Issue 32, 2016
From the journal:

Chemical Communications

Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding†‡

Jason Y. C. Lim,a   Igor Marques, ORCID logo bc   Liliana Ferreira,c   Vítor Félixbc  and  Paul D. Beer*a  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: paul.beer@chem.ox.ac.uk

b Department of Chemistry, CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

c Department of Medical Sciences, iBiMED – Institute of Biomedicine, University of Aveiro, 3810-193 Aveiro, Portugal

Abstract

Chiral halogen bonding (S)-BINOL-based receptors are demonstrated to enhance the enantioselective recognition and sensing of chiral anions compared to their hydrogen bonding analogues. Computational studies attribute this behaviour to the strict linearity of halogen bonding (XB) and steric environment conferred by the XB donor groups bridged by the (S)-BINOL motif.

Graphical abstract: Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CC01701K
Article type
Communication
Submitted
25 fev 2016
Accepted
15 mar 2016
First published
15 mar 2016

Chem. Commun., 2016,52, 5527-5530

Permissions

Request permissions

Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

J. Y. C. Lim, I. Marques, L. Ferreira, V. Félix and P. D. Beer, Chem. Commun., 2016, 52, 5527 DOI: 10.1039/C6CC01701K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements