Issue 10, 2022

Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions

Abstract

Over the past decade, the reactivity of 2-phosphaethynolate (OCP), a heavier analogue of the cyanate anion, has been the subject of momentous interest in the field of modern organometallic chemistry. It is used as a precursor to novel phosphorus-containing heterocycles and as a ligand in decarbonylative processes, serving as a synthetic equivalent of a phosphinidene derivative. This perspective aims to describe advances in the reactivities of phosphaethynolate and arsaethynolate anions (OCE; E = P, As) with main-group element, transition metal, and f-block metal scaffolds. Further, the unique structures and bonding properties are discussed based on spectroscopic and theoretical studies.

Graphical abstract: Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions

Article information

Article type
Perspective
Submitted
24 noy 2021
Accepted
17 yan 2022
First published
18 yan 2022

Dalton Trans., 2022,51, 3778-3806

Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions

S. Basappa, R. Bhawar, D. H. Nagaraju and S. K. Bose, Dalton Trans., 2022, 51, 3778 DOI: 10.1039/D1DT03994F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements