Issue 9, 2017

Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

Abstract

A metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N,N,N-trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.

Graphical abstract: Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

Supplementary files

Article information

Article type
Communication
Submitted
18 yan 2017
Accepted
15 fev 2017
First published
16 fev 2017

Green Chem., 2017,19, 2076-2079

Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

L. Liu and Z. Wang, Green Chem., 2017, 19, 2076 DOI: 10.1039/C7GC00212B

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