Issue 5, 2013

New generation biofuels: γ-valerolactone into valeric esters in one pot

Abstract

Ethyl valerate and pentyl valerate, suitable as a gasoline additive and diesel component respectively, can be obtained in a one pot one step reaction from γ-valerolactone, readily available from lignocellulosic biomass. The reaction takes place in ethanol under H2 through nucleophilic addition of the alcohol to the carboxylic group giving hydroxypentanoate, dehydration to pentenoate and hydrogenation to the saturated ester. The bifunctional catalyst used consists of a non noble metal, namely copper, supported on an amorphous weakly acidic material, therefore representing an interesting alternative to Pt–zeolite catalysts. Pentyl valerate can be obtained in one pot with conversions >90% and selectivity up to 83%.

Graphical abstract: New generation biofuels: γ-valerolactone into valeric esters in one pot

Supplementary files

Article information

Article type
Communication
Submitted
23 noy 2012
Accepted
23 noy 2012
First published
23 noy 2012

RSC Adv., 2013,3, 1302-1306

New generation biofuels: γ-valerolactone into valeric esters in one pot

C. E. Chan-Thaw, M. Marelli, R. Psaro, N. Ravasio and F. Zaccheria, RSC Adv., 2013, 3, 1302 DOI: 10.1039/C2RA23043G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements