Issue 74, 2020

[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Abstract

Cluster anions [Cp*RuPb11]3− (1) and [Cu@Cp*RuPb11]2− (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C5v point symmetry and are static on the 207Pb NMR time scale in solution.

Graphical abstract: [Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Supplementary files

Article information

Article type
Communication
Submitted
24 iyn 2020
Accepted
06 avq 2020
First published
06 avq 2020

Chem. Commun., 2020,56, 10859-10862

Author version available

[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

A. Li, Y. Wang, P. Y. Zavalij, F. Chen, A. Muñoz-Castro and B. W. Eichhorn, Chem. Commun., 2020, 56, 10859 DOI: 10.1039/D0CC03656K

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