Issue 30, 2012

“Frustrated Lewis pair” hydrogenations

Abstract

This perspective article discusses developments of metal-free hydrogenation catalysts derived from “frustrated Lewis pair” (FLP) systems. The range of catalysts uncovered and the applications to reductions of imines, aziridines, enamines, silyl enol ethers, diimines, metallocene derivatives and nitrogen-based heterocycles are described. In addition, FLP aromatic reduction of aniline derivatives to the cyclohexylamine analogs is discussed. The potential applications of these metal-free reductions are considered.

Graphical abstract: “Frustrated Lewis pair” hydrogenations

Additions and corrections

Article information

Article type
Perspective
Submitted
16 fev 2012
Accepted
21 mar 2012
First published
16 apr 2012

Org. Biomol. Chem., 2012,10, 5740-5746

“Frustrated Lewis pair” hydrogenations

D. W. Stephan, Org. Biomol. Chem., 2012, 10, 5740 DOI: 10.1039/C2OB25339A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements