Issue 22, 2024

A triazolium-based fluorophore intercalated in layered double hydroxides: from simple syntheses to bright solid-state luminescence

Abstract

This study presents the intercalation into Layered Double Hydroxides (LDHs) of two sulfonated organic molecules featuring the mesoionic triazolium scaffold. These sulfonated fluorophores exhibited excellent solubility in aqueous basic solutions, facilitating their compatibility with the synthesis of LDHs through coprecipitation methods. We applied the size-matching interlayer space (SMIS) approach by substituting a portion of a mono- or dianionic surfactant used in LDH preparation by the sulfonated fluorophore, we aimed to match the size of the luminescent interleaved guest effectively. Our investigation focused on two anion spacers: the classic monoanionic dodecyl sulfate (DS) and the dianionic phenylene dipropionate (PPA). Our results indicated that the latter spacer allowed a more efficient insertion of the fluorescent guest. Thermal resistance analysis underscored the robustness of the final hybrid materials, suggesting a promising design strategy for luminescent materials when applied in diverse applications.

Graphical abstract: A triazolium-based fluorophore intercalated in layered double hydroxides: from simple syntheses to bright solid-state luminescence

Supplementary files

Article information

Article type
Paper
Submitted
26 fev 2024
Accepted
10 may 2024
First published
13 may 2024

Dalton Trans., 2024,53, 9369-9379

A triazolium-based fluorophore intercalated in layered double hydroxides: from simple syntheses to bright solid-state luminescence

G. Zerbib, A. Roux, L. Salat, F. Cisnetti, D. Boyer, G. Chadeyron and F. Leroux, Dalton Trans., 2024, 53, 9369 DOI: 10.1039/D4DT00573B

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