Issue 58, 2024

Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(iii)-based dynamic MOFs

Abstract

The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6]·12H2O}n of mixed hexagonal/decagonal (63·103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition to give the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6]·4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n.

Graphical abstract: Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(iii)-based dynamic MOFs

Supplementary files

Article information

Article type
Communication
Submitted
27 may 2024
Accepted
20 iyn 2024
First published
21 iyn 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 7451-7454

Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs

N. El Alouani Dahmouni, M. Orts-Arroyo, A. Sanchis-Perucho, N. Moliner, J. Mayans, M. Pacheco, I. Castro, G. De Munno, N. Marino, R. Ruiz-García and J. Martínez-Lillo, Chem. Commun., 2024, 60, 7451 DOI: 10.1039/D4CC02539C

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