Issue 15, 2024

Efficient narrowband bluish-green emitters derived from a double-carbazole-fused organoboron multiple resonance skeleton with internal-structure modification

Abstract

The double-carbazole-fused organoboron framework CzBN is a widely used parent skeleton in designs of multiple resonance (MR) emitters. Currently, the majority of CzBN derivatives are derived from peripheral modification strategies. Here, we focus on internal-structure modification of the CzBN skeleton and thus develop two narrowband bluish-green MR emitters by directly embedding thiophene units into the CzBN skeleton. This incorporation of thiophene units not only extends the π-conjugated backbone towards red-shifted emission, but also improves the MR characteristics and structural rigidity for narrowband features. Both emitters achieve narrowband bluish-green emissions with extremely small full width at half maximum of ca. 23 nm in dilute toluene. Moreover, the optimized sensitized device based on BTPCzBN as the terminal emitter achieves a high maximum external quantum efficiency of up to 24% with suppressed efficiency roll-off. This work not only presents a distinct strategy for the development of CzBN derivatives via internal-structure modification of MR skeletons, but also provides valuable inspiration for the design of heteroatom-fused narrowband emitters.

Graphical abstract: Efficient narrowband bluish-green emitters derived from a double-carbazole-fused organoboron multiple resonance skeleton with internal-structure modification

Supplementary files

Article information

Article type
Paper
Submitted
25 dek 2023
Accepted
15 mar 2024
First published
18 mar 2024

J. Mater. Chem. C, 2024,12, 5386-5392

Efficient narrowband bluish-green emitters derived from a double-carbazole-fused organoboron multiple resonance skeleton with internal-structure modification

T. Zhang, Y. Cheng, H. Wang, F. Huang, X. Xiong, X. Fan, J. Yu, K. Wang and X. Zhang, J. Mater. Chem. C, 2024, 12, 5386 DOI: 10.1039/D3TC04771G

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