Issue 61, 2020

Mechanistic insights into polyoxometalate self-assembly in organic solvent: conversion of a cyclic polyoxovanadate-ethoxide to its Lindqvist congener

Abstract

We report the synthesis of a cyclic hexavanadate polyoxovanadate-alkoxide cluster, [VO(OC2H5)2]6, and its conversion, under solvothermal conditions, to an oxygen-deficient Lindqvist assembly, [V6O6(OC2H5)12]n (n = 1−, 0). This study presents insights into the mechanism of organo-functionalized polyoxovandate-alkoxide formation, namely identifying essential intermediates and the source of the central μ6-O2− ligand.

Graphical abstract: Mechanistic insights into polyoxometalate self-assembly in organic solvent: conversion of a cyclic polyoxovanadate-ethoxide to its Lindqvist congener

Supplementary files

Article information

Article type
Communication
Submitted
14 may 2020
Accepted
26 iyn 2020
First published
26 iyn 2020

Chem. Commun., 2020,56, 8607-8610

Author version available

Mechanistic insights into polyoxometalate self-assembly in organic solvent: conversion of a cyclic polyoxovanadate-ethoxide to its Lindqvist congener

R. L. Meyer, R. Love, W. W. Brennessel and E. M. Matson, Chem. Commun., 2020, 56, 8607 DOI: 10.1039/D0CC03464A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements