Issue 72, 2024

(Phosphino)(stannyl)carbene

Abstract

The synthesis of a (phosphino)(stannyl)carbene is documented. The combination of phosphino and stannyl substituents imparts a highly ambiphilic nature to this carbene, enabling reactions with cyanide, isocyanide, and carbon monoxide. This leads to rare stannylketenimines and a stannylketene.

Graphical abstract: (Phosphino)(stannyl)carbene

Supplementary files

Article information

Article type
Communication
Submitted
01 iyl 2024
Accepted
12 avq 2024
First published
13 avq 2024

Chem. Commun., 2024,60, 9793-9796

(Phosphino)(stannyl)carbene

R. Wei, X. Wang, C. Hu and L. L. Liu, Chem. Commun., 2024, 60, 9793 DOI: 10.1039/D4CC03275F

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