Issue 39, 2013
From the journal:

Chemical Communications

Unraveling the local energetics of transport in a polymer ion conductor†‡

Mark D. Lingwood,ab   Zhiyang Zhang,a   Bryce E. Kidd,a   Kacey B. McCreary,a   Jianbo Houa  and  Louis A. Madsen*a  

* Corresponding authors

a Department of Chemistry and Macromolecules and Interfaces Institute, Virginia Tech, Blacksburg, VA, USA
E-mail: lmadsen@vt.edu
Fax: +1 540 231 3255
Tel: +1 540 231 1270

b Department of Chemistry, Saint Mary's College of California, Moraga, CA, USA

Abstract

We compare diffusion activation energy measurements in a hydrated perfluorosulfonate ionomer and aqueous solutions of triflic acid. These measurements provide insight into water transport dynamics on sub-nm length scales, and gauge the contribution of the polymer sidechain terminal group. Future membrane materials design will hinge on detailed understanding of transport dynamics.

Graphical abstract: Unraveling the local energetics of transport in a polymer ion conductor

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC37173A
Article type
Communication
Submitted
02 okt 2012
Accepted
14 dek 2012
First published
17 dek 2012

Chem. Commun., 2013,49, 4283-4285

Permissions

Request permissions

Unraveling the local energetics of transport in a polymer ion conductor

M. D. Lingwood, Z. Zhang, B. E. Kidd, K. B. McCreary, J. Hou and L. A. Madsen, Chem. Commun., 2013, 49, 4283 DOI: 10.1039/C2CC37173A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements