Issue 55, 2024

Dinitrogen activation at chromium by photochemically induced CrII–C bond homolysis

Abstract

The synthesis of the organochromium(II) complexes [POCOPtBu]Cr(R) (R = p-Tol, Bn) is reported. Exposure of [POCOPtBu]Cr(Bn) to visible light promoted homolytic Cr–CBn bond cleavage and formed {[POCOPtBu]Cr}211μ-N2) via a putative [POCOPtBu]Cr(I) species.

Graphical abstract: Dinitrogen activation at chromium by photochemically induced CrII–C bond homolysis

Supplementary files

Article information

Article type
Communication
Submitted
17 may 2024
Accepted
12 iyn 2024
First published
13 iyn 2024

Chem. Commun., 2024,60, 7029-7032

Dinitrogen activation at chromium by photochemically induced CrII–C bond homolysis

O. L. Duletski, D. Platz, C. J. Pollock, M. A. Mosquera, N. Arulsamy and M. T. Mock, Chem. Commun., 2024, 60, 7029 DOI: 10.1039/D4CC02387K

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