[3,4‐a]indol‐1‐ones Derivatives

Hui Xie, Mei Zhong, Hua‐Jie Kang, Bing Shu and Shang‐Shi Zhang

Adv Synth Catal, 2021, 363, 1436
DOI: 10.1002/adsc.202001380

Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst

Alison E. Wendlandt and Shannon S. Stahl

J. Am. Chem. Soc., 2014, 136, 506
DOI: 10.1021/ja411692v

Base‐Promoted Decarboxylative Aza‐Michael Strategy: Accessing Succinimide Fused Spiro Indolin‐3‐ones with Potent Antibacterial Activity

Sai Lokavarapu, Chiranjeevi Pandikona, Linga Reddy Eeda, Rajesh Gujju, Rahul Shivaji Shingare, Jagadeesh Babu Nanubolu, Sai Krishna Chilaka and Ravindra M. Kumbhare

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500017

Palladium-catalyzed synthesis of 3-alkenyl indoles from 2-azido-3-arylacrylates and terminal alkenes at room temperature

Yaohong Zhang, Shen Liu, Wanwan Yu, Miao Hu, Guolin Zhang and Yongping Yu

Tetrahedron, 2013, 69, 2070
DOI: 10.1016/j.tet.2012.11.062

Cu(I)-Catalyzed Chemoselective and Stereoselective [3 + 3] Cycloaddition of Azomethine Ylides with 2-Indolylnitroethylenes: Facile Access to Highly Substituted Tetrahydro-γ-Carbolines

Wu-Lin Yang, Chun-Yan Li, Wen-Jing Qin, Fei-Fei Tang, Xingxin Yu and Wei-Ping Deng

ACS Catal., 2016, 6, 5685
DOI: 10.1021/acscatal.6b01596

Copper-Catalyzed Tandem O-Vinylation of Arylhydroxylamines/[3,3]-Rearrangement/Cyclization: Synthesis of Highly Substituted Indoles and Benzoindoles

Hairui Yuan, Lirong Guo, Fengting Liu, Zechen Miao, Lei Feng and Hongyin Gao

ACS Catal., 2019, 9, 3906
DOI: 10.1021/acscatal.9b00470

Selective Synthesis of 2‐(Indol‐3‐Yl)Phenols via Iodine‐Catalyzed C3‐Arylation of Indoles with Cyclohexanones

Qi Yin, Xinlin Zhou, Chao Zhang, Shanping Chen, Yuxia Li and Guo‐Jun Deng

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202401507

Iridium(III)-Catalyzed C-7 Selective C–H Alkynylation of Indolines at Room Temperature

Yunxiang Wu, Yaxi Yang, Bing Zhou and Yuanchao Li

J. Org. Chem., 2015, 80, 1946
DOI: 10.1021/jo502596k

Palladium-Catalyzed Asymmetric Cycloadditions of Vinylcyclopropanes and in Situ Formed Unsaturated Imines: Construction of Structurally and Optically Enriched Spiroindolenines

Ze-Shui Liu, Wen-Ke Li, Tai-Ran Kang, Long He and Quan-Zhong Liu

Org. Lett., 2015, 17, 150
DOI: 10.1021/ol503383x

Rhodium-Catalyzed Annulation of Tertiary Aniline N-Oxides to N-Alkylindoles: Regioselective C–H Activation, Oxygen-Atom Transfer, and N-Dealkylative Cyclization

Bin Li, Hong Xu, Huanan Wang and Baiquan Wang

ACS Catal., 2016, 6, 3856
DOI: 10.1021/acscatal.6b00311

Highly Efficient Rhodium‐Catalyzed Oxindole‐Directed Oxidative Heck‐Type Reaction of N‐Aryloxindoles with Alkenes

Wei‐Huan Li, Chao Li and Lin Dong

Asian J Org Chem, 2018, 7, 2448
DOI: 10.1002/ajoc.201800605

The Rich Legacy and Bright Future of Transition‐Metal Catalyzed Peroxide Based Radical Reactions

Anjali Dahiya and Bhisma K. Patel

The Chemical Record, 2021, 21, 3589
DOI: 10.1002/tcr.202100115

Synthetic Access to Poly-Substituted 6-Alkoxyindoles from 1,3-Cyclohexanediones and Nitroolefins through Facile Aromatization Reaction

Li-Jian Ma, Xiao-Xia Li, Tomoyo Kusuyama, Ibrahim El-Tantawy El-Sayed and Tsutomu Inokuchi

J. Org. Chem., 2009, 74, 9218
DOI: 10.1021/jo902068m

Synthesis of 3-Haloindoles via Cascade Oxidative Cyclization/Halogenation of 2-Alkenylanilines Mediated by PIDA and LiBr/KI

Bingyue Zhao, Xiaoxian Li, Xiaofan Wang, Luchen Jiang, Zhe Li and Yunfei Du

J. Org. Chem., 2023, 88, 1493
DOI: 10.1021/acs.joc.2c02480

Palladium-Catalyzed Sequential Vinylic C–H Arylation/Amination of 2-Vinylanilines with Aryl boronic Acids: Access to 2-Arylindoles

Ruixia Yu, Dejun Li and Fanlong Zeng

J. Org. Chem., 2018, 83, 323
DOI: 10.1021/acs.joc.7b02728

Selenium‐Mediated Cyclization Reaction of 2‐Vinylanilines with/without Isonitriles: Efficient Synthesis of 2‐Aminoquinoline/ 3‐Aryl‐1H‐indole Derivatives

Xi Zhang, Yong‐Qing Wang, Anwar L. Alduma, Ullah Arif S. H, Xi‐Cun Wang and Zheng‐Jun Quan

Asian J Org Chem, 2020, 9, 588
DOI: 10.1002/ajoc.202000119

Brønsted Acid‐Catalyzed Synthesis of N‐Arylindoles from 2‐Vinylanilines and Quinones

Han‐Ming Zhang, Zhong‐Hua Gao, Liang Yi and Song Ye

Chemistry An Asian Journal, 2016, 11, 2671
DOI: 10.1002/asia.201600420

Au(I)-Catalyzed Pictet–Spengler Reactions All around the Indole Ring

Pierre Milcendeau, Zhenhao Zhang, Nicolas Glinsky-Olivier, Elsa van Elslande and Xavier Guinchard

J. Org. Chem., 2021, 86, 6406
DOI: 10.1021/acs.joc.1c00270

Combining Trifunctionalization of Alkynoic Acids, Arene ortho C–H Functionalization and Amination: An Approach to Unsymmetrical 2,3-Diaryl Substituted Indoles

Narges Mohammadi, Farid Mohaghegh, Mehran Ghasemi and Farnaz Jafarpour

Org. Lett., 2024, 26, 9492
DOI: 10.1021/acs.orglett.4c03446

Palladium‐Catalyzed C–C Coupling/C–H Activation: Formation of Isoindolinone‐Fused Heterocyclic Compounds

Yimin Hu, Dong Ren, Lidong Zhang, Xiangang Lin and Jing Wan

Eur J Org Chem, 2010, 2010, 4454
DOI: 10.1002/ejoc.201000492

Catalytic Ring Expansion of Indole toward Dibenzoazepine Analogues Enabled by Cationic Palladium(II) Complexes

Jiaping Wu, Yanfei Liu, Baiyang Qian, Haitao Yang, Lili Lu, Jitan Zhang and Yongjia Shang

ACS Catal., 2022, 12, 6216
DOI: 10.1021/acscatal.1c06021

Copper in Efficient Synthesis of Aromatic Heterocycles with Single Heteroatom

Tapas Pal, Goutam Kumar Lahiri and Debabrata Maiti

Eur J Org Chem, 2020, 2020, 6859
DOI: 10.1002/ejoc.202000688

Diastereoselective synthesis of tetrasubstituted-octahydro-3,6-diazacarbazoles and tetrasubstituted-3,6-diazacarbazoles via double Pictet–Spengler reaction

Abdullah M.A. Shumaila, Vedavati G. Puranik and Radhika S. Kusurkar

Tetrahedron Letters, 2011, 52, 2661
DOI: 10.1016/j.tetlet.2011.03.060

Synthesis of benz[f]indole-4,9-diones via acetylenic derivatives of 1,4-naphthoquinone

Mark S. Shvartsberg, Ekaterina A. Kolodina, Nadezhda I. Lebedeva and Lidiya G. Fedenok

Tetrahedron Letters, 2009, 50, 6769
DOI: 10.1016/j.tetlet.2009.09.110

Dinuclear Ni(II) and Cu(II) complexes with indolecarboxamide ligand: Synthesis, structure and properties

Megha Munjal and Rajeev Gupta

Inorganica Chimica Acta, 2010, 363, 2734
DOI: 10.1016/j.ica.2010.04.022

Pd–C bond formation with the indole ring in palladium complexes of N,N,O-donor ligands. Effect of the nitrogen donor properties

Syogo Tanooka, Takuya Suzuki, Tatsuo Yajima, Tadashi Shiraiwa, Satoshi Iwatsuki and Yuichi Shimazaki

Inorganica Chimica Acta, 2013, 407, 41
DOI: 10.1016/j.ica.2013.07.032

2-Trifluoromethylated Indoles via Radical Trifluoromethylation of Isonitriles

Bo Zhang and Armido Studer

Org. Lett., 2014, 16, 1216
DOI: 10.1021/ol5001395

Pd‐Catalyzed Regioselective Direct Double C–H Arylation of 6,7‐Benzindoles

Ping‐Gui Li, Youqing Yang, Shuai Zhu, Hong‐Xi Li and Liang‐Hua Zou

Eur J Org Chem, 2019, 2019, 73
DOI: 10.1002/ejoc.201801473

[(S)-BINAP]PdBr2-catalyzed direct synthesis of 2,3-disubstituted indoles via a tandem reaction between arylamines and α-diketones

A. Cabrera, P. Sharma, M. Ayala, L. Rubio-Perez and Manuel Amézquita-Valencia

Tetrahedron Letters, 2011, 52, 6758
DOI: 10.1016/j.tetlet.2011.10.025

Synthesis of Indoles through Highly Efficient Cascade Reactions of Sulfur Ylides and N‐(ortho‐Chloromethyl)aryl Amides

Qing‐Qing Yang, Cong Xiao, Liang‐Qiu Lu, Jing An, Fen Tan, Bin‐Jie Li and Wen‐Jing Xiao

Angewandte Chemie, 2012, 124, 9271
DOI: 10.1002/ange.201203657

Dimerization of (+)-Lysergic Acid Esters

István Moldvai, Luca Russo, Kari Rissanen, Julianna Kardos, Eszter Gács-Baitz, Eszter Termesvári-Major, Imre Pápai, Éva Szárics and Csaba Szántay

HETEROCYCLES, 2007, 71, 1075
DOI: 10.3987/COM-07-11011

Synthesis of Indoles and Pyrroles Utilizing Iridium Carbenes Generated from Sulfoxonium Ylides

Janakiram Vaitla, Annette Bayer and Kathrin H. Hopmann

Angew Chem Int Ed, 2017, 56, 4277
DOI: 10.1002/anie.201610520

Construction of 2‐Methylindoles Using Solid Calcium Carbide as a Substitute for Gaseous Acetylene

Zhiqiang Wang, Zhenrong Liu, Botao Wang and Zheng Li

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202301262

Synthesis of Substituted 3-Indolylimines and Indole-3-carboxaldehydes by Rhodium(II)-Catalyzed Annulation

Basker Rajagopal, Chih-Hung Chou, Ching-Cheng Chung and Po-Chiao Lin

Org. Lett., 2014, 16, 3752
DOI: 10.1021/ol501618z

A [4+1] Cyclative Capture Approach to 3H‐Indole‐N‐oxides at Room Temperature by Rhodium(III)‐Catalyzed CH Activation

Yaxi Yang, Xuan Wang, Yuanchao Li and Bing Zhou

Angewandte Chemie, 2015, 127, 15620
DOI: 10.1002/ange.201508702

Au-promoted Pd-catalyzed arylative cyclization of N,N-dimethyl-o-alkynylaniline with aryl iodides: Access to 2,3-diaryl indoles and mechanistic insight

Kemeng Yuan, Jiwei Wang, Feijun Wang and Jun Zhang

Tetrahedron Letters, 2021, 65, 152766
DOI: 10.1016/j.tetlet.2020.152766

Rh(III)-catalyzed selective C7-H functionalization of indolines with 1,3-enynes enables access to six-membered 1,7-fused indolines

Yunkai Shi, Chao Chen, Yaxi Yang and Bing zhou

Tetrahedron Letters, 2021, 72, 153065
DOI: 10.1016/j.tetlet.2021.153065

A Copper‐Catalyzed Decarboxylative Amination/Hydroamination Sequence: Switchable Synthesis of Functionalized Indoles

Tian‐Ren Li, Bei‐Yi Cheng, Ya‐Ni Wang, Mao‐Mao Zhang, Liang‐Qiu Lu and Wen‐Jing Xiao

Angew Chem Int Ed, 2016, 55, 12422
DOI: 10.1002/anie.201605900

Regiocontrolled Direct C−H Arylation of Indoles at the C4 and C5 Positions

Youqing Yang, Pan Gao, Yue Zhao and Zhuangzhi Shi

Angewandte Chemie, 2017, 129, 4024
DOI: 10.1002/ange.201612599

An Unexpected FeCl3-Catalyzed Cascade Reaction of Indoles and o-Hydroxychalcones for the Assembly of Chromane-Bridged Polycyclic Indoles

Wenbo Wang, Xuguan Bai, Shaojing Jin, Jiaomei Guo, Yang Zhao, Hongjie Miao, Yanshuo Zhu, Qilin Wang and Zhanwei Bu

Org. Lett., 2018, 20, 3451
DOI: 10.1021/acs.orglett.8b01107

Recent Advances in the Synthesis of Indole and Quinoline Derivatives through Cascade Reactions

José Barluenga, Félix Rodríguez and Francisco J. Fañanás

Chemistry An Asian Journal, 2009, 4, 1036
DOI: 10.1002/asia.200900018

Visible‐Light‐Induced Direct Photocatalytic Carboxylation of Indoles with CBr4/MeOH

Qing‐Qing Yang, Marianna Marchini, Wen‐Jing Xiao, Paola Ceroni and Marco Bandini

Chemistry A European J, 2015, 21, 18052
DOI: 10.1002/chem.201503787

Rh(III)-Catalyzed Synthesis of N-Unprotected Indoles from Imidamides and Diazo Ketoesters via C–H Activation and C–C/C–N Bond Cleavage

Zisong Qi, Songjie Yu and Xingwei Li

Org. Lett., 2016, 18, 700
DOI: 10.1021/acs.orglett.5b03669

Palladium-Catalyzed Synthesis of 2,3-Diaryl-N-methylindoles fromortho-Alkynylanilines and Aryl Pinacol Boronic Esters

Yue-Gui Luo, R. Sidick Basha, Daggula Mallikarjuna Reddy, Yong-Jing Xue, Te-Hsuan Chen and Chin-Fa Lee

Org. Lett., 2018, 20, 6872
DOI: 10.1021/acs.orglett.8b02835

Structural Investigations on 4-Chloro-6-Phenyl-7,8,9,14-Tetrahydroquinolino [2′,3′:7,6]cyclohept[b]indoles

Ezhumalai Yamuna, Makuteswaran Sridharan, Karnam Jayarampillai Rajendra Prasad and Matthias Zeller

J Chem Crystallogr, 2010, 40, 402
DOI: 10.1007/s10870-009-9668-z

N‐Heterocyclic Carbene‐Catalyzed Homoenolate Additions with N‐Aryl Ketimines as Electrophiles: Efficient Synthesis of Spirocyclic γ‐Lactam Oxindoles

Bo Zhang, Peng Feng, Li‐Hui Sun, Yuxin Cui, Song Ye and Ning Jiao

Chemistry A European J, 2012, 18, 9198
DOI: 10.1002/chem.201201375

Csp2–Csp2 bond formation via Lewis acid/ammonium salt cocatalyzed tandem addition and oxidative dehydrogenation strategy: alkenylation of indoles with α,β-unsaturated ketones

Shi-Kai Xiang, Guolin Wu, Bo Zhang, Yuxin Cui and Ning Jiao

Tetrahedron Letters, 2012, 53, 3802
DOI: 10.1016/j.tetlet.2012.05.053

Electronic Effect Directed Au(I)-Catalyzed Cyclic C2–H Bond Functionalization of 3-Allenylindoles

Bo Chen, Wu Fan, Guobi Chai and Shengming Ma

Org. Lett., 2012, 14, 3616
DOI: 10.1021/ol301408g

Metal-Free Directed C–H Borylation of Indoles at the Sterically Congested C2 Position

Wang Jiang, Jingyi Bai, Jiahang Lv, Yue Zhao, Chaoguo Yan and Zhuangzhi Shi

Synlett, 2023, 34, 2220
DOI: 10.1055/a-2126-1750

A simple approach for the synthesis of azocine alkaloids: The total synthesis of megallanesine

Prajesh S. Volvoikar and Santosh G. Tilve

Tetrahedron Letters, 2018, 59, 2567
DOI: 10.1016/j.tetlet.2018.05.055

Tandem Phospha‐Michael Addition/N‐Acylation/ Intramolecular Wittig Reaction of aza‐o‐Quinone Methides: Approaches to 2,3‐Disubstituted Indoles

Ting‐Bi Hua, Fei Chao, Long Wang, Chen‐Yang Yan, Cong Xiao, Qing‐Qing Yang and Wen‐Jing Xiao

Adv Synth Catal, 2020, 362, 2615
DOI: 10.1002/adsc.202000343

Copper-mediated intramolecular aza-Wacker-type cyclization of 2-alkenylanilines toward 3-aryl indoles

Rui Yang, Jin-Tao Yu, Song Sun, Qingheng Zheng and Jiang Cheng

Tetrahedron Letters, 2017, 58, 445
DOI: 10.1016/j.tetlet.2016.12.053

Indoles from Simple Anilines and Alkynes: Palladium‐Catalyzed CH Activation Using Dioxygen as the Oxidant

Zhuangzhi Shi, Chun Zhang, Si Li, Delin Pan, Shengtao Ding, Yuxin Cui and Ning Jiao

Angew Chem Int Ed, 2009, 48, 4572
DOI: 10.1002/anie.200901484

Selective Synthesis of N-Unsubstituted and N-Arylindoles by the Reaction of Arynes with Azirines

Manikandan Thangaraj, Sachin Suresh Bhojgude, Shailja Jain, Rajesh G. Gonnade and Akkattu T. Biju

J. Org. Chem., 2016, 81, 8604
DOI: 10.1021/acs.joc.6b01472

Palladium-Catalyzed 2-fold C–H Activation/C–C Coupling for C4-Arylation of Indoles Using Weak Chelation

Shubhajit Basak, Tripti Paul and Tharmalingam Punniyamurthy

Org. Lett., 2022, 24, 554
DOI: 10.1021/acs.orglett.1c03970

Rhodium(III)‐ and Iridium(III)‐Catalyzed C7 Alkylation of Indolines with Diazo Compounds

Wen Ai , Xueyan Yang, Yunxiang Wu, Xuan Wang, Yuanchao Li, Yaxi Yang and Bing Zhou

Chemistry A European J, 2014, 20, 17653
DOI: 10.1002/chem.201405077

Acenaphtho[1,2-b]Indoles Synthesis Using SBA-Pr-SO3H

Ghodsi Mohammadi Ziarani, Marziesadat Mirhosseyni, Fatemeh Kiani-Amiri and Alireza Badiei

Chemistry Africa, 2024, 7, 4713
DOI: 10.1007/s42250-024-01022-0

Mononuclear nickel and copper complexes with indolecarboxamide ligands: Synthesis, properties and electrochemistry

Megha Munjal and Rajeev Gupta

Inorganica Chimica Acta, 2011, 372, 266
DOI: 10.1016/j.ica.2011.02.056

PtCl4-catalyzed cyclization of N-acetyl-2-alkynylanilines: A mild and efficient synthesis of N-acetyl-2-substituted indoles

Nattawadee Chaisan, Wilailak Kaewsri, Charnsak Thongsornkleeb, Jumreang Tummatorn and Somsak Ruchirawat

Tetrahedron Letters, 2018, 59, 675
DOI: 10.1016/j.tetlet.2018.01.014

Versatility of Substituted 1‐Formyl‐9H‐β‐carbolines for the Synthesis of New Fused β‐Carbolines via Intramolecular 1,3‐Dipolar Cycloaddition

Virender Singh, Samiran Hutait, Subhasish Biswas and Sanjay Batra

Eur J Org Chem, 2010, 2010, 531
DOI: 10.1002/ejoc.200901166

Scope of the Reactions of Indolyl- and Pyrrolyl-Tethered N-Sulfonyl-1,2,3-triazoles: Rhodium(II)-Catalyzed Synthesis of Indole- and Pyrrole-Fused Polycyclic Compounds

Liangbing Fu and Huw M. L. Davies

Org. Lett., 2017, 19, 1504
DOI: 10.1021/acs.orglett.7b00180

Microwave-assisted synthesis of indole- and azaindole-derivatives in water via cycloisomerization of 2-alkynylanilines and alkynylpyridinamines promoted by amines or catalytic amounts of neutral or basic salts

Adriano Carpita, Arianna Ribecai and Paolo Stabile

Tetrahedron, 2010, 66, 7169
DOI: 10.1016/j.tet.2010.06.083

Assembly of Indole Cores through a Palladium-Catalyzed Metathesis of Ar–X σ-Bonds

Farnaz Jafarpour, Mehran Ghasemi, Hamed Navid, Niloofar Safaie, Saideh Rajai-Daryasarei, Azizollah Habibi and Robert C. Ferrier

Org. Lett., 2020, 22, 9556
DOI: 10.1021/acs.orglett.0c03611

Benzoic Acid-Promoted C2–H Borylation of Indoles with Pinacolborane

Youliang Zou, Binfeng Zhang, Li Wang and Hua Zhang

Org. Lett., 2021, 23, 2821
DOI: 10.1021/acs.orglett.1c00809

Synthesis of fluorinated β-carbolines by one-pot reaction

Mingtiao Cai, Jiuxi Chen, Xiaobo Huang, Miaochang Liu, Jinchang Ding and Huayue Wu

Journal of Chemical Research, 2008, 2008, 696
DOI: 10.3184/030823408X380740

Ligand‐Free Copper‐Catalyzed One‐Pot Synthesis of Indole‐2‐carboxylic Esters

Zhiqiang Zhu, Jiangjun Yuan, Yirong Zhou, Yang Qin, Jingshi Xu and Yiyuan Peng

Eur J Org Chem, 2014, 2014, 511
DOI: 10.1002/ejoc.201301607

Facile Access to Polysubstituted Indoles via a Cascade Cu-Catalyzed Arylation−Condensation Process

Yu Chen, Xiaoan Xie and Dawei Ma

J. Org. Chem., 2007, 72, 9329
DOI: 10.1021/jo702059q