Issue 18, 2017

Quantifying and understanding the steric properties of N-heterocyclic carbenes

Abstract

This Feature Article presents and discusses the use of different methods to quantify and explore the steric impact of N-heterocyclic carbene (NHC) ligands. These include (a) the percent buried volume (%Vbur), which provides a convenient single number to measure steric impact and (b) steric maps, which provide a graphical representation of the steric profile of a ligand using colour-coded contour maps. A critical discussion of the scope and limitations of these tools is presented, along with some examples of their use in organometallic chemistry and catalysis. This Article should provide all users of NHCs, from organic, organometallic, and inorganic chemistry backgrounds, with an appreciation of how these tools can be used to quantify and compare their steric properties.

Graphical abstract: Quantifying and understanding the steric properties of N-heterocyclic carbenes

Associated articles

Supplementary files

Article information

Article type
Feature Article
Submitted
11 yan 2017
Accepted
09 fev 2017
First published
09 fev 2017

Chem. Commun., 2017,53, 2650-2660

Quantifying and understanding the steric properties of N-heterocyclic carbenes

A. Gómez-Suárez, D. J. Nelson and S. P. Nolan, Chem. Commun., 2017, 53, 2650 DOI: 10.1039/C7CC00255F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements