Issue 21, 2021

Molecular motion in organometallic crystals: photoinduced 2π/5 rotation of n-hexyltetramethylcyclopentadienyl ligand

Abstract

Crystalline-state photoreaction of a newly prepared organorhodium dithionite complex with n-hexyltetramethyl-cyclopentadienyl (CpHex: η5-C5Me4n-Hexyl) ligands was studied by single crystal X-ray diffraction experiments; 2π/5 rotation of the CpHex ligand is induced by the photoisomerization of the dithionite group (μ-O2SSO2).

Graphical abstract: Molecular motion in organometallic crystals: photoinduced 2π/5 rotation of n-hexyltetramethylcyclopentadienyl ligand

Supplementary files

Article information

Article type
Communication
Submitted
20 yan 2021
Accepted
04 may 2021
First published
04 may 2021

CrystEngComm, 2021,23, 3790-3793

Molecular motion in organometallic crystals: photoinduced 2π/5 rotation of n-hexyltetramethylcyclopentadienyl ligand

H. Nakai, Y. Kajiwara and S. Miyata, CrystEngComm, 2021, 23, 3790 DOI: 10.1039/D1CE00093D

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